Unsuccessful synthesis of individual 1,1-dinitroethene

• Autorzy: Kras Jowita , Mikulska Maria , Allnajar Radwan , Kula Karolina

Identyfikatory

DOI

10.58332/scirad2024v3i1a02

• Języki publikacji: EN

Abstrakty

EN

The possibility of the preparation of free 1,1-dinitroethene was examined experimentally on the basis of procedures described earlier for other examples of 1-R-1-nitroethenes. It was found, that these types of protocols are non-usable for the preparation of the title compound due to its high reactivity and tendency to decomposition and oligomerization.

Słowa kluczowe

EN

nitroalkenes; nitroalcohols; dehydratation

PL

nitroalkeny; nitroalkohole; dehydratacja

• Wydawca: Radomskie Towarzystwo Naukowe
• Czasopismo: Scientiae Radices
• Rocznik: 2024
• Tom: Vol. 3, Iss. 1
• Strony: 9--13
• Opis fizyczny: Bibliogr. 12 poz., 1 il. kolor., 1 rys.

Twórcy

autor

Kras Jowita

• Department of Organic Chemistry and Technology,Cracow University of Technology, Warszawska 24, 31-155 Cracow (Poland)

autor

Mikulska Maria

• Department of Organic Chemistry and Technology,Cracow University of Technology, Warszawska 24, 31-155 Cracow (Poland)

autor

Allnajar Radwan

• PharmD, Faculty of Pharmacy, Libyan International Medical University, Benghazi, Libya

autor

Kula Karolina

• Department of Organic Chemistry and Technology,Cracow University of Technology, Warszawska 24, 31-155 Cracow (Poland)

Bibliografia

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• [9] Jasiński, R.; Dresler, E.; Mikulska, M.; Polewski, D.; [3+2] Cycloadditions of 1-halo-1-nitroethenes with (Z)-C-(3,4,5-trimethoxyphenyl)-N-methyl-nitrone as regio- and stereocontrolled source of novel bioactive compounds: preliminary studies. Curr. Chem. Lett. 2016, 5, 123-128. DOI: 10.5267/j.ccl.2016.2.001
• [10] Sadowski, M.; Synkiewicz-Musialska, B.; Kula, K.; (1E,3E)-1,4-Dinitro-1,3-butadiene - synthesis, spectral characteristics and computational study based on MEDT, ADME and PASS simulation. Molecules 2024, 29 (2), 542. DOI: 10.3390/molecules29020542
• [11] Noland, W.E.; 2-nitroethanol. Org. Synth. 1961, 41, 67. DOI: 10.15227/orgsyn.041.0067
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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).