New energetic materials derived from common explosives. Review

• Autorzy: Szala Mateusz , Sałaciński Tomasz

Identyfikatory

DOI

10.22211/matwys/0114E

Warianty tytułu

PL

2,4,6-Trinitrotoluen jako źródło nowoczesnych materiałów wybuchowych. Przegląd

• Języki publikacji: EN

Abstrakty

EN

The review discusses the products of 2,4,6-trinitrotoluene reactions which have explosive properties or are potentially high-energy compounds. The following compounds are discussed: trinitrobenzene, cyanotrinitrobenzene, trinitroxylene, aminotrinitrotoluenes, trinitronitromethylbenzene, methylene bis(2,4,6-trinitrobenzene), hexanitrostilbene, nitromethyldiphenylamines, 4,4’,6,6’-tetranitro- 2,2’-azoxytoluene and 2,4,6-trinitrobenzylideneamine derivatives. The synthesis pathways are provided for all compounds and the detonation parameters are presented for selected compounds.

PL

Omówiono wybrane, mające właściwości wybuchowe lub będące potencjalnie związkami energetycznymi, produkty reakcji w których 2,4,6-trinitrotoluen jest substratem. Opisano między innymi: trinitrobenzen, cyjanotrinitrobenzen, trinitroksylen, amino-trinitrotolueny, trinitro-nitrometylo-benzen, metylenobis(2,4,6-trinitrobenzen), heksanitrostilben, nitro-metylo-difenyloaminy, 4,4’,6,6’-tetranitro- 2,2’-azoksytoluen oraz pochodne 2,4,6-trinitrobenzylidenoaminy. Dla każdego opisanego związku przedstawiono ścieżkę syntezy oraz dla wybranych materiałów podano parametry detonacyjne.

Słowa kluczowe

EN

2,4,6-trinitrotoluene (TNT); synthesis; cyanotrinitrobenzene; trinitro-nitromethyl-benzene; nitromethyl-diphenylamine; ATNT; BTNHT; DATNT; DNTN; HNDFM; HNS; TNAT; TNB; TNBHT; TNX

PL

2,4,6-trinitrotoluen (TNT); synteza; cyjano-2,4,6-trinitrobenzen; 1,3,5-trinitro-2-(nitrometylo) benzen; nitro-metylo-difenyloamina; ATNT; BTNHT; DATNT; DNTN; HNDFM; HNS; TNAT; TNB; TNBHT; TNX

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Materiały Wysokoenergetyczne
• Rocznik: 2020
• Tom: T. 12(1)
• Strony: 90--110
• Opis fizyczny: Bibliogr. 126 poz., rys., tab.

Twórcy

autor

Szala Mateusz

• Military University of Technology, Faculty of Advanced Technologies and Chemistry, Laboratory of Explosives, 2 gen. S. Kaliskiego Street, 00-908 Warsaw, Poland

autor

Sałaciński Tomasz

• Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, 6 Annopol Street, 03-236 Warsaw, Poland

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Artykuł został pierwotnie opublikowany w jęz. polskim w Materiały Wysokoenergetyczne 2015, 7: 125-143.