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The ecological risk of contamination with toxic metals in soils around the Trepça complex, the Kosovo thermal power plants, and a New Co Ferronickeli complex

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Języki publikacji
EN
Abstrakty
EN
Toxic waste, soil, and ash samples were collected in the landfill (solid environmental hot spots) near the Trepça complex, New Co Ferronickeli, and Kosovo thermal power plants. They were analyzed by the ICP-OES method to measure the concentration of some toxic metals. The pollutant with the highest mean concentration (in an acidic medium) was Fe (36 400.0), followed by Mn (8683.0), Cr (6575.0), As (4739.0), Pb (3364.0), Zn (2394.0), Ni (922.6), Cu (297.6), Co (46.6), and Cd (61.8) (all concentrations in mg/kg). Three pollution indices were used such as the geoaccumulation index (Igeo), contamination factor (CFi), and pollution load index (PLI). The CFi values determined for Fe, Mn, Cr, As, Pb, Zn, Ni, Cu, Co, and Cd indicated high contamination. In all soil samples, the PLI values showed the presence of soil pollution.
Rocznik
Strony
5--17
Opis fizyczny
Bibliogr. 28 poz., rys., tab.
Twórcy
autor
  • University of Pristina, "Hasan Prishtina", Faculty of Mathematical Natural Sciences, Department of Chemistry, Pristine, Kosovo
  • University of Pristina, "Hasan Prishtina", Faculty of Education, Pristine, Kosovo
  • University of Pristina, "Hasan Prishtina", Faculty of Mathematical Natural Sciences, Department of Chemistry, Pristine, Kosovo
autor
  • University of Pristina, "Hasan Prishtina", Faculty of Mathematical Natural Sciences, Department of Chemistry, Pristine, Kosovo
  • University of Tirana, Faculty of History and Philology, Department of Geography, Tirana, Albania
  • University of Pristina, "Hasan Prishtina", Faculty of Mathematical Natural Sciences, Department of Chemistry, Pristine, Kosovo
Bibliografia
  • [1] DEMAKU S., Assessment of the heavy metals present in the water, soil and landfill of the Drenicë River – nearby the industrial by Complex Ferronickel, Int. J. Ecosyst. Ecol. Sci., 2020, 10 (1), 137–144. DOI: 10.31407/ijees10.118.
  • [2] BAJRAKTARI N., MORINAI I., DEMAKU S., Assessing the presence of heavy metals in the area of Glloogoc (Kosovo) by using Mosses as a bioindicator for heavy metals, 2019, J. Ecol. Eng., 20 (6), 135–140. DOI: 10.12911/22998993/108639.
  • [3] SHALA A., GASHI B., HYSENI S. M., BYTYÇI P., DRESHAJ A., Analysis of the impact of Ferronickel industrial activity on Drenicë River quality, J. Ecol. Eng., 2022, 23 (7), 312–322. DOI: 10.12911/22998993/150184.
  • [4] DEMAKU S., KASTRATI G., HALILI J., Assessment of contamination with heavy metals in the environment. Water, sediment and soil around Kosovo power plants, Environ. Prot. Eng., 2022, 48 (2), 15–27. DOI: 10.37190/epe220202.
  • [5] DEMAKU S., BAJRAKTARI N., Physicochemical analysis of the water wells in the area of Kosovo Energetic Corporation (Obilic, Kosovo), J. Ecol. Eng., 2019., 20 (7), 155–160. DOI: 10.12911/22998993/109874.
  • [6] Energy Strategy of the Republic of Kosovo for the period 2009–2018, Ministry of Energy and Mining, Pristine, 2009.
  • [7] Energy Strategy of the Republic of Kosovo 2017–2026, Ministry of Economic Development, Pristine, 2017.
  • [8] RADOMIROVIĆ M., ĆIROVIĆ Ž., MAKSIN D., BAKIĆ T., LUKIĆ J., STANKOVIĆ S., ONJIA A., Ecological risk assessment of heavy metals in the soil at a former painting industry facility, Front. Environ. Sci., 2020, 8, 560415. DOI: 10.3389/fenvs.2020.560415.
  • [9] HYSENI A., MUZAQI M., DURMISHAJ B., HYSENI S., Metal losses at the Trepça concentrator during the enrichment process, Min. Miner. Depos., 2022, 16 (4), 132–137. DOI: 10.33271/mining16.04.132.
  • [10] GASHI F., FRANQISHKOVIQ-BILINSKI S., BILINSKI H., THAQI B., SHOSHOLLI S.H., Chemical determination of heavy metals in Pb-Zn concentrates of Trepça (Kosovo) and correlations coefficients study between chemical data, Min. Geol. Petrol. Eng. Bull., 2017, 32 (2), 29–35. DOI: 10.17794/rgn.2017.2.4.
  • [11] FERAND J., DESCHAMPS Y., French scientific cooperation 2007–2008 on the Trepça lead-zinc-silver mine and the gold potential of Novo Brdo/Artana tailing (Kosovo), Unit 4, pp. 41–46, and Unit 5, pp. 47–52, 2009.
  • [12] NRIAGU J.O., PACYNA J.M., Quantitative assessment of worldwide contamination of air, water and soils by trace metals, Nature, 1988, 333 (6169), 134–139. DOI: 10.1038/333134a0.
  • [13] US EPA, Method 6010C (SW-846). Inductively Coupled Plasma-Atomic Emission Spectrometry, Rev. 3, 2007.
  • [14] US EPA, Method 3051A (SW-846). Microwave assisted acid digestion of sediments, sludges, and oils, Rev. 1, 2007.
  • [15] LU S., TENG Y., WANG Y., WU J., WANG J., Research on the ecological risk of heavy metals in the soil around a Pb-Zn mine in the Huize County, China, Chin. J. Geochem., 2015, 34, 540–549. DOI: 10.1007/s11631-015-0062-6.
  • [16] CANBAY H.S., DOĞANTÜRK M., Metals determination by microwave digestion ICP-OES of some dietary supplements and diet products in Turkey, Eur. J. Anal. Chem., 2017, 12 (1), 45–53. DOI: 10.12973/ejac. 2017.00143a.
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  • [18] ABRAHIM G.M.S., PARKER R.J., Assessment of heavy metal enrichment factors and the degree of contamination in marine sediments from Tamaki estuary, Auckland, New Zealand, Environ. Monit. Assess., 2008, 136 (1–3), 227–238. DOI: 10.1007/s10661-007-9678-2.
  • [19] TOMLINSON D.L., WILSON J.G., HARRIS C.R., JEFFREY D.W., Problems in the assessment of heavy metal levels in estuaries and the formation of a pollution index, Helg. Meer., 1980, 33, 566–575. DOI: 10.1007/BF02414780.
  • [20] ENNAJI W., BARAKAT A., EL BAGHDADI M., RAIS J., Heavy metal contamination in agricultural soil and ecological risk assessment in the northeast area of Tadla plain, Morocco, J. Sediment. Environ., 2020, 5 (3), 307–320. DOI: 10.1007/s43217-020-00020-9.
  • [21] BAS ISO 11047:2000, Soil quality. Determination of cadmium, chromium, cobalt, copper, lead, manganese, nickel and zinc in aqua regia extracts of soil. Flame and electrothermal atomic absorption spectrometric methods, 2000.
  • [22] MULLER G., Index of geoaccumulation in sediments of the Rhine River, Geo. J., 1969, 2, 108.
  • [23] TAHRI M., BENYAICH F., BOUNAKHLA M., BILAL E., GRUFFAT J.-J., MOUTTE J., GARCIA D., Multivariate analysis of heavy metal contents in soils, sediments and water in the region of Meknes (Central Morocco), Environ. Monit. Assess., 2005, 102, 405–417. DOI: 10.1007/s10661-005-6572-7.
  • [24] Soil Quality – Urban Technical Note No. 3, Heavy Metal Soil Contamination, September 2000, https://semspub.epa.gov/work/03/2227185.pdf
  • [25] KABATA-PENDIAS A., PENDIAS H., Trace Elements in Soils and Plants, CRC Press, New York 2001.
  • [26] LU S., TENG Y., WANG Y., WU J., WANG J., Research on the ecological risk of heavy metals in the soil around a Pb-Zn mine in the Huize County, China, Chin. J. Geochem., 2015, 34 (4), 540–549. DOI: 10.1007/s11631-015-0062-6.
  • [27] Dutch Target and Intervention Values (the New Dutch List), Annexes Circular on Target Values and Intervention Values for Soil Remediation, 4th Ed., February 2000.
  • [28] U.S. EPA, Supplemental guidance for developing soil screening levels for superfund sites, Office of Solid Waste and Emergency Response, Washington D.C., 2002, available: http://www.epa.gov/super-fund/health/conmedia/soil/index.htm
Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e8c2594d-b78e-4848-b074-228d0265b90b
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