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The physical properties of pure CuO and Pb doped CuO thin films, deposited on glass substrates by a sol-gel method, were investigated. Structural analysis revealed the polycrystalline nature of the pure CuO and Pb:CuO composite films with a monoclinic structure, the crystallite size decreased and ranged from 36.78 nm to around 21.5 nm. The SEM images of the CuO thin films showed that the Pb doping concentration affects the surface morphology of the Pb:CuO composites. The absorbance of the Pb:CuO composites is higher than that of the undoped CuO thin films. The optical band gap energies of undoped CuO and Pb doped CuO thin films were estimated to 1.9 (pure), 2.17(5%) and 2.74 (7%)eV, and found that the band gap energy (Eg) increases with the Pb concentration. This blue shift is due to the quantum confinement induced by the reduction in the size of the crystallites.
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Czasopismo
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Strony
5--13
Opis fizyczny
Bibliogr. 23 poz., rys., tab., wykr.
Twórcy
autor
- Laboratory of Materials and Sustainable Development, University of Bouira, Faculty of Sciences and Applied Sciences, Department of Physics, Bouira, Algeria
autor
- Laboratory of Materials and Sustainable Development, University of Bouira, Faculty of Sciences and Applied Sciences, Department of Physics, Bouira, Algeria
autor
- Laboratory of Materials and Sustainable Development, University of Bouira, Faculty of Sciences and Applied Sciences, Department of Physics, Bouira, Algeria
autor
- Nuclear Research Centre of Birine, Algeria
Bibliografia
- 1. Chang H., Kao M.-J., Cho K.-C., Chen S.-L., Chu K.-H., Chen C.-C., Integration of CuO thin films and dye sensitized solar cells for thermoelectric generators, Current Applied Physics, vol 11 issue 4 (2011) pp. 19-22.
- 2. Liu L., Hong K., Ge X., Xu M., Aligned CuO nanorod arrays: fabrication and anisotropic ferromagnetism, Journal of Applied Physics, vol 115 issue 4 (2014) pp. 1147–1150.
- 3. Li R., Du J., Luan Y., Xue Y., Zou H., Zhuang G., Li Z., Ionic liquid precursor-based synthesis of CuO nanoplates for gas sensing and amperometric sensing applications, Sensors and Actuators B, vol 65 (2012) pp.156-164.
- 4. Jindal K., Tomar M., Gupta V., CuO thin film based uric acid biosensor with enhanced response characteristics, Biosensors and Bioelectronics, vol 38 issue 1 (2012) pp. 11-18.
- 5. Inamdar S.M., More V.K., Mandal S.K., CuO nano-particles supported on silica, a new catalyst for facile synthesis of benzimidazoles, benzothiazoles and benzoxazoles, Tetrahedron Letters, vol 54 issue 6 (2013) pp. 579-583.
- 6. Yin Z., Ding Y., Zheng Q., Guan L., CuO/polypyrrole core–shell nanocomposites as anode materials for lithium-ion batteries, Electrochemistry Communications, vol 20 (2012) pp. 40-43.
- 7. Chen A., Long H., Li X., Li Y., Yang G., Lu P., Controlled growth and characteristics of single-phase Cu2O and CuO films by pulsed laser deposition, Vacuum, vol 83 issue 6 (2009) pp. 927-930.
- 8. Gao F., Liu X.J., Zhang J.S., Song M.Z., and Li N., J., Photovoltaic properties of the p-CuO/n-Si heterojunction prepared through reactive magnetron sputtering, Journal of Applied Physics, vol 111 (2012) pp. 084507.
- 9. Bayansal F., Çetinkara H.A., Kahraman S., Çakmak H.M., GüderH.S., Nanostructured CuO films prepared by simple solution methods: plate-like, needle like and network-like architectures, Ceramics International, vol 38 issue 3 (2012) pp. 1859-1866.
- 10. Saravanan V., Shankar P., Mani G.K., Rayappan J.B.B., Growth and characterization of spray pyrolysis deposited copper oxide thin films: Influence of substrate and annealing temperatures, Journal of Analytical and Applied Pyrolysis, vol 111 (2015) pp. 272-277.
- 11. Kaur M., Muthe K.P., Despande S.K., Choudhury S., Singh J.B., Verma N., Gupta S.K.,Yakhmi J.V., Growth and Branching of CuO Nanowires by Thermal Oxidation of Copper, Journal of Crystal Growth, vol 289 issue 2 (2006) pp. 670-675.
- 12. Stamataki M., Mylonas D., Tsamakis D., Kompitsas M., Tsakiridis P., Christoforou E., Christoforou, CO-sensing properties of CuxO-based nanostructured thin films grown by reactive pulsed laser deposition, Sensor Letters, vol 11 issue 12 (2013) pp. 1964-1967.
- 13. Mukherjee N., Show B., Maji S.K., Madhu U., Bhar S.K., Mitra B.C., Khan G.G., Mondal A.,CuOnano-whiskers: electrodeposition, Raman analysis, photoluminescence study and photocatalytic activity, Materials Letters, vol 65 issue 21-22 (2011) pp. 3248-3250.
- 14. Muthe K.P., Vyas J.C., Narang S.N., Aswal D.K., Gupta S.K., Bhattacharya D., Pinto R., Kothiyal G.P., Sabharwal S.C., A study of the CuO phase formation during thin film deposition by molecular beam epitaxy, Thin Solid Films, vol 324 issue 1-2 (1998) pp. 37-43.
- 15. Oral A.Y., Mensur E., Aslan M.H., Basaran E., The preparation of copper (II) oxide thin films and the study of their microstructures and optical properties, Materials Chemistry and Physics, vol 83 issue 1 (2004) pp. 140-144.
- 16. Mehdi D., Mohamed J., Imen S., Islem B., George M., Michael K., Wissem D., Physical properties of copper oxide thin films prepared by sol–gel spin–coating method, American Journal of Physics and Applications, vol 6 no. 2 (2018) pp. 43-50.
- 17. Touka N., Tabli D., Badari K., Effect of annealing temperature on structural and optical properties of copper oxide thin films deposited by sol-gel spin coating method, Journal of Optoelectronics and Advanced Materials, vol 21 issue 12 (2019) pp. 698-701.
- 18. Klug H.P., Alexander L.E., X-ray diffraction procedures for polycristalline and amorphous materials, Wiley, New York, second edition, 618 (1974).
- 19. Dastan D., Panahi S.L., Chaure N.B., Characterization of titania thin films grown by dip-coating technique. Journal of Materials Science: Materials in Electronics, vol 27 issue 12 (2016) pp. 12291-12296.
- 20. Malek M.F., Mamat M.H., Sahdan M.Z., Zahidi M.M., Khusaimi Z., Mahmood M.R., Influence of various sol concentrations on stress/strain and properties of ZnO thin films synthesised by sol–gel technique, Thin Solid Films, vol 527 (2013) 102–109.
- 21. Dastan D., Effect of preparation methods on the properties of titania nanoparticles: solvothermal versus sol–gel, Applied Physics A, vol 123 issue 11 (2017) pp. 1-13.
- 22. Breiby, D. W., Lemke, H. T., Hammershøj, P., Andreasen, J. W., Nielsen, M. M., X-ray diffraction study of directionally grown perylene crystallites, The Journal of Physical Chemistry C, vol 112 issue 12 (2008) pp. 4569-4572.
- 23. Jundale D., Pawar S., Chougule M., Godse P., Patil S., Raut B., Sen S., Patil V., Nanocrystalline CuO Thin Films for H2S Monitoring: microstructural and optoelectronic characterization, Journal of Sensor Technology, vol 1 issue 2 (2011) pp. 34-36.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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