Sodium metasilicate-MgO blend catalyst for producing mono and diacylglycerol from palm kernel oil using high shear compartment reactor

• Autorzy: Affandi Arief Rakhman , Millati Ria , Hidayat Chusnul

Identyfikatory

DOI

10.2478/pjct-2024-0035

• Języki publikacji: EN

Abstrakty

EN

Sodium metasilicate (SMS) tended to agglomerate during glycerolysis reactions in high shear compartment reactors (HSCR), hindering triacylglycerol (TAG) conversion. Therefore, the aim was to evaluate the SMS-magnesium oxide (MgO) blend as a heterogeneous catalyst for glycerolysis reactions. Various SMS-MgO ratios (ranging from 2.5:1 to 10.0:1) were evaluated. The results demonstrated that increasing MgO in the blend reduced catalyst basicity and minimized O-Si-O groups and catalyst crystallinity, preventing clumping and increasing catalyst surface area. The SMS-MgO 5.0:1 blend exhibited the smallest pore size (<2 nm) with a surface area of 4.22 m² . g^–1 and basicity of 11.59 ± 0.115 mmol . g^–1. This blend achieved the highest TAG conversion of 53.98%, with a MAG content of 16.86 ± 0.528% when it was performed at 120 °C with an agitator speed of 2,000 rpm for 6 h. Thus, the SMS-MgO 5.0:1 blend shows promise as a heterogeneous catalyst in glycerolysis reaction in HSCR, hindering agglomeration and enhancing surface area.

Słowa kluczowe

EN

basicity; catalyst agglomeration; glycerolysis; high shear compartment reactor; (HSCR); MgO-sodium metasilicate blend

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2024
• Tom: Vol. 26, nr 4
• Strony: 17--24
• Opis fizyczny: Bibliogr. 49 poz., rys., tab., wz.

Twórcy

autor

Affandi Arief Rakhman

• Department of Food and Agricultural Product Technology, Faculty of Agricultural Technology Universitas Gadjah Mada, Jl. Flora No 1 Bulaksumur, Yogyakarta, Indonesia
• Department of Food Technology, Universitas PGRI Semarang, Jl. Sidodadi Timur No. 24 Semarang, Indonesia

autor

Millati Ria

• Department of Food and Agricultural Product Technology, Faculty of Agricultural Technology Universitas Gadjah Mada, Jl. Flora No 1 Bulaksumur, Yogyakarta, Indonesia

autor

Hidayat Chusnul

• Department of Food and Agricultural Product Technology, Faculty of Agricultural Technology Universitas Gadjah Mada, Jl. Flora No 1 Bulaksumur, Yogyakarta, Indonesia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki (2025).