PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Emulsion polymerization of thiophene – the new way of conducting polymers synthesis

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The aim of this study was to investigate the new method of polythiophene polymerization. It was made an attempt of the chemical oxidation of thiophene in aqueous medium without the addition of any surfactant. The oxidative compound applied in the synthesis was gaseous ozone. Resulting polymer was obtained in the form of nano-spheres dispersed in water. The method developed in this study allow to obtain the polythiophene nanoparticles. Further study is required to fully identify the resulting product properties in comparison with polymer obtained in other methods.
Słowa kluczowe
Twórcy
autor
  • Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 78-100 Toruń, Poland
autor
  • Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 78-100 Toruń, Poland
  • Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 78-100 Toruń, Poland
Bibliografia
  • 1. Yamamoto T., Sanechika K., Yamamoto A.: Preparation of thermostable and electric-conducting poly(2,5-thienylene). J. Polym. Sci. B Polym. Lett. Ed., 18, 1980, 9–12.
  • 2. Lin J.W.-P., Dudek L.P.: Synthesis and properties of poly(2,5-thienylene). J. Polym. Sci. Polym. Chem. Ed., 18, 1980, 2869–2873.
  • 3. Skotheim T.A., Reynolds J. (Eds): Conjugated polymers: processing and applications. Handbook of Conducting Polymers. Boca Raton, FL, CRC Press 2007.
  • 4. Ocampo C., Armelin E., Liesa F., Alemán C., Ramis X., Iribarren J.I.: Application of a polythiophene derivative as anticorrosive additive for paints. Progress in Organic Coatings, 53, 3, 2005, 217–224.
  • 5. Diaz A.F., Crowley J., Bargon J., Gardini G.P., Tor¬rance J. B.: Electrooxidation of aromatic oligomers and conducting polymers. Journal of Electroanalytical Chemistry, 121, 1981, 355–361.
  • 6. Sugimoto R., Takeda S., et al.: Preparation of soluble polythiophene derivatives utilizing transition metal halides as catalysts and their property. Chemistry Express, 1, 11, 1986, 635–638.
  • 7. Fall M., Diagne A.A., Dieng M.M., Deflorian F., Rossi S., Bonora P.L., Della Volpe C., Aaron J.-J.: Electrochemical impedance spectroscopy of poly(3- methoxythiophene) thin films in aqueous LiClO4 solutions. Synthetic Metals, 155, 3, 2005, 569–575.
  • 8. Fall M., Aaron J.J., Sakmeche N., Dieng M.M., Jouini M., Aeiyach S., Lacroix J.C., Lacaze P.C.: Electrochemical and spectroscopic properties of poly(3-methoxythiophene) electrosynthesized in an aqueous micellar medium. Synthetic Metals, 93, 3, 1997, 175–179,
  • 9. Buehler R. E., Staehelin J., Hoigne J.: Ozone decomposition in water studied by pulse radiolysis. 1. Perhydroxyl (HO2)/hyperoxide (O2-) and HO3/ O3- as intermediates. J. Phys. Chem., 88, 12, 1984, 2560–2564.
  • 10. Wang Y., Chen K., Li T., Li H., Zeng R., Zhang R., Gu Y., Ding J., Liu H.: Soluble polyaniline nanofibers prepared via surfactant-free emulsion polymerization. Synthetic Metals, 198, 2014, 293–299.
  • 11. Kane M., Krafcik K.: Nanostructured soluble conducting polyaniline produced by emulsion polym¬erization. Synthetic Metals, 181, 2013, 129–135.
  • 12. Oriakhi C.O., Lerner M.M.: Poly(pyrrole) and poly(thiophene)/claynanocomposites via latex-colloid interaction. Materials Research Bulletin 30, 6, 1995, 723–729.
  • 13. Suryawanshi A.J., et al.: Advances in Science and Technology, 79, 2012, 7.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e837cc7f-64ca-4803-9408-84c116510457
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.