Synthesis and Characterization of Four Energetic Transition Metal Complexes of 3,4-Diamino-1,2,4-triazole

• Autorzy: Yin X. , Jin X. , Xu C.-X. , He P. , Wang K. , Zhang J.-G.
• Języki publikacji: EN

Abstrakty

EN

Four complexes with the formula of [M5(DATr)12~14(H2O)6](ClO4)10 (M = Mn (1), Co (2), Ni (3), Zn (4)) about their synthesis, structures and some energetic properties (such as sensitivities tests) have been described, where the DATr here denotes 3,4-diamino-1,2,4-triazole. These four compounds are all light metallic complexes with good thermal stability. The structures of 2-4 were determined by single-crystal X-ray diffraction, and the crystal structures mainly consist of penta-nuclear units. All the structures have a common interesting property in which DATr plays a role of bi-dentate ligand. Besides, it is observed from the crystal structure of 4 that DATr can be also act as a mono-dentate ligand. Thermodynamic studies of their decomposition properties and kinetic parameters show that the four complexes have high thermal stabilities. Furthermore, tests of their impact and friction sensitivities show that complexes (2) and (3) can be potential candidates as primary explosives to replace toxic lead azide.

Słowa kluczowe

EN

3,4-diamino-1,2,4-triazole; theoretic study; crystal structure; thermal stability; sensitivity

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2016
• Tom: Vol. 13, no. 2
• Strony: 301--320
• Opis fizyczny: Bibliogr. 23 poz., rys., tab.

Twórcy

autor

Yin X.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, P. R. China

autor

Jin X.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, P. R. China

autor

Xu C.-X.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, P. R. China

autor

He P.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, P. R. China

autor

Wang K.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, P. R. China

autor

Zhang J.-G.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, P. R. China

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.