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Effect of plasma nitrided layers on low-alloy steel on its hydrogen degradation

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: Purpose of this paper is evaluation of susceptibility to hydrogen degradation of structural low-alloy steel, plasma nitrided in the atmosphere with various contents of N2 and H2. Design/methodology/approach: Susceptibility of 34CrAlNi7-10 steel and samples with various plasma nitrided layers have been evaluated under monotonically increasing load in 0.005 M H2SO4 solution. Slow-strain rate tensile test (SSRT) test was carried out under cathodic polarisation. Elongation, reduction in area, fracture energy and tensile strength were chosen as measures of susceptibility to hydrogen embrittlement. Fracture modes of failed samples were examined with the use of scanning electron microscope (SEM). Findings: All tested samples revealed susceptibility to hydrogen degradation under hydrogenation. Samples with nitrided layer have lower lost of reduction in are than base metal samples. The nitrided layer established in standard atmosphere 30% H2 and 70% N2 has the highest resistance to hydrogen degradation. Research limitations/implications: Further research should be taken to reveal the exact mechanism of increased plasticity of nitided layer with absorbed hydrogen. Practical implications: Plasma nitriding may prevent hydrogen charging of machines and vehicles parts in hydrogen generating environments, and thus decreasing susceptibility to hydrogen embrittlement. Originality/value: Under the increasing load and hydrogen generating environments plasma nitrided layers are effective barriers to hydrogen entry into a bulk of steel, and additionally increased plasticity of nitrided layers with absorbed hydrogen was observed.
Rocznik
Strony
213--216
Opis fizyczny
Bibliogr. 15 poz., rys., tab.
Twórcy
  • Faculty of Mechanical Engineering, Gdańsk University of Technology, ul. Narutowicza 11/12, 80-952 Gdańsk, Poland
autor
  • Faculty of Mechanical Engineering, Gdańsk University of Technology, ul. Narutowicza 11/12, 80-952 Gdańsk, Poland
  • Faculty of Mechanical Engineering, Gdańsk University of Technology, ul. Narutowicza 11/12, 80-952 Gdańsk, Poland
Bibliografia
  • [1] ASM Handbook. Vol. 11 Failure Analysis and Prevention, ASM Int., 1986.
  • [2] P.F. Timmins, Solutions to hydrogen attack in steels, AMS Int., 1997.
  • [3] N. Eliaz, A. Shachar, B. Tal, D. Eliezer, Characteristic of hydrogen embrittlement, stress corrosion cracking and tempered martensite embrittlement in high-strength steels, Engineering Failure Analysis 9 (2002) 176-184.
  • [4] M. Śmiałowski, Hydrogen in steels, Pergamon Press, Oxford, 1962.
  • [5] R.A. Oriani, J.P. Hirth, M. Smialowski (eds.), Hydrogen degradation of ferrous alloys, Noyes Publ. Park, Ridge, USA, 1985.
  • [6] H.K. Birnbaum, Mechanisms of hydrogen-related fracture of metals. Proc. Int. Conf. „Environment-Induced Cracking of Metals”, National Association of Corrosion Engineers, Houston, Texas, USA, 1988, 21-29.
  • [7] S.P. Lynch, Failures of structures and components by environmentally assisted cracking, Engineering Failure Analysis, 2 (1994) 77-90.
  • [8] A. Zieliński, E. Łunarska, P. Michalak, W, Serbiński, Strength degradation of 26H2MF and 34HNM steels used in ship engines: hydrogen factor, Materials Science, 6 (2004) 822-830.
  • [9] T. Zakroczymski, N. Łukomski, J. Flis, The effect of plasma nitriding-base treatments on the absorption of hydrogen by iron, Corrosion Science, 37 (1995) 811-822.
  • [10] P. Kula, The comparision of resistance to “hydrogen wear” of hardened surface layers, Wear, 178 (1994) 117-121.
  • [11] P. Kula, The “self-lubrication” by hydrogen during dry friction of hardened surface layers, Wear, 201 (1996) 155-162.
  • [12] PN-EN 10085:2003 Nitriding steels – Technical delivery conditions.
  • [13] PN-EN 6507-1: 1999. Metallic materials. Vickers hardness test – Part 1: Test method.
  • [14] PN-EN ISO 7539-7:2000 Corrosion of metals and alloys – Stress corrosion testing – Part 7: Slow strain rate testing.
  • [15] PN-EN ISO 7539-4:2000 Corrosion of metals and alloys – Stress corrosion testing – Part 4: Preparation and use of uniaxially loaded tensions specimens.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e72ac3be-286a-4d4d-b5bb-13b6b6f2b7f3
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