High Temperature Isothermal Oxidation at 950°C of Ni-based Fe-40Ni-24Cr Alloy

• Autorzy: Anuar Aqmar Ikhmal , Parimin Noraziana , Ahad Nor Azwin , Derman Mohd Nazree , Garus Sebastian , Vizureanu Petrica

Identyfikatory

DOI

https://doi.org/10.24425/amm.2024.150942

• Języki publikacji: EN

Abstrakty

EN

The effect of different heat treatment temperatures on the isothermal oxidation of Ni-based Fe-40Ni-24Cr alloy was studied. The alloy underwent a heat treatment process at 1000°C and 1200°C for 3 hours of soaking time, followed by water quenching. These samples are labeled as N10 and N12. The heat-treated samples were characterized in terms of grain size using an optical microscope and hardness testing using a Rockwell hardness. As a result, increasing the heat treatment temperature increases the average grain size of the alloy and lowers the hardness value. Heat-treated N10 and N12 samples were subjected to an isothermal oxidation test at 950°C for an exposure time of 150 h. Oxidized heat-treated samples were characterized in terms of oxidation kinetics calculated based on weight change per surface area as a function of time. In addition, phase analysis and oxide surface morphology were measured using x-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques. As a result, the oxidation kinetics of both samples showed a pattern of weight gain with N10 recording the lowest weight gain. Both samples obey a parabolic rate law, indicating a controlled oxide growth rate. N10 recorded the lowest parabolic rate constant of 2.5×10^-8 mg²cm^-4s^-1, indicating a low oxidation rate, thus having good oxidation resistance. Phase analysis using XRD shows that several oxide phases have been formed consisting of Cr-containing oxides Cr₂O₃ and MnCr₂O₄. In addition, SEM analysis displayed a uniform oxide layer formed on the N10 sample, indicating good oxide adhesion. This finding shows an important contribution to the oxidation protection mechanism that records the fine grain obtained from the heat treatment process can increase good oxidation resistance.

Słowa kluczowe

EN

Ni-based Fe-Ni-Cr alloys; Haynes HR-120 alloys; isothermal oxidation; heat treatment; oxidation kinetics

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2024
• Tom: Vol. 69, iss. 3
• Strony: 1191--1198
• Opis fizyczny: Bibliogr. 23 poz., fot., rys., tab.

Twórcy

autor

Anuar Aqmar Ikhmal

• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering & Technology, 02600 Arau, Perlis, Malaysia

• https://orcid.org/0009-0001-2740-3884

autor

Parimin Noraziana

• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering & Technology, 02600 Arau, Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering & Technology, Surface Technology Special Interest Group, 02600 Arau, Perlis, Malaysia

• https://orcid.org/0000-0003-2069-7207

autor

Ahad Nor Azwin

• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering & Technology, 02600 Arau, Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering & Technology, Surface Technology Special Interest Group, 02600 Arau, Perlis, Malaysia

• https://orcid.org/0009-0002-5157-7216

autor

Derman Mohd Nazree

• Universiti Malaysia Perlis (UniMAP), Faculty of Mechanical Engineering & Technology, 02600 Arau, Perlis, Malaysia

• https://orcid.org/0000-0002-8564-7326

autor

Garus Sebastian

• Czestochowa University of Technology, Faculty of Mechanical Engineering and Computer Science, 42-201 Częstochowa, Poland

• https://orcid.org/0000-0002-6649-5435

autor

Vizureanu Petrica

• Gheorghe Asachi Technical University of Iasi, Faculty of Material Science and Engineering, 41 D. Mangeron St., 700050 Iasi, Romania

• https://orcid.org/0000-0002-3593-9400

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Uwagi

This research was funded by the Ministry of Higher Education Malaysia under the Fundamental Research Grant Scheme (FRGS) FRGS/1/2020/TK0/UNIMA)/02/43.