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Effect of chromium doping on the structure and mechanical properties of anti‑wear TiB2 coatings

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Języki publikacji
EN
Abstrakty
EN
TiB2-based coatings have been intensively developed due to their physical and mechanical properties, including excellent thermal stability and high hardness with good abrasion and corrosion resistance, which appear to be the most beneficial in industrial application. Previous investigations have shown that doping TiB2 with W, Ni and C can significantly reduce residual stresses and improve adhesion, making these coatings ideal on tools to machining aluminum alloys. The aim of this study was to analyze the effect of an Cr interlayer on the durability (adhesion) of the fabricated Ti1−xCrxB2 (x = 0; 0.03; 0.06; 0.10) films and determine the influence of Cr on their microstructure and mechanical properties. The structural characterization of Ti1−xCrxB2 coatings was carried out using X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy and atomic force microscopy. To investigate the mechanical properties, nano-scratch and-hardness tests (NST, NHT) were performed, and fracture toughness of the substrate layer systems was determined. The use of an adhesive layer of pure Cr increased the adhesion of the coatings to the substrate. It is shown that the changes in Cr content not only affect the microstructure, mainly by decreasing the crystallite size (column width), but also the texture (preferred film orientation) and phase composition. The addition of chromium also has an effect on the mechanical properties of TiB2 films by reducing their hardness and Young’s modulus and increasing their fracture toughness (KIC).
Słowa kluczowe
Rocznik
Strony
art. no. e80, 2023
Opis fizyczny
Bibliogr. 36 poz., rys., tab., wykr.
Twórcy
  • Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, al. A. Mickiewicza 30, 30‑059 Krakow, Poland
  • Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, al. A. Mickiewicza 30, 30‑059 Krakow, Poland
  • Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, al. A. Mickiewicza 30, 30‑059 Krakow, Poland
  • Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, al. A. Mickiewicza 30, 30‑059 Krakow, Poland
autor
  • Łukasiewicz Research Network-Institute for Sustainable Technologies, K. Pułaskiego St. 6/10, 26‑600 Radom, Poland
Bibliografia
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  • 7. Smolik J, Mazurkiewicz A, Garbacz H, Kopia A. Tungsten doped TiB2 coatings obtained by magnetron sputtering. J Mach Constr Maint. 2018;4:27-32.
  • 8. Lubas J. Assessment and application of TiB2 coating in sliding pair under lubrication conditions. Wear. 2012;296:504-9. https://doi.org/10.1016/j.wear.2012.08.005.
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  • 10. Panich N, Wangyao P, Visuttipitukul P, Sricharoenchai P, Sun Y. Improvement in adhesion of sputtered TiB2 nano-compostite coatings onto high speed steel by a chromium interlayer. Mater Trans. 2008;49:2331-4. https://doi.org/10.2320/matertrans.MRA2008107.
  • 11. Ye Y, Liu Z, Liu W, Zhang D, Wang Y, Zhao H, Li X. Effect of interlayer design on friction and wear behaviors of CrAlSiN coating under high load in seawater. RSC Adv. 2018;8:5596-607. https://doi.org/10.1039/C7RA12409K.
  • 12. Akhter R, Zhou Z, Xie Z, Munroe P. Enhancing the adhesion strength and wear resistance of nanostructured NiCrN coatings. Appl Surf Sci. 2021;541:148533. https://doi.org/10.1016/j.apsusc.2020.148533.
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  • 23. Panich N, Sun Y. Effect of substrate rotation on structure, hardness and adhesion of magnetron sputtered TiB2 coating on high speed steel. Thin Solid Films. 2006;500:190-6. https://doi.org/10.1016/j.tsf.2005.11.055.
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  • 34. Lofaj F, Moskalewicz T, Cempura G, Mikula M, Dusza J, Czyrska-Filemonowicz A. Nanohardness and tribological properties of nc-TiB2 coatings. J Eur Ceram Soc. 2013;33:2347-53. https://doi.org/10.1016/j.jeurceramsoc.2013.02.024.
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  • 36. Chen X, Du Y, Chung YW. Commentary on using H/E and H3/E2 as proxies for fracture toughness of hard coatings. Thin Solid Films. 2019;688:137265. https://doi.org/10.1016/j.tsf.2019.04.040.
Uwagi
PL
Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e5c7c51c-6edf-4147-8111-7d84ef71a3af
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