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Abstrakty
TiB2-based coatings have been intensively developed due to their physical and mechanical properties, including excellent thermal stability and high hardness with good abrasion and corrosion resistance, which appear to be the most beneficial in industrial application. Previous investigations have shown that doping TiB2 with W, Ni and C can significantly reduce residual stresses and improve adhesion, making these coatings ideal on tools to machining aluminum alloys. The aim of this study was to analyze the effect of an Cr interlayer on the durability (adhesion) of the fabricated Ti1−xCrxB2 (x = 0; 0.03; 0.06; 0.10) films and determine the influence of Cr on their microstructure and mechanical properties. The structural characterization of Ti1−xCrxB2 coatings was carried out using X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy and atomic force microscopy. To investigate the mechanical properties, nano-scratch and-hardness tests (NST, NHT) were performed, and fracture toughness of the substrate layer systems was determined. The use of an adhesive layer of pure Cr increased the adhesion of the coatings to the substrate. It is shown that the changes in Cr content not only affect the microstructure, mainly by decreasing the crystallite size (column width), but also the texture (preferred film orientation) and phase composition. The addition of chromium also has an effect on the mechanical properties of TiB2 films by reducing their hardness and Young’s modulus and increasing their fracture toughness (KIC).
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
art. no. e80, 2023
Opis fizyczny
Bibliogr. 36 poz., rys., tab., wykr.
Twórcy
autor
- Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, al. A. Mickiewicza 30, 30‑059 Krakow, Poland
autor
- Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, al. A. Mickiewicza 30, 30‑059 Krakow, Poland
autor
- Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, al. A. Mickiewicza 30, 30‑059 Krakow, Poland
autor
- Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, al. A. Mickiewicza 30, 30‑059 Krakow, Poland
autor
- Łukasiewicz Research Network-Institute for Sustainable Technologies, K. Pułaskiego St. 6/10, 26‑600 Radom, Poland
Bibliografia
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- 3. Vereschaka A, Aksenenko A, Sitnikov N, Migranov M, Shevchenko S, Sotova C, Batako A, Andreev N. Effect of adhesion and tribological properties of modified composite nanostructured multi-layer nitride coatings on WC-Co tools life. Tribol Int. 2018;128:313-27. https://doi.org/10.1016/j.triboint.2018.07.039.
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- 6. Kullmer R, Lugmair C, Figueras A, Bassas J, Stoiber M, Mitterer C. Microstructure, mechanical and tribological properties of PACVD Ti(B, N) and TiB2 coatings. Surf Coat Technol. 2003;1229:174-5. https://doi.org/10.1016/s0257-8972(03)00532-2.
- 7. Smolik J, Mazurkiewicz A, Garbacz H, Kopia A. Tungsten doped TiB2 coatings obtained by magnetron sputtering. J Mach Constr Maint. 2018;4:27-32.
- 8. Lubas J. Assessment and application of TiB2 coating in sliding pair under lubrication conditions. Wear. 2012;296:504-9. https://doi.org/10.1016/j.wear.2012.08.005.
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- 10. Panich N, Wangyao P, Visuttipitukul P, Sricharoenchai P, Sun Y. Improvement in adhesion of sputtered TiB2 nano-compostite coatings onto high speed steel by a chromium interlayer. Mater Trans. 2008;49:2331-4. https://doi.org/10.2320/matertrans.MRA2008107.
- 11. Ye Y, Liu Z, Liu W, Zhang D, Wang Y, Zhao H, Li X. Effect of interlayer design on friction and wear behaviors of CrAlSiN coating under high load in seawater. RSC Adv. 2018;8:5596-607. https://doi.org/10.1039/C7RA12409K.
- 12. Akhter R, Zhou Z, Xie Z, Munroe P. Enhancing the adhesion strength and wear resistance of nanostructured NiCrN coatings. Appl Surf Sci. 2021;541:148533. https://doi.org/10.1016/j.apsusc.2020.148533.
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- 17. Wang H, Wang B, Li S, Xue Q, Huang F. Toughening magnetron sputtered TiB2 coatings by Ni addition. Surf Coat Technol. 2013;232:767-74. https://doi.org/10.1016/j.surfcoat.2013.06.094.
- 18. Contreras E, Galindez Y, Gomez MA. Microstructure, mechanical and tribological properties of TiBC coatings by DC magnetron sputtering onto AISI M2 steel using independent TiB2 and graphite targets. Surf Coat Technol. 2018;350:298-306. https://doi.org/10.1016/j.surfcoat.2018.05.079.
- 19. Chudzik-Poliszak E, Cieniek Ł, Moskalewicz T, Kowalski K, Kopia A, Smolik J. Influence of W addition on microstructure and resistance to brittle cracking of TiB2 coatings deposited by DCMS. Materials. 2021;14:4664. https://doi.org/10.3390/ma14164664.
- 20. Huang X, Sun S, Tu G. Investigation of mechanical properties and oxidation resistance of CVD TiB2 ceramic coating on molybdenum. J Mat Res Tech. 2020;9(1):282-90. https://doi.org/10.1016/j.jmrt.2019.10.056.
- 21. Elders J, Quist PA, Rooswijk B, Voorst JDW, Nieuwkoop J. CO2-laser-induced chemical vapour deposition of TiB2. Surf Coat Technol. 1991;45:105-13. https://doi.org/10.1142/S0218625X1250045X.
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- 23. Panich N, Sun Y. Effect of substrate rotation on structure, hardness and adhesion of magnetron sputtered TiB2 coating on high speed steel. Thin Solid Films. 2006;500:190-6. https://doi.org/10.1016/j.tsf.2005.11.055.
- 24. Kelesoglu E, Mitteter C. Structure and properties of TiB2 based coatings prepared by unbalanced DC magnetron sputtering. Surf Coat Technol. 1998;98:1483-9. https://doi.org/10.1016/S0257-8972(97)00397-6.
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- 27. Burton AW, Ong K, Rea T, Chan I. On the estimation of average crystallite size of zeolites from the Scherrer equation: a critical evaluation of its application to zeolites with one-dimensional pore systems. Microporous Mesoporous Mater. 2009;117:75-90. https://doi.org/10.1016/j.micromeso.2008.06.010.
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- 36. Chen X, Du Y, Chung YW. Commentary on using H/E and H3/E2 as proxies for fracture toughness of hard coatings. Thin Solid Films. 2019;688:137265. https://doi.org/10.1016/j.tsf.2019.04.040.
Uwagi
PL
Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e5c7c51c-6edf-4147-8111-7d84ef71a3af