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Effect and mechanism on the flotation desulfurization of high-sulfur bauxite by using the mixed collector of PYDH

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Języki publikacji
EN
Abstrakty
EN
Desulfurization of high sulfur bauxite is an important issue in Bayer alumina production. In this study, by using two anionic sulphydryl collectors (HX, HD) as mixed collectors (PYDH), the selectivity of flotation separation between pyrite and diaspore was improved, thereby reducing the sulfur content of high sulfur bauxite and ultimately meeting the production requirements of Bayer alumina. The findings showed that under the optimized conditions of 500 g/Mg collector, 150 g/Mg inhibitor, 200 g/Mg activator, 100 g/Mg foaming agent, and a slurry pH of 9, the sulfur content of bauxite can be reduced from 3.35% to 0.33% through one rough selection, one fine selection, and one scavenging flotation. Moreover, the interaction mechanism between mixed collectors and pyrite was studied through scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), Zeta potential analysis, and contact angle testing. SEM-EDS research confirmed that PYDH adsorbed on the surface of pyrite. The contact angle measurement analysis showed that compared to individual collectors, pretreated pyrite with mixed collectors had better hydrophobicity. Zeta potential, FTIR, and XPS results indicated that PYDH selectively adsorbed pyrite through chemical adsorption. The mixed collector PYDH is an effective collector for pyrite in high sulfur bauxite flotation desulfurization.
Rocznik
Strony
art. no. 183812
Opis fizyczny
Bibliogr. 32 poz., rys., tab., wykr.
Twórcy
autor
  • Mining College, Guizhou University, Guiyang 550025, China
autor
  • Guizhou Academy of Sciences, Guiyang 550001, China
  • National & Local Joint Laboratory of Engineering for Effective Utilization of Regional Mineral Resources from Karst Areas, Guiyang 550025, China
  • Guizhou Key Lab of Comprehensive Utilization of Nonmetallic Mineral Resources, Guiyang 550025, China
Bibliografia
  • ABIKENOVA G.K., KOVZALENKO V.A., AMBARNIKOVA G.A., ET AL. 2008. Investigation of the effect and behavior of sulfur compounds on the technological cycle of alumina production. Russ. J. Non-ferrous Metals. 49, 91-96.
  • AWE A.A., SUNDKVIST J.E., SANDSTRÖM Å., 2013. Formation of sulphur oxyanions and their influence on antimony electrowinning from sulphide electrolytes. Minerals Engineering. 53, 39–47.
  • BARBOSA F.M., BERGERMAN M.G., HORTA D.G., ET AL. 2016. Removal of iron-bearing minerals from gibbsitic bauxite by direct froth flotation, Technol. Tecnologia em Metalurgia, Materiais e Mineração. 13(1), 106-112.
  • BLIGHT K., RALPU D.E., THURGATE S. 2000. Pyrite surfaces after bio-leaching: a mechanism for bio-oxidation. Hydrometallurgy. 58(3), 227-237.
  • BULUT G., ARSLAN F., ATAK S., ET AL. 2004. Flotation behaviors of pyrites with different chemical compositions. Mining, Metallurgy & Exploration. 21, 86-92.
  • CALDEIRA C.L., CIMINELLI V.S.T., DIAS A., ET AL. 2003. Pyrite oxidation in alkaline solutions: Nature of the product layer [J]. International Journal of Mineral Processing. 72(1-4), 373-386.
  • CHAI W.C., HUANG Y.F., PENG W.J., ET AL. 2018. Enhanced separation of pyrite from high-sulfur bauxite using 2-mercaptobenzimidazole as chelate collector: Flotation optimization and interaction mechanisms. Minerals Engineering. 129, 93-101.
  • ERSOY Ö.F., TURGUT H., Güven O., ET AL, 2013. Effect of heat treatment on the flotation of Turkish lignites in brine solution. Materials Science and Technology. 10, 2044-2052.
  • GE L., GONG X.Z., 2015. Sulfur removal from bauxite water slurry (BWS) electrolysis intensified by ultrasonic. Ultrasonics Sonochemistry, 26, 142–148.
  • GIBSON B., WONYEN D.G., CHELGANI S.C. 2017. A review of pretreatment of diasporic bauxite ores by flotation separation [J]. Minerals Engineering. 114, 64-73.
  • HE M.F., LI S.K., CAO M., ET AL. 2021. Activation mechanism of tantalum niobium flotation by lead ions in a combined collector flotation system. Physicochemical Problems of Mineral Processing. 57(1), 29–38.
  • LI M.X., CHEN X.H., WANG S., et al. 2015. Study on the desulfurization mechanism of high-sulfur bauxite by microwave. Light Metals. 01, 16–19.
  • LIU H., HE J., LUO T., ET AL. 2023. Interfacial Adsorption Mechanism of Diethyldithiocarbamate in High-Sulfur Residue Flotation. Processes. 11(5), 1568.
  • LIU Z., YAN H., MA W., ET AL. 2020. Digestion behavior and removal of sulfur in high-sulfur bauxite during bayer process. Minerals Engineering, 149(2), 106237.
  • LOU Z., XIONG Y., FENG X., ET AL. 2016. Study on the roasting and leaching behavior of high-sulfur bauxite using ammonium bisulfate [J]. Hydrometallurgy. 165, 306–311.
  • MONDILLO N., HERRINGTON R., BONI M. 2021. Encyclopedia of Geology. Academic Press. 5, 694-707.
  • MOULDER J.F., CHASTAIN J., KING R.C., ET AL. 1992. Handbook of x-ray photoelectron spectroscopy: a reference book of standard spectra for identification and interpretation of XPS data. Chemical Physics Letters. 220(1), 7-10.
  • OLIVEIRA C.M., MACHADO C.M., DUARTE G.W., ET AL. 2016. Beneficiation of pyrite from coal mining. Journal of Cleaner Production. 139, 821-827.
  • PARASKEVAS D., VOORDE A.V.D., KELLENS K., ET AL. 2016. Current Status, Future Expectations and Mitigation Potential Scenarios for China's Primary Aluminium Industry, Procedia CIRP, 295-300.
  • SUN Q., WANG S., MA X., ET AL. 2021. Desulfurization in high-sulfur bauxite with a novel thioether-containing hydroxamic acid: Flotation behavior and separation mechanism. Separation and Purification Technology. 275, 119147.
  • TABEREAUX A.T., PETERSON R.D. 2014. Aluminum Production. Treatise on Process Metallurgy. 3, 839-917.
  • TAGUTA J., O’CONNOR C.T., MCFADZEAN B., ET AL. 2003. The effect of the alkyl chain length and ligand type of thiol collectors on the heat of adsorption and floatability of sulphide minerals. Minerals Engineering. 110, 145-152.
  • VEAR M., SCHIPPERS A., SAND W., ET AL. 2013. Progress in bioleaching: fundamentals and mechanisms of bacterial metal sulfide oxidation—part A. Applied Microbiology & Biotechnology. 97(17), 7529-7541.
  • XIE W.K., ZHOU Z.Q., CHEN X.H., 2017. Study on the Flotation Desulfurization of High-sulfur Bauxite in Henan[J]. Nonferrous Metals (Mineral Processing Section). 01, 43-45.
  • YANG X.L., ALBIJANIC B., LIU G.Y., ET AL. 2018. Structure–activity relationship of xanthates with different hydrophobic groups in the flotation of pyrite. Minerals Engineering. 125, 155–164.
  • YIN W.Z., XUE J.W., LI D., ET AL. 2018. Flotation of heavily oxidized pyrite in the presence of fine digenite particles. Minerals Engineering. 115, 142-149.
  • YU, S.X., SUN, W., WANG, Y.L., ZHANG, P., 2002. Recycling uses of wastewater from flotation of phosphate ores by electrochemical treatment. Industrial Water Treatment. 22(2), 12-14.
  • ZHANG Y.H., CAO Z., CAO Y.D., ET AL. 2013. FTIR studies of xanthate adsorption on chalcopyrite, pentlandite and pyrite surfaces. Journal of Molecular Structure. 1048, 434-440.
  • ZHANG N., ZHOU C., CONG L., ET AL. 2016. Semi-industrial experimental study on bauxite separation using a cell-column integration process. Int. J. Miner. Metallurgy Mater. 23, 7–15.
  • ZHOU J., MEI G., YU M., ET AL. 2019. Effect and mechanism of surface pretreatment on desulfurization and desilication from low-grade high-sulfur bauxite using flotation. Physicochemical Problems of Mineral Processing, 55(4): 940-950.
  • ZHOU J.Q., MEI G.J., YU M.M., ET AL. 2022. Effect and mechanism of quaternary ammonium salt ionic liquid as a collector on desulfurization and desilication from artificial mixed bauxite using flotation. Minerals Engineering. 181, 107523.
  • ZHU Z.P., TENG X., YANG Y., ET AL. 2023. Flotation Decarbonization and Desulfurization of a High-Sulfur Bauxite in China. Minerals. 13(8), 1008.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e53fb495-b465-4e98-a152-454cf5e2d46d
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