Hydrogenation of cinnamaldehyde over supported palladium catalysts

• Autorzy: Wąsikowska K. , Dmowska P. , Bączek N. , Strzelec K. , Pernak J. , Markiewicz B.
• Języki publikacji: EN

Abstrakty

EN

The selective hydrogenation of cinnamaldehyde has been studied using palladium catalysts based on epoxy resin cured with ionic liquids. Characterization of palladium catalysts has involved the following methods: IR spectroscopy, X-ray photoelectron spectroscopy (XPS), AAS spectroscopy and time-of-flight secondary ion mass spectrometry (TOF-SIMS). The investigated catalysts showed high stability and good recycling efficiency what makes them useful for a prolonged use. The factors influencing the selectivity of the supported catalysts were discussed.

Słowa kluczowe

EN

selective hydrogenation; supported catalyst; epoxy resin; ionic liquids

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2013
• Tom: Vol. 15, nr 4
• Strony: 28--32
• Opis fizyczny: Bibliogr. 14 poz., rys., tab., wz.

Twórcy

autor

Wąsikowska K.

• Lodz University of Technology, Institute of Polymer & Dye Technology, Stefanowskiego 12/16, 90-924 Lodz, Poland

autor

Dmowska P.

• Lodz University of Technology, Institute of Polymer & Dye Technology, Stefanowskiego 12/16, 90-924 Lodz, Poland

autor

Bączek N.

• Lodz University of Technology, Institute of Polymer & Dye Technology, Stefanowskiego 12/16, 90-924 Lodz, Poland

autor

Strzelec K.

• Lodz University of Technology, Institute of Polymer & Dye Technology, Stefanowskiego 12/16, 90-924 Lodz, Poland

autor

Pernak J.

• Poznan University of Technology, Institute of Technology and Chemical Engineering, Faculty of Chemical Technology, 2 M. Skłodowska-Curie Square, 60-965 Poznan, Poland

autor

Markiewicz B.

• Poznan University of Technology, Institute of Technology and Chemical Engineering, Faculty of Chemical Technology, 2 M. Skłodowska-Curie Square, 60-965 Poznan, Poland

Bibliografia

• 1. Bauer, K. & Garbe, D. (1985). Common Fragrance and Flavor Materials,VCH, Weinheim.
• 2. Bauer, K. & Garbe, D. (1988). Ullman Encyclopedia, Vol. All, VCH, New York.
• 3. Weissermel, K. & Arpe H.J. (1978). Industrial Organic Chemistry, Verlage Chemie, Weinheim.
• 4. Li, Y., Zhou, R.X. & Lai, G.H. (2006). Effect of transition metals (Cr, Mn, Fe, Co, Ni and Cu) on selective hydrogenation of cinnamaldehyde over Pt/CNTs catalyst. React. Kinet. Catal. Lett. 88, 105−110. DOI: 10.1556/RKCL.88.2006.1.14.
• 5. Maki-Arvela, P., Hajek, J., Salmi, T. & Yu, D.M. (2005). Chemoselective hydrogenation of carbonyl compounds over heterogeneous catalysts. Applied Catalysis A: General 292, 1-49. DOI: 10.1016/j.apcata.2005.05.045.
• 6. Clapham, B., Reger, T.S. & Janda, K.D. (2001). Tetrahedron, 57, 4637-4662. DOI: 10.1016/S0040-4020(01)00298-8.
• 7. Corain, B., Zecca, M., Biffi s, A., Lora, S. & Palma, G. (1994). J. Organomet. Chem. 475, 283.
• 8. Patel, D.R. & Ram, R.N. (1998). Hydrogenation of nitrobenzene using polymer anchored Pd(II) complexes as catalyst. J. Mol. Catal. 130, 57-64. DOI: 10.1016/S1381-1169(97)00197-0.
• 9. Dell’Anna, M.M., Gagliardi, M., Mastrorilli, P., Suranna, G.P. & Nobile, C.F. (2000). Hydrogenation reactions catalysed by a supported palladium complex. J. Mol. Catal. A: Chem.158, 515-520. DOI: 10.1016/S1381-1169(99)00445-8.
• 10. Michalska, Z.M., Ostaszewski, B., Zientarska, J. & Sobczak, J.W. (1998). Catalytic hydrogenation of alkadienes and alkynes by palladium catalysts supported on heterocyclic polyamides. J. Mol. Catal. A: Chem. 129, 207-218. DOI: 10.1016/S1381-1169(97)00212-4.
• 11. Jung, A., Jess, A., Schubert, T. & Schutz, W. (2009). Performance of carbon nanomaterial (nanotubes and nanofi bres) supported platinum and palladium catalysts for the hydrogenation of cinnamaldehyde and of 1-octyne. Applied CatalysisA: General. 362, 95-105. DOI: 10.1016/j.apcata.2009.04.026.
• 12. Benvenuti, F., Carlini, C., Marchionna, M., Galletti, A. M. & Sbrana, G. (1999). Hydrogenation of organic substrates by an heterogenized catalyst based on a bis(diphenylphosphino) methane polymer-bound palladium(II) complex. J. Mol. Catal. A: Chem, 145, 221-228. DOI: 10.1016/S1381-1169(99)00022-9.
• 13. Gallezot, P. & Richard, D. (1998). Selective hydrogenation of α,β-unsaturated aldehydes. Catal. Rev. Eng. 40, 81-126. DOI: 10.1080/01614949808007106.
• 14. Strzelec, K., Wąsikowska, K., Cypryk, M. & Pospiech, P. (2011). Terpolymers of N-vinylpyrrolidinone and 1-vinylimidazole as new supports for palladium nanocluster catalysts. Retrieved March, 15 from the World Wide Web: www.e-Polymers.org, 024.