Recovery of Niobium Pentaoxide and Ammonium Sulfate from Titanium-Magnesium Production Waste

• Autorzy: Ultarakova Almagul , Lokhova Nina , Karshyga Zaure , Toishybek Azamat , Yessengaziyev Azamat , Kassymzhanov Kaisar , Mukangaliyeva Arailym

Identyfikatory

DOI

10.12911/22998993/171647

• Języki publikacji: EN

Abstrakty

EN

This study was aimed to investigate the development of a technology for the extraction of niobium pentaoxide and ammonium sulfate from titanium-magnesium production waste, specifically, the sublimates of dust chamber into concentrate in the form of niobium pentoxide. Optimal conditions for washing the niobium hydroxide precipitate by repulpation with hot (60–70°C) distilled water, drying at 200°C for 6 hours were determined. The influence of temperature and duration of the process was studied. Optimal conditions for the dynamic desorption of niobium from saturated ionite (Purolite A100) was determined. The results further indicated that the optimum quantity of the solution of desorption with sulfuric acid was equal to 5.5% and ammonium oxalate was equal to 4%, while temperature and the flow rate of the desorbing solution was 22–27°C and 6 rpm, respectively. The study of the precipitation of niobium from sulfuric acid desorbates showed that the interaction of niobium ions with ammonia takes place at a low rate. The degree of precipitation of niobium hydroxide equal to 99.6% was achieved in 7 hours of agitation of the suspension at a temperature of 22–25°C.

Słowa kluczowe

EN

titanium residue; sludge; leaching; niobium chloride; niobium pentaoxide; purification; dust chamber; sublimation; desorption; ammonium sulfate

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2023
• Tom: Vol. 24, nr 11
• Strony: 227--235
• Opis fizyczny: Bibliogr. 17 poz., rys., tab.

Twórcy

autor

Ultarakova Almagul

• JSC Institute of Metallurgy and Ore Benefication, Satbayev University, Shevchenko St. 29/133, Almaty 050010, Kazakhstan

• https://orcid.org/0000-0001-9428-8508

autor

Lokhova Nina

• JSC Institute of Metallurgy and Ore Benefication, Satbayev University, Shevchenko St. 29/133, Almaty 050010, Kazakhstan

• https://orcid.org/0000-0001-9436-5462

autor

Karshyga Zaure

• JSC Institute of Metallurgy and Ore Benefication, Satbayev University, Shevchenko St. 29/133, Almaty 050010, Kazakhstan

• https://orcid.org/0000-0002-3025-7363

autor

Toishybek Azamat

• JSC Institute of Metallurgy and Ore Benefication, Satbayev University, Shevchenko St. 29/133, Almaty 050010, Kazakhstan

• https://orcid.org/0000-0002-7431-0103

autor

Yessengaziyev Azamat

• JSC Institute of Metallurgy and Ore Benefication, Satbayev University, Shevchenko St. 29/133, Almaty 050010, Kazakhstan

• https://orcid.org/0000-0002-4989-4119

autor

Kassymzhanov Kaisar

• JSC Institute of Metallurgy and Ore Benefication, Satbayev University, Shevchenko St. 29/133, Almaty 050010, Kazakhstan

• https://orcid.org/0000-0001-8062-8655

autor

Mukangaliyeva Arailym

• JSC Institute of Metallurgy and Ore Benefication, Satbayev University, Shevchenko St. 29/133, Almaty 050010, Kazakhstan

Bibliografia

• 1. Baigenzhenov О., Toishybek А., Khabiyev А., Aimbetova, I., & Dagubayeva А. 2021. Recovery of niobium from wastes generated in titanium production by cation exchange sorbents. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources, 318(3), 97–103. https://doi.org/10.31643/2021/6445.33 (in Kazakh)
• 2. Bollaert, Q., Chassé, M., Allard, T., Courtin, A., Galoisy, L., Landrot, G., Quantin, C., Vantelon, D. and Calas, G., 2023. Multiscale processes controlling niobium mobility during supergene weathering. Geochimica et Cosmochimica Acta, 353, pp.142–157.
• 3. Braun P.M., Vu Rong-Chejn R., Pedikone R.S., Madara M.G. 2002. Compounds of tantalum pentaoxide and niobium pentoxide. RU Patent 2189359 C2. (In Russian)
• 4. European Commission, Directorate-General for Internal Market, Industry, Entrepreneurship and SMEs, Study on the review of the list of critical raw materials : final report, Publications Office, 2017, https://data.europa.eu/doi/10.2873/876644
• 5. Ghosh, M., Remya Devi, P. S., Verma, R., & Reddy, A. V. R. 2015. Sorption of niobium on colloidal silica and the effect of humic acid. Journal of Radioanalytical and Nuclear Chemistry, 306, 147–153.
• 6. Khabiyev, A., Baigenzhenov, O., Korganbayeva, Z., Toishybek, A., Chepushtanova, T. and Orynbayev, B., 2022. Niobium (v) recovery from leaching solution of titanium wastes: Kinetic studies. Metalurgija, 61(3–4), pp.793–796.
• 7. Khudaibergenov T.E. 1996.Titanium and magnesium production. Technology of processing of industrial products and waste. Almaty: IPF S&K., 178. (in Russian)
• 8. Kokotov Yu.A., Zolotarev P.P., Elkin G.E. 1986. Theoretical foundations of ion exchange. – L.: Chemistry,– 280 p. (in Russian)
• 9. Kudryavsky, Yu.P., 2004. The ways and prospects of improving the technology of neutralization of titanium production waste. Modern high-tech technologies, (1), pp.88–88. (in Russian)
• 10. Hadlocon L.S, Zhao L. Y. 2015. Production of ammonium sulfate (AS) fertilizer using acid spray wet scrubbers. Agric Eng Int: CIGR Journal, Special issue 2015: 18th World Congress of CIGR: 41–51.
• 11. Mitchell, R.H., 2015. Primary and secondary niobium mineral deposits associated with carbonatites. Ore Geology Reviews, 64, pp.626–641.
• 12. Nzeh, N.S., Adeosun, S., Popoola, A.P., Adeleke, A. and Okanigbe, D., 2022. Process applications and challenges in mineral beneficiation and recovery of niobium from ore deposits–A review. Mineral Processing and Extractive Metallurgy Review, 43(7), 833–864.
• 13. Sanz, J., Tomasa, O., Jimenez-Franco, A., Sidki-Rius, N. 2022. Niobium (Nb) [Z = 41]. In: Elements and Mineral Resources. Springer Textbooks in Earth Sciences, Geography and Environment. Springer, Cham. https://doi.org/10.1007/978–3-030–85889–6_36
• 14. Shayakhmetov B.M., Khudaibergenov T.E. 1998. The main milestones of scientific and technological progress at the Ust-Kamenogorsk Titanium Magnesium Plant (1965–1995). Almaty, pp. 150 (in Russian)
• 15. Shikika, A., Sethurajan, M., Muvundja, F. and Mugumaoderha, M.C., 2020. A review on extractive metallurgy of tantalum and niobium. Hydrometallurgy, 198, #105496.
• 16. Ultarakova, A., Naimanbayev, M., Murat, O., Nadira, A. and Botakoz, B., 2016. October. Production of Synthetic Carnallite from The Wastes of Titanium and Magnesium Production with The Extraction of Niobium-Containing Middlings. In: IOP Conference Series: Earth and Environmental Science, IOP Publishing, 44(3), #032001.
• 17. Ultarakova, Almagul, Zaure Karshyga, Nina Lokhova, Azamat Yessengaziyev, Kaisar Kassymzhanov, and Arailym Mukangaliyeva. 2023. “Studies of Niobium Sorption from Chloride Solutions with the Use of Anion-Exchange Resins” Processes 11, no. 4: 1288. https://doi.org/10.3390/pr11041288

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).