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The Effect of Detonator Shell Materials on Detonation Calorimetry Results

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Detonation calorimetry is a method for the determination of the heat released by the detonation of an explosive charge. Compared to classical combustion calorimetry, detonation calorimetry requires an inert atmosphere, a large sample mass and a detonator for its initiation. This detonator releases some energy for which the results must be corrected. Four types of detonator have been tested in the calorimeter alone and also in combination with explosive charges of PETN. It was found that the aluminium shell of the detonator considerably increases the apparent heat of detonation of the PETN samples in a vacuum, while the presence of combustible (polymeric) components has the opposite effect. Pressurization of the calorimetric vessel with nitrogen gas only partially suppresses these effects. The preferred technique is to use copper or glass confinement in a high pressure inert atmosphere.
Rocznik
Strony
552--565
Opis fizyczny
Bibliogr. 15 poz., rys., tab.
Twórcy
  • OZM Research, Blížňovice 32, Hrochův Týnec, Czech Republic
  • Austin Detonator, Vsetín, Czech Republic
  • OZM Research, Blížňovice 32, Hrochův Týnec, Czech Republic
Bibliografia
  • [1] Ornellas, D.L.; Carpenter, J.H.; Gunn, S.R. Detonation Calorimeter and Results Obtained with Pentaerythritol Tetranitrate (PETN). Rev. Sci. Instrum. 1966, 37(7):907-912.
  • [2] Tongchang, Y.; Menchao, Y.; Jianling, W. Determination of Heats of Detonation and Influence of Components of Composite Explosives on Heats of Detonation of High Explosives. J. Therm. Anal. 1995, 44: 1347-1356.
  • [3] Orne l l a s , D.L. The Hea t and Produc ts of Detona t ion of Cyclotetramethylenetetranitramine, 2,4,6-Trinitrotoluene, Nitromethane, and Bis[2,2-dinitro-2-fluoroethyl]formal. J. Phys. Chem. 1968, 72(7): 2390-2394.
  • [4] Ornellas, D.L. The Heat and Products of Detonation in a Calorimeter of CNO, HNO, CHNF, CHNO, CHNOF, and CHNOSi Explosives. Combust. Flame 1974, 23: 37-46.
  • [5] Trzciński, W. On Some Methods of Determination of the Detonation Energy of Explosives. New Trends Res. Energ. Mater., Proc. Semin., Pardubice, Czech Republic, 2006, pp. 748-755.
  • [6] Cudziło, S.; Trębiński, R.; Trzciński, W.; Wolański, P. Comparison of Heat Effects of Combustion and Detonation of Explosives in a Calorimetric Bomb. Int. Annu. Conf. Fraunhofer ICT, Karlsruhe, Germany, 1998, pp. 150/1-150/8.
  • [7] Pepekin, V.I.; Gubin, S.A. Heat of Explosion of Commercial and Brisant High Explosives. Combust., Explos. Shock Waves (Engl. Transl.) 2007, 43(2): 212-218.
  • [8] Kiciński, W.; Trzciński, W.A. Calorimetry Studies of Explosion Heat of Non-ideal Explosives. J. Therm. Anal. Calorim. 2009, 96: 623-630.
  • [9] Makhov, M.N.; Gogulya, M.F.; Dolgoborodov, A.Y.; Brazhnikov, M.A.; Arkhipov, V.I.; Pepekin, V.I. Acceleration Ability and Heat of Explosive Decomposition of Aluminized Explosives. Combust., Explos. Shock Waves (Engl. Transl.) 2004, 40(4): 458-466.
  • [10] Sućeska, M. Explo5 Version 6.05/2018 User’s Guide. ed. 2018, OZM Research, Hrochuv Tynec, Czech Republic, 2018.
  • [11] Sućeska, M. Calculation of the Detonation Properties of C-H-N-O Explosives. Propellants Explos. Pyrotech. 1991, 16(4): 197-202.
  • [12] Sućeska, M.; Braithwaite, C.H.; Klapötke, T.M.; Stimac, B. Equation of State of Detonation Products Based on Exponential-6 Potential Model and Analytical Representation of the Excess Helmholtz Free Energy. Propellants Explos. Pyrotech. 2019, 44(5): 564-571.
  • [13] Brown, W.B. Analytical Representation of the Excess Thermodynamic Equation of State for Classical Fluid Mixtures of Molecules Interacting with α-Exponential-six Pair Potentials up to High Densities. J. Chem. Phys. 1987, 87(1): 566-577.
  • [14] Sućeska, M. Evaluation of Detonation Energy from EXPLO5 Computer Code Results. Propellants Explos. Pyrotech. 1999, 24(5): 280-285.
  • [15] Ornellas, D.L. Calorimetric Determinations of the Heat and Products of Detonation for Explosives: October 1961 to April 1982, Lawrence Livermore National Laboratory, Report UCRL-52821, 1982.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e4ae35d0-29a7-461d-a699-ed904e4d212f
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