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Barrierity of Hydrogenated Butadiene-Acrylonitrile Rubber and Butyl Rubber After Exposure to Organic Solvents

Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Resistance of antichemical clothing primarily depends on the type of material it is made from, in particular on the type of polymer used for coating the fabric carrier. This paper reports on systematic investigations on the influence of the cross-linking density of an elastomer and the composition of a cross-linked elastomer on its resistance to permeation of selected organic solvents. Tests of barrier material samples made from nonpolar butyl rubber (IIR) and polar hydrogenated butadiene-acrylonitrile rubber (HNBR) showed that (a) in rubber–solvent systems with medium thermodynamic affinity, cross-linking density influenced resistance to permeation and (b) the polarity of the system had a significant influence on barrierity.
Rocznik
Strony
41--47
Opis fizyczny
Bibliogr. 10 poz., rys., wykr.
Twórcy
  • Department of Personal Protective Equipment, Central Institute for Labour Protection – National Research Institute (CIOP-PIB), Łódź, Poland
  • Institute of Polymer and Dye Technology, Technical University of Łódź, Łódź, Poland
Bibliografia
  • 1.European Committee for Standardization (CEN). Protective clothing—protection against liquid chemicals—test method: resistance of materials to permeation by liquids (Standard No. EN ISO 6529:2001). Brussels, Belgium: CEN; 2001.
  • 2.Smejda-Krzewicka A, Rzymski WM, Tarniowy A. Novel elastomers containing carboxyl groups. In: Parasiewicz W, Rzymski WM, editors. Elastomery i przemysł gumowy. Piastów, Poland: Instytut Przemysłu Gumowego/Łódź, Poland: Politechnika Łódzka; 2006. p. 29–47. In Polish.
  • 3.International Organization for Standardization (ISO). Rubber—measurement of vulcanization characteristics with the oscillating disc curemeter (Standard No. ISO 3417:2008). Geneva, Switzerland: ISO; 2008.
  • 4.Krzemińska S. Determination of organic solvents mixtures permeating through butyl rubber membranes by means of gas chromatography. Polish Journal of Applied Chemistry. 2007;51(1–2):49–53.
  • 5.Krzemińska S, Rzymski WM. Effect of layered silicate on barrier properties of cured butyl rubber. J Phys: Conf Ser. 2009;146(1). Retrieved January 17, 2011, from: http://iopscience.iop.org/1742-6596/146/1/012007.
  • 6.Krzemińska S, Rzymski WM. Effect of condition treatments of organic solvents on barrier properties of cured butyl rubber. Polimery. 2008;53(4):60–6. In Polish.
  • 7.Krzemińska S, Rzymski WM. Study on barrier properties of elastomers. In: XII Research Workshop: Processing of Polymer Materials. Toruń, Poland: Instytut Przetwórstwa Tworzyw Sztucznych “Metalchem”; 2007. p. 121–5. In Polish.
  • 8.Krzemińska S, Rzymski WM. Barrier properties of butyl rubber vulcanizates exposed to organic solvents. Elastomery. 2007;11(5):3–9. In Polish.
  • 9.George SC, Ninan KN, Thomas S. Permeation of nitrogen and oxygen gases through styrene-butadiene rubber, natural rubber and styrene-butadiene rubber/natural rubber blend membranes. European Polymer Journal. 2001;37(1):183–91.
  • 10.George S, Varughese KT, Thomas S. Molecular transport of aromatic solvents in isotactic polypropylene/acrylonitrile-cobutadiene rubber blends. Polymer. 2000;41(2):579–94.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e49ceb64-d0e6-418b-9ddd-1578cd3272fb
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