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Tytuł artykułu

Process simulation of dimethyl ether synthesis via methanol vapor phase dehydration

Autorzy
Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The production processes included catalytic dehydration of methanol in an adiabatic fixed-bed reactor and two columns product separations. In this study, the technological process for dimethyl ether (DME) synthesis is built on PRO/II platform based on the combined parameters of the reaction dynamic model for methanol dehydration reaction, the improved NRTL model of the liquid phase, the PR model of vapor phase. In order to validate the proposed model, the simulation results have been compared with the available data from a set of industrial production equipment with a production capacity of 200 000 tonnes per annum. A comparison between the calculated and measured results has proved that these results are satisfactory. The bed height and the volume of the catalytic bed are calculated aim at one million t/a DME yields and while taking account of high-purity DME production. After discussing the influence of feed stage location and reflux ratio for DME product purity, the suitable unit operation conditions are chosen. Accordingly, accurate process simulation results provide the basis and guidance for an improvement and development of the similar industrial device.
Rocznik
Strony
122–127
Opis fizyczny
Bibliogr. 20 poz., rys., tab., wykr.
Twórcy
autor
  • East China University of Science and Technology, Engineering Research Center of Large Scale Reactor Engineering and Technology, Ministry of Education, State Key Laboratory of Chemical Engineering, Shanghai, 200237, China
autor
  • East China University of Science and Technology, Engineering Research Center of Large Scale Reactor Engineering and Technology, Ministry of Education, State Key Laboratory of Chemical Engineering, Shanghai, 200237, China
autor
  • East China University of Science and Technology, Engineering Research Center of Large Scale Reactor Engineering and Technology, Ministry of Education, State Key Laboratory of Chemical Engineering, Shanghai, 200237, China
autor
  • East China University of Science and Technology, Engineering Research Center of Large Scale Reactor Engineering and Technology, Ministry of Education, State Key Laboratory of Chemical Engineering, Shanghai, 200237, China
autor
  • East China University of Science and Technology, Engineering Research Center of Large Scale Reactor Engineering and Technology, Ministry of Education, State Key Laboratory of Chemical Engineering, Shanghai, 200237, China
Bibliografia
  • 1. Somelsberger, T.A., Borup, R.L. & Greene, H.L. (2006). Dimethyl ether (DME) a s an alternative fuel. Journal of Power Sources. 156 (2), 497-511. DOI: 10.1016/j.jpowsour.2005.05.082.
  • 2. Adachi, Y., Komoto, M. & Watanabe, I. (2000). Effective utilization of remote coal through dimethyl ether synthesis. Fuel, 79, 229-234. DOI: 10.1016/S0016-2361(99)00156-8.
  • 3. Arcoumanis, C., Bae, C. & Crookes, R. (2008). The potential of dimethyl ether (DME) as an alternative fuel for compression-ignition engines: a review. Fuel, 87, 1014-1030. DOI: 10.1016/j.fuel.2007.06.007.
  • 4. Galvita, V.V., Semin, G.L., Belyaev, V.D., Yurieva, T.M. & Sobyanin, V.A. (2001). Production of hydrogen from dimethyl ether. Applied Catalyst. 216 (1-2), 85-90. DOI: 10.1016/ S0926-860X(01)00540-3.
  • 5. Yoshitugi Kikkawa. & Ichizo Aoki. (1998). Dimethyl Ethe r Fuel Proposed as an Alternative to LNG. Oil & Gas Journal. 96, 55-59. from http://www.ogj.com/index.html.
  • 6. Lee, S., Gogate, M. R. & Kulik, C.J. (1992). A novel single- -step dimethyl ether (DME) synthesis in a three-phase slurry reactor from co-rich syngas. Chem. Eng. Science. 47 (13-14), 3769-3776. DOI: 10.1016/0009-2509(92)85096-T.
  • 7. Ng, K.L., Chadwick, D. & Toseland, B.A. (1999). Kinetics and modellin g of dimethyl ether synthesis from synthesis gas. Chem. Eng. Sci. 54 (1 5-16), 3587-3592. DOI: 10.1016/S0009-250 9(98)00514-4.
  • 8. Ramos, F.S., Duarte, de Farias, A.M., Borges, L.E.P., Monteiro, J.L., Fraga, M.A., Sousa-Aguiar, E.F. & Appel, L.G. (2005). Role of dehydration ca talyst acid properties on one- -step DME synthesis over physical mixtures. Catalysis Today. 101 (1), 39-44. DOI: 10.1016/j.cattod.2004.12.007.
  • 9. Lu, W.Z., Teng, L.H. & Xiao, W.D. (2004). Simulation and experim ent study of dimethyl ether synthesis from syngas in a fluidized-bed reactor. Chem. Eng. Sci. 59 (22-23), 5455-5464. DOI: 10.1016/j.ces.2004.07.031.
  • 10. Yaripour, F., Baghaei, F., Schmidt, I. & Perregaard, J. (2005). Catalytic dehydration of methanol to dimethyl ether (DME) over solid-acid catalysts. Catalysis Communicatio ns. 6 (2), 147-152. DOI: 10.1016/j.catcom.2004.11.012.
  • 11. Fazlollahnejad, M., Taghizadeh, M., Eliassi, A. & Bakeri, G. (2009). Experimental Study and Modeling of an Adiabatic Fixed-bed Reactor for Methanol Dehydration to Dimethyl Ether. Chinese Journal of Chemical Engineering. 17 (4), 630-634. DOI: 10.1016/S1004-9541(08)60255-4.
  • 12. Moradi, G.R., Yaripour, F. & Vale-Sheyda, P. (2010). Catalytic dehydration of methanol to dimethyl ether over mordenite catalysts. Fuel Processing Technology. 91 (5), 461-468. DOI: 10.1016/j.fuproc.2009.12.005.
  • 13. Hu, Y.F., Nie, Z.G. & Fang, D.Y. (2008). Simulation and model design of pipe-shell reactor for the direct synthesis of dimethyl ether from syngas. Journal of Natural Gas Chemistry. 17 (2), 195-200. DOI: 10.1016/S1003-9953(08)60051-1.
  • 14. Farsi, M., Eslamloueyan, R. & Jahanmiri, A. (2010). Modeling, simulation a nd control of dimethyl ether synthesis in an industrial fixed-bed reactor. Chemical Engineering and Processing. 50, 85-94. DOI: 10.1016/j.cep.2010.11.013.
  • 15. Wei, Z.A., Karl, T. C. & Alan, R.S. (2004). Dehydration of Methanol to Dimethyl Ether by Catalytic Distillation. The Canadian Journal of Chemical Engineering. 82, 949-955. DOI: 10.1002/cjce.5450820510.
  • 16. Han, Y.Y., Zhang, H.T., Ying, W.Y. & Fang, D.Y. (2009). Modeling and Simulation of Production Process on Dimethyl Ether Synthesized from Coal-based Syngas by One-step Method. Chinese Journal of Chemical Engineering. 17 (1), 108-112. DOI: 10.1016/S1004-9541(09)60041-0.
  • 17. Zhang, L., Zhang, Y .Z., Pan, Q., Song, C.X., Zhang, H.T., Ying, W.Y. & Fang, D.Y. (2011). Intrinsic kinetics of methanol dehydration to dimethyl ether. Journal of China Coal Society. 36 (7), 1195-1199. from http://wenku.baidu.com/view/c86341e94afe04a1b071de30.html.
  • 18. Ying, W.Y., Zhang, H.T., Ma, H.F. & Fang, D.Y. (2011). China. Patent No. 201110127054. Shanghai.: P.R.C. State Intellectual Property Office.
  • 19. Li, R., Zhang, H.T., Ying, W.Y. & Fang, D.Y. (2009). Research on the intrinsic kinetics of methanol dehydration to dimethyl ether. Natural gas Chemical Industry. 39 (5), 9-12. from http://wenku.baidu.com/view/4da361da7f1922791688e8be.html.
  • 20. Song, H.J., Zhang, H.T., Ying, W.Y. & Fang, D.Y. (2005). Measurement and calculation of vapor-liquid equilibrium for dimethyl ether-methanol-water ternary system. Journal of Chemical Industry and Engineering (China). 30, 67-71. from http://wenku.baidu.com/view/55f065ff910ef12d2af9e771.html.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e4214ddb-8db5-4302-b8c9-156172555ad3
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