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The levels of persistent organic pollutants (POPs) from industrial by-products were determined in beach sand and marine sediments from different sites along the Jordanian coast of the Gulf of Aqaba. Seventeen polychlorinated dibenzo-p-dioxins and polychlorinated dibenzo-p-furans (PCDD/Fs) compounds were identified. Automatic Soxhlet (Soxtec) extraction method was used for PCDD/Fs extractions using toluene as a solvent. Pre-washed multilayer silica gel column was used for cleanup step. Samples were analyzed using high-resolution gas chromatography and mass spectroscopy detector (HRGC–MS). Low levels of POPs were found in all sand and sediment samples. Concentrations of PCDD/Fs ranged between 3.91 and 8.91 ng kg−1 dw with an average of 6.49 ng kg−1 dw for beach sand samples and between 6.560 and 45.95 ng kg−1 dw with an average of 28.70 ng kg−1 dw for marine sediment samples. Concentrations of PCDD/Fs for soil and sediment were mostly less than other sites worldwide. PCDD/Fs concentrations measured in this study can be considered as a baseline for future monitoring and control of PCDD/Fs as requested by Stockholm Convention.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
38--42
Opis fizyczny
Bibliogr. 21 poz., rys.
Twórcy
autor
- Aqaba Special Economic Zone Authority (ASEZA), Ben Hayyan — Aqaba International Laboratories, Aqaba 77110, Jordan
autor
- Department of Chemistry, The University of Jordan, Amman, Jordan
- Mote Marine Laboratory — Mote Aquaculture Research Park, Sarasota, FL 34240, USA
Bibliografia
- [1] Le Van, A. Unpublished Master Dissertation , Sweden , 2011 .
- [2] Stockholm Convention on Persistent Organic Pollutants , Geneva , Secretariat of the Stockholm Convention ( http://chm.pops.int ), 2009 .
- [3] Kojima, H. ; Takeuchi, S. ; Iida, M. ; Nakayama, S. F. ; Shiozaki, T. Environ. Sci. Poll. Res. 1 – 12 , DOI: 10.1007/s11356-015-4662-9 .
- [4] Hurst, M. R. ; Balaam, J. ; Chan-Man, Y. L. ; Thain, J. E. ; Thomas, K. V. Mar. Poll. Bull. 2004 , 49 , 648 – 658 .
- [5] Klanova, J. ; Matykiewiczova, N. ; Zdenek Macka, Z. ; Prosek, P. ; Lask, K. ; Petr Klan, P. Sci. Direct Environ. Pollut. 2007 , 152 , 1 – 8 .
- [6] Minh, N.H. ; Someya, M. ; Minh, B. ; Kunisue, T. ; Iwata, H. ; Watanabe, M. ; Tanabe, S. ; Viet, P. H. ; Tuyen, B. C. Environ. Pollut. 2004 , 129 , 431 – 441 .
- [7] El-Kady, A. A. ; Abdel-Wahhab, M. A. ; Henkelmann, B. ; Belal, M. H. ; Khairy, M. ; Morsi, S. ; Galal, S. M. ; Schramm, K. Chemosph. 2007 , 68 , 1660 – 1668 .
- [8] UNIDO , Promotion of strategies to reduce unintentional production of POPs in the Red Sea and Gulf of Aden (PERSGA) coastal zone , 2011 .
- [9] ICES , Determination of polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and dioxin-like polychlorinated biphenylsin biota and sediment . ICES TIMES No. 50, 2012 .
- [10] US EPA , Tetra- through octachlorinated dioxins and furans by isotope dilution HRGC/HRMS . US. Environmental Protection Agency Office of Water Engineering and Analysis Division , Washington DC , US EPA method 1613 Rev. B, 1994 .
- [11] US EPA , Polychlorinated dibenzodioxins (PCDD) and polychlorinated dibenzofurans (PCDF) by High Resolution Gas Chromatography and High Resolution Mass Spectrometry (HRGS/HRMS) , US EPA method 8290 Rev., 1998 .
- [12] Skoog, D. A. ; Holler, F. J. ; Crouch, S. R. Principles of Instrumental Analysis , 6th edn, Thomson Brooks/Cole Publishers , USA , 2007 .
- [13] Tundo, P. ; Raccanelli, S. ; Reda, L. A. ; Ahmed, M. T. Chem. Ecol. 2004 , 20 , 257 – 265 .
- [14] Fiedler, H. Dioxins and Furans (PCDD/PCDF) . In: H. Fiedler (Ed), The Handbook of Environmental Chemistry . Vol. 3 , Part O Persistent Organic Pollutants , Springer-Verlag, Berlin, Heidelberg , 2003 , pp. 133 – 135 .
- [15] Urban, J. D. ; Wikoff, D. S. ; Bunch, A. T. ; Harris, M. A. ; Haws, L. C. Sci. Total Env. 2014 , 466 , 586 – 597 .
- [16] Wenning, R. ; Von Burg, A. ; Martello, L. ; Pekala, J. ; Maier, M. ; Luksemburg, W. Organohalogen Compd. 2004 , 66 , 1482 .
- [17] Birmingham, B . Chemosphere 1990 , 20 , 807 – 814 .
- [18] Burniston, D. A. ; Klawunn, P. ; Hill, B. ; Marvin, C. H. Chemosphere 2015 , 123 , 71 – 78 .
- [19] Bakoglu, M. ; Karademir, A. ; Durmusoglu, E. Chemosphere 2005 , 59 , 1373 – 1385 .
- [20] Karademir, A. ; Ergül, H. A. ; Telli, B. ; Kılavuz, S. A. ; Terzi, M. Env. Sci. Poll. Res. 2013 , 20 , 6611 – 6619 .
- [21] Jia, S. ; Wang, Q. ; Li, L. ; Fang, A. ; Shi, Y. ; Xu, W. ; Hu, J. Sci. Total Env. 2014 , 497 , 353 – 359 .
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e41db9be-4186-488c-b5e6-32790488abbc