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GC–Mass determination of low levels polychlorinated dibenzodioxin and polychlorinated dibenzofuran in beach sand and marine sediment of the Gulf of Aqaba

Autorzy
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The levels of persistent organic pollutants (POPs) from industrial by-products were determined in beach sand and marine sediments from different sites along the Jordanian coast of the Gulf of Aqaba. Seventeen polychlorinated dibenzo-p-dioxins and polychlorinated dibenzo-p-furans (PCDD/Fs) compounds were identified. Automatic Soxhlet (Soxtec) extraction method was used for PCDD/Fs extractions using toluene as a solvent. Pre-washed multilayer silica gel column was used for cleanup step. Samples were analyzed using high-resolution gas chromatography and mass spectroscopy detector (HRGC–MS). Low levels of POPs were found in all sand and sediment samples. Concentrations of PCDD/Fs ranged between 3.91 and 8.91 ng kg−1 dw with an average of 6.49 ng kg−1 dw for beach sand samples and between 6.560 and 45.95 ng kg−1 dw with an average of 28.70 ng kg−1 dw for marine sediment samples. Concentrations of PCDD/Fs for soil and sediment were mostly less than other sites worldwide. PCDD/Fs concentrations measured in this study can be considered as a baseline for future monitoring and control of PCDD/Fs as requested by Stockholm Convention.
Słowa kluczowe
Rocznik
Strony
38--42
Opis fizyczny
Bibliogr. 21 poz., rys.
Twórcy
autor
  • Aqaba Special Economic Zone Authority (ASEZA), Ben Hayyan — Aqaba International Laboratories, Aqaba 77110, Jordan
autor
  • Department of Chemistry, The University of Jordan, Amman, Jordan
  • Mote Marine Laboratory — Mote Aquaculture Research Park, Sarasota, FL 34240, USA
Bibliografia
  • [1] Le Van, A. Unpublished Master Dissertation , Sweden , 2011 .
  • [2] Stockholm Convention on Persistent Organic Pollutants , Geneva , Secretariat of the Stockholm Convention ( http://chm.pops.int ), 2009 .
  • [3] Kojima, H. ; Takeuchi, S. ; Iida, M. ; Nakayama, S. F. ; Shiozaki, T. Environ. Sci. Poll. Res. 1 – 12 , DOI: 10.1007/s11356-015-4662-9 .
  • [4] Hurst, M. R. ; Balaam, J. ; Chan-Man, Y. L. ; Thain, J. E. ; Thomas, K. V. Mar. Poll. Bull. 2004 , 49 , 648 – 658 .
  • [5] Klanova, J. ; Matykiewiczova, N. ; Zdenek Macka, Z. ; Prosek, P. ; Lask, K. ; Petr Klan, P. Sci. Direct Environ. Pollut. 2007 , 152 , 1 – 8 .
  • [6] Minh, N.H. ; Someya, M. ; Minh, B. ; Kunisue, T. ; Iwata, H. ; Watanabe, M. ; Tanabe, S. ; Viet, P. H. ; Tuyen, B. C. Environ. Pollut. 2004 , 129 , 431 – 441 .
  • [7] El-Kady, A. A. ; Abdel-Wahhab, M. A. ; Henkelmann, B. ; Belal, M. H. ; Khairy, M. ; Morsi, S. ; Galal, S. M. ; Schramm, K. Chemosph. 2007 , 68 , 1660 – 1668 .
  • [8] UNIDO , Promotion of strategies to reduce unintentional production of POPs in the Red Sea and Gulf of Aden (PERSGA) coastal zone , 2011 .
  • [9] ICES , Determination of polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and dioxin-like polychlorinated biphenylsin biota and sediment . ICES TIMES No. 50, 2012 .
  • [10] US EPA , Tetra- through octachlorinated dioxins and furans by isotope dilution HRGC/HRMS . US. Environmental Protection Agency Office of Water Engineering and Analysis Division , Washington DC , US EPA method 1613 Rev. B, 1994 .
  • [11] US EPA , Polychlorinated dibenzodioxins (PCDD) and polychlorinated dibenzofurans (PCDF) by High Resolution Gas Chromatography and High Resolution Mass Spectrometry (HRGS/HRMS) , US EPA method 8290 Rev., 1998 .
  • [12] Skoog, D. A. ; Holler, F. J. ; Crouch, S. R. Principles of Instrumental Analysis , 6th edn, Thomson Brooks/Cole Publishers , USA , 2007 .
  • [13] Tundo, P. ; Raccanelli, S. ; Reda, L. A. ; Ahmed, M. T. Chem. Ecol. 2004 , 20 , 257 – 265 .
  • [14] Fiedler, H. Dioxins and Furans (PCDD/PCDF) . In: H. Fiedler (Ed), The Handbook of Environmental Chemistry . Vol. 3 , Part O Persistent Organic Pollutants , Springer-Verlag, Berlin, Heidelberg , 2003 , pp. 133 – 135 .
  • [15] Urban, J. D. ; Wikoff, D. S. ; Bunch, A. T. ; Harris, M. A. ; Haws, L. C. Sci. Total Env. 2014 , 466 , 586 – 597 .
  • [16] Wenning, R. ; Von Burg, A. ; Martello, L. ; Pekala, J. ; Maier, M. ; Luksemburg, W. Organohalogen Compd. 2004 , 66 , 1482 .
  • [17] Birmingham, B . Chemosphere 1990 , 20 , 807 – 814 .
  • [18] Burniston, D. A. ; Klawunn, P. ; Hill, B. ; Marvin, C. H. Chemosphere 2015 , 123 , 71 – 78 .
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  • [21] Jia, S. ; Wang, Q. ; Li, L. ; Fang, A. ; Shi, Y. ; Xu, W. ; Hu, J. Sci. Total Env. 2014 , 497 , 353 – 359 .
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e41db9be-4186-488c-b5e6-32790488abbc
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