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Tytuł artykułu

The Effect of Different Copper Salts on the Mechanical and Ballistic Characteristics of Double Base Rocket Propellants

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This paper discusses the enhancement in the ballistic performance of double base rocket propellants (DBRPs) by the addition of different copper salts vs lead salts as burning rate modifiers through stable combustion and the formation of a plateau region in the low pressure region. Compositions based on DBRPs containing different percentages of lead stearate and different types of copper salts were prepared and studied. For comparison, a conventional DBRP was studied. The ignition temperature and heat of combustion were determined experimentally, and the mechanical properties were measured and evaluated. The performance in terms of ballistic characteristics (burning rate, operating pressure) were measured at different throat diameters (8, 8.5, 9, 9.5 mm) and at different temperatures (−20 and 50 °C). Specific impulses were calculated using the ICT thermodynamic code. The experimental data from the proportional study indicate that the compositions containing the studied burning rate modifiers are superior to the original DBRP in respect of ballistic performance and mechanical properties.
Rocznik
Strony
469--482
Opis fizyczny
Bibliogr. 23 poz., rys., poz.
Twórcy
  • Department of Chemistry, Faculty of Science, Cairo University, Giza, Egypt
autor
  • Military Technical College, Kobry Elkobbah, Cairo, Egypt
autor
  • Center of Excellence in Scientific and Technological, Ministry of Military Production, El-Salam, Egypt
Bibliografia
  • [1] Venkatachalam S., Santhosh G., Ninan K.N., High Energy Oxidisers for Advanced Solid Propellants and Explosives, Advances in Solid Propellant Technology, 1st Int. HEMS1 Workshop, Ranchi, India, 2002, 87.
  • [2] Folly P., Mäder P., Propellant Chemistry, CHIMIA Int. J. Chem., 2004, 58, 374.
  • [3] Fry R.S., Solid Propellant Test Motor Scaling, The Johns Hopkins University, Chemical Propulsion Information Agency, Columbia, Maryland, 2001.
  • [4] Nadir Y., Burl D., Walter G., William E., Solid Propellant Burning Rate from Strand Burner Pressure Measurement, Propellants Explos. Pyrotech., 2008, 33,109.
  • [5] Yasuyoshi M., Kazuo H., Effect of Initial Temperature and Pressure on the Burning Rate of AGAT/AN Mixtures, J. Energ. Mater., 2011, 29, 26.
  • [6] Joshi A.D., Singh H., Effect of Certain Lead and Copper Compounds as Ballistic Modifier for Double Base Rocket Propellants, J. Energ. Mater., 1992, 10, 299.
  • [7] Singh H., Rao K.R.K., Raman K.V., Ballistic Modification of Composite Modified Double-Base Propellants Containing Ammonium Perchlorate, Propellants Explos. Pyrotech., 1987, 13, 13.
  • [8] Singh H., Rao K.R.K., Thermal Decomposition Studies of Catalysed Double Base Propellants, Proc. Indian Acad. Sci. (Chem. Sci.), 1984, 93(2), 93.
  • [9] Stiles S., McCool P., Ballistic Modifier Formulation for Double Base Propellant, US Patent 8,864,923 B1, 2014.
  • [10] Demidova L.A., Denisyuk A.P., Effect of Some Catalysts on Combustion of Doublebase Propellants, Comb. Expl. Shock Waves (Engl. Transl.), 2004, 311.
  • [11] Chen P., Zhao F.Q., Luo Y., Hu R.Z., Gao S.L., Zheng Y.M., Deng M.Z., Gao Y., Thermal Decomposition Behavior and Non-isothermal Decomposition Reaction of Copper(II) Salt of 4-Hydroxy-3,5-dinitropyridine Oxide and Its Application in Solid Rocket Propellant, Chinese J. Chem., 2004, 22, 1056.
  • [12] Yi J.H., Zhao F.Q., Wang B.Z., Liu Q., Zhou C., Hu R.Z., Ren Y.H., Xu S.Y., Xu K.Z, Ren X.N., Thermal Behaviors, Nonisothermal Decomposition Reaction Kinetics, Thermal Safety and Burning Rates of BTATz-CMDB Propellant, J. Hazard. Mater., 2010, 181, 432.
  • [13] Singh H., Rao K.R.K., Mechanism of Combustion of Catalyzed Double Base Propellants, Combust. Flame, 1988, 71, 205.
  • [14] Muller D., Stewart J., Twin Screw Extrusion for the Production of Stick Propellants, J. Hazard. Mater., 1984, 9, 47.
  • [15] Suceska M., Test Methods for Explosives, Springer, Heideleberg, 1995; ISBN 9780387945552.
  • [16] Herder G., Weterings F.P., Klerk W.P.C.D., Mechanical Analysis on Rocket Propellants, J. Therm. Anal. Calorim., 2003, 72, 921.
  • [17] Frosch R.A., Ramohalli N.R.K., Silicone Containing Solid Propellant, US Patent 4210474, 1998.
  • [18] Bathelt H., Volk F., The ICT-Thermochemical Data Base, 27th Int. Annu. Conf. ICT, Karlsruhe, Germany, 1996, 91.
  • [19] Volk F., Bohn M.A., Wunsch G., Determination of Chemical and Mechanical Properties of Double Base Propellants during Aging, Propellants Explos. Pyrotech., 1987, 13, 81.
  • [20] De Luca L., Price E.W., Summerfield M., Nonsteady Burning and Combustion Stability of Solid Propellants, in: Progress in Astronautic and Aeronautics, vol. 143, AIAA, Washington, DC, 1992, ISBN 978-1-56347-014-1.
  • [21] French J.C., Non-Linear Combustion Stability Prediction of SRMs Using SPP/SSP, 39th AIAA Joint Propulsion Conference, Huntsville, AL, 20-23 July 2003.
  • [22] Fry R.S., Solid Propellant Subscale Burning Rate Analysis Methods for U.S. and Selected NATO Facilities, The Johns Hopkins University, Chemical Propulsion Information Agency, Columbia, Maryland, 2002.
  • [23] Lengellé G., Duterque J., Trubert J.F., Combustion of Solid Propellants, the RTO/ VKI Special Course on Internal Aerodynamics in Solid Rocket Propulsion, held in Rhode-Saint-Genèse, Belgium, 27-31 May 2002, and published in RTO-EN-023, 2004, ISBN 92-837-1103-3.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e38d6890-33b8-4141-ba20-568cddae9245
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