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Tetracycline removal from water by adsorption on geomaterial, activated carbon and clay adsorbents

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The use of antibiotics for breeding and for humans increased considerably in recent years, as a dietary supplement to enhance animal growth. This frequent use leads to the detection of residues in water and wastewater. Thus, the emergence of new strains of bacteria resistant to these antibiotics and, can lead to incurable diseases of livestock, and can lead to a possible transmission of these strains to humans. The purpose of this work is to develop new materials based on treated Maghnia clay, activated carbon, cement, and PVA polymer, named geomaterials. These materials were intended for the containment of hazardous wastes in landfills. The removal of tetracycline from aqueous solution was tested by adsorption onto synthesised geomaterials and their mineral constituents. Adsorption kinetics revealed that tetracycline was rapidly retained by GM and ATMa. This was confirmed by the relatively short equilibrium time of 30 min. The pseudo-second-order and intraparticle models well fitted the adsorption kinetic of the TC-adsorbent studied systems. It was noticed that the adsorption kinetic passes through several mechanisms, was demonstrated by the multi-linearity on the plot of qt against the square root of t. The adsorption capacity (Qa) of TC onto GM is pH-dependent. Indeed, Qa reaches a maximum value (Qa = 12.58 mg · g–1 at a very acidic pH of 2, then the adsorbed amount decreases to reach a minimum value at pH of 8, and for basic pHsQa increases up to 10 mg · g–1.
Rocznik
Strony
303--328
Opis fizyczny
Bibliogr. 193 poz., il., tab., wykr., zdj.
Twórcy
  • Scientific and Technical Research Center in Physico-Chemical Analysis, PO box 384, Headquarters ex-Pasna Industrial area Bou-Ismail, zip code 42004 Tipaza, Algeria, phone +213(0)24325774, fax +213(0)24325774
  • LPCEMAE Laboratory, Faculty of Chemistry, Houari Boumediene University of Science and Technology (USTHB), PO box 32 ELALIA, Bab Ezzouar Algiers, Algeria
  • Controlled Porosity Materials Team, Institute of Materials Sciences of Mulhouse UMRCNRS 7361, University of Strasbourg, University of Haute Alsace, ENSCMu, 3 rue Alfred Werner, 68093 Mulhouse Cedex, France
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Uwagi
1. This work was carried out at the IS2M institute, at the laboratory of Equipe des materiaux à porositécontrôllée de Mulhouse France, and funded by the Ministry of Higher Education and Research (Algeria).
2. Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e38224a6-cfcb-41ac-9a3f-9eb946bf6070
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