Photochromic Polypropylene Filaments: Impacts of Mechanical Properties on Kinetic Behaviour

• Autorzy: Periyasamy Aravin Prince , Viková Martina , Vik Michal

Identyfikatory

DOI

10.5604/01.3001.0013.0738

Warianty tytułu

PL

Fotochromowe włókna polipropylenowe: wpływ właściwości mechanicznych na zachowanie kinetyczne

• Języki publikacji: EN

Abstrakty

EN

Spiro [2H-indole-2,3’–[3H]naphth[2,1-b][1,4]oxazine],1,3-dihydro-1,3,3-trimethyl-6’–(1-piperidinyl) was incorporated onto polypropylene and photochromic polypropylene multifilaments produced through the mass coloration technique. Subsequently the polypropylene (PP) filaments were doped with a different concentration of photochromic pigment, and after producing the filaments different drawing ratios were applied. The photochromic colour build was found to be maximum with the highest concentration of dyes as well as with the lowest drawing ratio. Also the colour differences for L*, a*, b* and ΔE* were analysed with respect to the different concentrations and drawing ratios of the filament. The filaments generally showed good stability of photocoloration during the colour measurement till five cycles. The results for the optical density were reduced by increasing the fineness of the filament. In this experimental work, the impact of the drawing ratio on the optical and mechanical properties of these multifilaments were investigated.

PL

W pracy przedstawiono efekty wprowadzenia spiro [2H-indolo-2,3’ ‚– [3H] nafta [2,1-b][1,4] oksazyna], 1,3-dihydro-1,3,3-trimetylo-6’ – (1- piperydynylu) do polipropylenu i fotochromowych polipropylenowych multifilamentów wytwarzanych techniką masowego zabarwienia. Następnie włókna polipropylenowe (PP) domieszkowano różnym stężeniem pigmentu fotochromowego, a po wytworzeniu włókien zastosowano różne współczynniki rozciągania. Stwierdzono, że kolor fotochromowy jest maksymalny przy najwyższym stężeniu barwników, jak również przy najniższym stosunku rozciągania. Analizowano również różnice koloru dla L*, a*, b* i ΔE* w odniesieniu do różnych stężeń i współczynników rozciągania. Włókna na ogół wykazywały dobrą stabilność fotokoloracji podczas pomiaru barwy do pięciu cykli. Wyniki gęstości optycznej zmniejszono przez zwiększenie rozdrobnienia włókna. W pracy zbadano również wpływ współczynnika rozciągania na właściwości optyczne i mechaniczne włókien.

Słowa kluczowe

EN

coloration; drawing process; photochromism; polypropylene; kinetic properties; mass coloration; mechanical properties

PL

barwienie; fotochromizm; polipropylen; właściwości kinetyczne włókien; właściwości mechaniczne włókien

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2019
• Tom: Vol. 27, no. 3 (135)
• Strony: 19--25
• Opis fizyczny: Bibliogr. 32 poz., rys.

Twórcy

autor

Periyasamy Aravin Prince

• Technical University of Liberec, Department of Material Engineering, Laboratory of Color and Appearance Measurement (LCAM), Czech Republic

autor

Viková Martina

• Technical University of Liberec, Department of Material Engineering, Laboratory of Color and Appearance Measurement (LCAM), Czech Republic

autor

Vik Michal

• Technical University of Liberec, Department of Material Engineering, Laboratory of Color and Appearance Measurement (LCAM), Czech Republic

Bibliografia

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).