Removal of methylene blue from aqueous solutions via adsorption on activated biocarbon obtained from post-extraction residue

• Autorzy: Przytulska Agata , Gargol Mateusz , Gil-Kowalczyk Małgorzata , Nowicki Piotr

Identyfikatory

DOI

10.37190/ppmp/146709

• Konferencja: Physicochemistry of interfaces - instrumental methods (22-26.08.2021 ; Lublin, Poland)
• Języki publikacji: EN

Abstrakty

EN

This paper deals with adsorption of a cationic dye – methylene blue - on the activated biocarbon obtained via chemical activation of horsetail herb post-extraction residue. The effects of initial dye concentration, temperature, solution pH, as well as the phase contact time on the adsorption effectiveness have been tested. The adsorbent prepared was characterized based on the results of elementary analysis, surface area measurements, thermal analysis as well as determination of the acid-base nature of its surface. It has been shown that micro/mesoporous horsetail herb-based activated biocarbon exhibits a significantly higher ability to methylene blue uptake than the commercial activated carbon prepared from peat. It has been also found that the adsorption capacity increases with the increasing initial dye concentration in the solution and the phase contact time. The maximum adsorption toward methylene blue was found at pH=12 and at temperature of 40 C. A better fit to the experimental data was obtained with a Langmuir isotherm than Freundlich one, whereas better fit of the kinetic data was achieved using the pseudo-second order model.

Słowa kluczowe

EN

post-extraction residue; chemical activation; activated biocarbon; methylene blue; adsorption

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2022
• Tom: Vol. 58, iss. 2
• Strony: art. no. 146709
• Opis fizyczny: Bibliogr. 28 poz., rys., wykr.

Twórcy

autor

Przytulska Agata

• Adam Mickiewicz University in Poznań, Faculty of Chemistry, Laboratory of Applied Chemistry, Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland

autor

Gargol Mateusz

• Maria Curie-Sklodowska University in Lublin, Faculty of Chemistry, Institute of Chemical Sciences, Laboratory of Optical Fibers Technology, M. Curie-Sklodowska Sq. 5, 20-031 Lublin, Poland

autor

Gil-Kowalczyk Małgorzata

• Maria Curie-Sklodowska University in Lublin, Faculty of Chemistry, Institute of Chemical Sciences, Laboratory of Optical Fibers Technology, M. Curie-Sklodowska Sq. 5, 20-031 Lublin, Poland

autor

Nowicki Piotr

• Adam Mickiewicz University in Poznań, Faculty of Chemistry, Laboratory of Applied Chemistry, Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland

• https://orcid.org/0000-0002-8345-2146

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).