The structure of electrical double layer formed on the kaolinite surface in the mixed system of cationic polyacrylamide and lead (II) ions

• Autorzy: Fijałkowska Gracja , Wiśniewska Małgorzata , Szewczuk-Karpisz Katarzyna

Identyfikatory

DOI

10.5277/ppmp19044

• Języki publikacji: EN

Abstrakty

EN

The bioavailability of toxic heavy metalsfor organisms depends mainly on the soil physicochemical properties, i.e. type and granulometric composition, pH value, redox potential, individual fractions content and microorganisms presence. The addition of artificial fertilizers rich in humic substances or polyacrylamide soil flocculants may also affect the content of easily absorbed heavy metal forms. Due to their chelating properties, the added substances can bind metal ions in the form of complexes characterized by low mobility in soil environment. As a consequence, the immobilization process takes place, which is a desirable phenomenon for organism health.The aim of the study was to determine the structure of electrical double layer formed on the kaolinite surface in the mixed system of cationic polyacrylamide and lead(II) cations. The influence of cationic PAM presence on the Pb(II) ions sorption on the kaolinite surface as well as heavy metal ion addition on the polymer adsorbed amount on the same clay mineral were studied. The adsorption and electrokinetic properties of studied kaolinite/CT PAM/Pb(II) systems were determined based on the spectrophotometric study, zeta potential measurements as well as potentiometric titration.

Słowa kluczowe

EN

kaolinite; cationic PAM; Pb(II) ions; electrical double layer; adsorption

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2019
• Tom: Vol. 55, iss. 6
• Strony: 1339--1349
• Opis fizyczny: Bibliogr. 45 poz., rys., wz., wykr.

Twórcy

autor

Fijałkowska Gracja

• Department of Radiochemistry and Colloids Chemistry, Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq.3, 20-031 Lublin, Poland

autor

Wiśniewska Małgorzata

• Department of Radiochemistry and Colloids Chemistry, Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq.3, 20-031 Lublin, Poland

autor

Szewczuk-Karpisz Katarzyna

• Institute of Agrophysics, Polish Academy of Sciences, Doświadczalna 4, 20-290 Lublin, Poland

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).