The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main Plasticizer

• Autorzy: Song F. , Xia H. , Jia P. , Zhang M. , Hu L. , Zhou Y.

Identyfikatory

DOI

10.2478/pjct-2018-0048

• Języki publikacji: EN

Abstrakty

EN

In this work, an environmentally friendly type plasticizer was introduced. The synthesis consisted of two steps. In the first step, castor oil (CO) was acrylated and then the acrylated castor oil (ACO) was epoxidized with the presence of formic acid and hydrogen peroxide in the second step. The epoxidized acrylated castor oil (EACO) was characterized by FTIR and  ¹H-NMR techniques. The EACO was used as a main plasticizer to obtain plasticized PVC materials and compared with DOP. The results showed that EACO improved polyvinyl-chloride (PVC) plasticization performance and reduced Tg from 81.06°C to 1.40°C. Plasticized PVC materials with EACO showed similar mechanical properties and better thermal stability than DOP. EACO had better volatility stabilities, migration and solvent extraction in PVC than DOP. EACO can be used to replace DOP to prepare soft films.

Słowa kluczowe

EN

Castor Oil; Poly(vinyl chloride); Epoxy Plasticizer; thermal property; Migration Resistance

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2018
• Tom: Vol. 20, nr 4
• Strony: 13--19
• Opis fizyczny: Bibliogr. 41 poz., rys., tab.

Twórcy

autor

Song F.

• Chinese Academy of Forestry (CAF), Institute of Chemical Industry of Forest Products, National Engineering Lab for Biomass Chemical Utilization, Key Lab on Forest Chemical Engineering, State Forestry Administration and Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road, Nanjing 210042, P.R. China

autor

Xia H.

• Nanjing Tech University, College of Chemical Engineering, 30 Pu Zhu Road, Nanjing 211800, P.R. China

autor

Jia P.

• Chinese Academy of Forestry (CAF), Institute of Chemical Industry of Forest Products, National Engineering Lab for Biomass Chemical Utilization, Key Lab on Forest Chemical Engineering, State Forestry Administration and Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road, Nanjing 210042, P.R. China
• Nanjing Forestry University, Co-Innovation Center of Effi cient Processing and Utilization of Forest Resources, Nanjing 211800, P.R. China

autor

Zhang M.

• Chinese Academy of Forestry (CAF), Institute of Chemical Industry of Forest Products, National Engineering Lab for Biomass Chemical Utilization, Key Lab on Forest Chemical Engineering, State Forestry Administration and Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road, Nanjing 210042, P.R. China
• Nanjing Forestry University, Co-Innovation Center of Effi cient Processing and Utilization of Forest Resources, Nanjing 211800, P.R. China

autor

Hu L.

• Chinese Academy of Forestry (CAF), Institute of Chemical Industry of Forest Products, National Engineering Lab for Biomass Chemical Utilization, Key Lab on Forest Chemical Engineering, State Forestry Administration and Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road, Nanjing 210042, P.R. China
• Nanjing Forestry University, Co-Innovation Center of Effi cient Processing and Utilization of Forest Resources, Nanjing 211800, P.R. China

autor

Zhou Y.

• Chinese Academy of Forestry (CAF), Institute of Chemical Industry of Forest Products, National Engineering Lab for Biomass Chemical Utilization, Key Lab on Forest Chemical Engineering, State Forestry Administration and Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road, Nanjing 210042, P.R. China
• Nanjing Forestry University, Co-Innovation Center of Effi cient Processing and Utilization of Forest Resources, Nanjing 211800, P.R. China

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).