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Adsorption of reactive dyes and their mixtures on activated carbon. Kinetics, equilibrium and thermodynamic evaluation

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The adsorption of three reactive dyes (Reactive Bezactiv Yellow (RBY), Reactive Bezactiv Blue (RBB) and Reactive Bezactiv (RBR)) on a commercially available activated carbon (CAC) has been evaluated. It was shown that CAC is capable to effectively remove these dyes from a solution. The adsorption increased with higher contact time, adsorbent dose, and initial dye concentration. The data indicated that the adsorption kinetics of dyes on CAC followed a pseudo-second order model. The adsorption isotherms followed the Langmuir isotherm model. Evaluation of thermodynamic parameters revealed that the adsorption process is endothermic for all dyes and spontaneous in a single system and became spontaneous in mixture systems at high temperature, expect RBY and RBB in the ternary mixture. Adsorption was higher for RBY, followed by RBB, and was lowest for RBR. The total adsorption efficiency was confirmed by chemical oxygen demand (COD) measurements.
Rocznik
Strony
5--24
Opis fizyczny
Bibliogr. 14 poz., tab., rys.
Twórcy
  • LEC-ESITH, Laboratory of Expertise and Control, Higher School of Textile and Clothing Industries, Casablanca, Morocco
  • Mohammed-V University Rabat-EMI, Mohammedia School of Engineering, Environmental and Energy Process (GPEE), Rabat, Morocco
  • Mohammed-V University Rabat-EMI, Mohammedia School of Engineering, Environmental and Energy Process (GPEE), Rabat, Morocco
  • Mohammed-V University Rabat-EMI, Mohammedia School of Engineering, Environmental and Energy Process (GPEE), Rabat, Morocco
autor
  • KU Leuven, Department of Chemical Engineering, Process and Environmental Technology Lab, J. De Nayerlaan 5, B-2860 Sint-Katelijne-Waver, Belgium
Bibliografia
  • [1] DAOUD M., BENTURKI O., KECIRA Z., GIRODS P., DONNOT A., Removal of reactive dye (Bezaktiv Red S-Max) from aqueous solution by adsorption onto activated carbons prepared from date palm rachis and jujube stones, J. Mol. Liq., 2017, 243, 799–809.
  • [2] ALLEGRE C., MOULINE P., MAISSEU M., CHARBIT F., Treatment and reuse of reactive dyeing effluents, J. Membr. Sci., 2006, 269, 15–34.
  • [3] CRACIUNESCU I., PETRAN A., LIEBSCHER J., VEKAS L., TURCU R., Synthesis and characterization of size-controlled magnetic clusters functionalized with polymer layer for wastewater depollution, Mater. Chem. Phys., 2017, 185, 91–97.
  • [4] MANE V.S., VIJAY BABU P.V., Kinetic and equilibrium studies on the removal of Congo Red from aqueous solution using eucalyptus wood (Eucalyptus globulus) saw dust, J. Taiwan Inst. Chem., 2013, 44, 1, 81–88.
  • [5] MAHMOODI N.M., SALEHI R., ARAMI M., Binary system dye removal from colored textile wastewater using activated carbon: Kinetic and isotherm studies, Desalination, 2011, 272 (1–3), 187–195.
  • [6] Water quality. Determination of the chemical oxygen demand index (ST-COD). Small-scale closed- -pipe method, ISO 15705 dco.pdf
  • [7] HAMDAOUI M., TURKI S., ROMDHANI Z., HALAOUA S., Effect of reactive dye mixtures on exhaustion values, Indian J. Fiber Text., 2013, 38, 405–409.
  • [8] SIMONIN J.P., On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics, Chem. Eng. J., 2016, 300, 254–263.
  • [9] FABRYANTY R., VALENCIA C., SOETAREDJO E.F., PUTRO J.N., PERMATASARI SANTOSO S., KURNIAWAN A., JU Y.-H., ISMADJI S., Removal of crystal violet dye by adsorption using bentonite – alginate composite, J. Environ. Chem. Eng., 2017, 5 (6), 5677–5687.
  • [10] RINCÓN-SILVA N.G., MORENO-PIRAJÁN J.C., GIRALDO L., Equilibrium, kinetics and thermodynamics study of phenols adsorption onto activated carbon obtained from lignocellulosic material (Eucalyptus globulus Labill seed), Adsorption, 2016, 22 (1), 33–48.
  • [11] BENTAHAR S., DBIK A., KHOMRI M.E., MESSAOUDI N.E., LACHERAI A., Adsorption of Methylene Blue, Crystal Violet and Congo Red from binary and ternary systems with natural clay. Kinetics, isotherm, and thermodynamics, J. Environ. Chem. Eng., 2017, 5 (6), 5921–5932.
  • [12] ALDEGS Y., ELBARGHOUTHI M., ELSHEIKH A., WALKER G., Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon, Dyes Pigm., 2008, 77 (1), 16–23.
  • [13] REN T.-Z., ZHU X.-H., MA T.-Y., YUAN Z.-Y., Adsorption of Methylene Blue from aqueous solution by periodic mesoporous titanium phosphonate materials, Ads. Sci. Technol., 2013, 31 (6), 535–548.
  • [14] OLADIPO A.A., GAZI M., YILMAZ E., Single and binary adsorption of azo and anthraquinone dyes by chitosan-based hydrogel. Selectivity factor and Box–Behnken process design, Chem. Eng. Res. Des., 2015, 104, 264–279.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e191e866-6af8-4929-9377-9c3f42ce0c3d
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