High Efficient Photocatalytic Degradation of Methyl Orange Dye in an Aqueous Solution by CoFe2O4-SiO2-TiO2 Magnetic Catalyst

• Autorzy: Hariani Poedji Loekitowati , Said Muhammad , Salni , Aprianti Nabila , Naibaho Yohanna Asina Lasma Rohana

Identyfikatory

DOI

10.12911/22998993/143908

• Języki publikacji: EN

Abstrakty

EN

This study successfully synthesized a core-shell-shell in the form of CoFe₂O₄-SiO₂-TiO₂ catalyst magnetic and recyclable. The catalyst was employed for the photocatalytic degradation of methyl orange (MO) dye. Subsequently, the catalyst was subjected to XRD, FTIR, SEM-EDS, VSM, as well as UV-DRS characterizations. The photocatalytic degradation was studied as a function of the solution pH, MO concentration, and irradiation time, while the kinetics of photocatalytic degradation and the catalyst reusability were also evaluated. On the basis of the XRD, FTIR, and SEM-EDS characterizations, the CoFe₂O₄ coating was successfully carried out using SiO₂ and TiO₂. CoFe₂O₄-SiO₂-TiO₂ was discovered to possess magnetic properties with a saturation magnetization of 17.59 emu/g and a bandgap value of 2.4 eV. The photocatalytic degradation of MO followed the Langmuir-Hishelwood model. The optimum degradation was obtained at the MO concentration of 25 mg/L, solution pH of 4, catalyst dose of 0.05 g/L, irradiation time of 160 minutes, MO removal efficiency achieved 93.46%. The regeneration study showed CoFe₂O₄-SiO₂-TiO₂ after 5 cycles were able to catalyze the photocatalytic degradation with an MO removal efficiency of 89.96%.

Słowa kluczowe

EN

magnetic; degradation; photocatalytic; methyl orange

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2022
• Tom: Vol. 23, nr 1
• Strony: 118--128
• Opis fizyczny: Bibliogr. 43 poz., rys., tab.

Twórcy

autor

Hariani Poedji Loekitowati

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jalan Palembang-Prabumulih, Indralaya, Ogan Ilir, Indonesia

• https://orcid.org/0000-0002-3436-7199

autor

Said Muhammad

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jalan Palembang-Prabumulih, Indralaya, Ogan Ilir, Indonesia

• https://orcid.org/0000-0003-2513-2571

autor

Salni

• Department of Biology, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jalan Palembang-Prabumulih, Indralaya, Ogan Ilir, Indonesia

autor

Aprianti Nabila

• Doctoral Program of Environmental Science, Graduate School, Sriwijaya University, Jalan Padang Selasa 524 Bukit Besar, Palembang 30139, South Sumatra, Indonesia

• https://orcid.org/0000-0002-7391-5178

autor

Naibaho Yohanna Asina Lasma Rohana

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jalan Palembang-Prabumulih, Indralaya, Ogan Ilir, Indonesia

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