Adsorptive molecularly imprinted composite membranes for chiral separation of phenylalanine

• Autorzy: Shah N. , Rehan T. , Park J. K.

Identyfikatory

DOI

10.1515/pjct-2016-0044

• Języki publikacji: EN

Abstrakty

EN

Two types of composite imprinted membranes, i.e., composite membrane comprised of D-Phe imprinted beads and D-Phe imprinted membrane or DCM and composite membrane comprised of L-Phe imprinted beads and L-Phe imprinted membranes or LCM, were synthesized by phase inversion technique after a uniform dispersion of beads within the polymeric solutions using simple physico-mechanical process. The assemblies of the prepared DCM, LCM and control membranes were employed in ultrafiltration for chiral separation of D, L-Phenylalanine racemate solution. DCM and LCM showed an improved adsorption capacity (0.334 mg g^-1 and 0.365 mg g^-1 respectively), and adsorption selectivity (2.72 and 2.98 respectively). However, the percent rejection of the template and counter enantiomer were lower than that of control membranes. Compared to control membrane, the DCM and LCM showed inverse permselectivity. These composite membranes having better adsorption and separation ability for Phenylalanine racemate solution will be suitable in the future for various other applications.

Słowa kluczowe

EN

molecularly imprinted composite membranes; Phe imprinted beads; Phe imprinted membranes; ultrafiltration; adsorption selectivity

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2016
• Tom: Vol. 18, nr 3
• Strony: 22--29
• Opis fizyczny: Bibliogr. 42 poz., rys., tab.

Twórcy

autor

Shah N.

• Kyungpook National University, Department of Chemical Engineering, Taegu, Korea Pakistan
• Abdul Wali Khan University Mardan, Department of Chemistry, Mardan, Pakistan

autor

Rehan T.

• Quaid-i-Azam University, Department of Biochemistry, Islamabad, Pakistan

autor

Park J. K.

• Kyungpook National University, Department of Chemical Engineering, Taegu, Korea Pakistan

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.