Adsorption of Ni2+ from aqueous solution by magnetic Fe@graphite nano-composite

Konicki, W.; Pelka, R.; Arabczyk, W.

doi:10.1515/pjct-2016-0077

Artykuł - szczegóły

Tytuł artykułu

Adsorption of Ni2+ from aqueous solution by magnetic Fe@graphite nano-composite

Autorzy

Konicki W. , Pelka R. , Arabczyk W.

Treść / Zawartość

Pełne teksty:

Polish Journal of Chemical Technology_4_2016_Konicki.pdf

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Identyfikatory

DOI

10.1515/pjct-2016-0077

Warianty tytułu

Języki publikacji

Abstrakty

The removal of Ni²⁺ from aqueous solution by iron nanoparticles encapsulated by graphitic layers (Fe@G) was investigated. Nanoparticles Fe@G were prepared by chemical vapor deposition CVD process using methane as a carbon source and nanocrystalline iron. The properties of Fe@G were characterized by X-ray Diffraction method (XRD), High-Resolution Transmission Electron Microscopy (HRTEM), Fourier Transform-Infrared Spectroscopy (FTIR), BET surface area and zeta potential measurements. The effects of initial Ni²⁺ concentration (1–20 mg L⁻¹ ), pH (4–11) and temperature (20–60°C) on adsorption capacity were studied. The adsorption capacity at equilibrium increased from 2.96 to 8.78 mg g⁻¹ , with the increase in the initial concentration of Ni²⁺ from 1 to 20 mg L⁻¹ at pH 7.0 and 20°C. The experimental results indicated that the maximum Ni²⁺ removal could be attained at a solution pH of 8.2 and the adsorption capacity obtained was 9.33 mg g⁻¹ . The experimental data fitted well with the Langmuir model with a monolayer adsorption capacity of 9.20 mg g⁻¹ . The adsorption kinetics was found to follow pseudo-second-order kinetic model. Thermodynamics parameters, ΔHO, ΔGO and ΔSO, were calculated, indicating that the adsorption of Ni²⁺ onto Fe@G was spontaneous and endothermic in nature.

Słowa kluczowe

magnetic nanocomposite iron nanoparticles nickel adsorption

Wydawca

West Pomeranian University of Technology. Publishing House

Czasopismo

Polish Journal of Chemical Technology

Rocznik

2016

Tom

Vol. 18, nr 4

Strony

96--103

Opis fizyczny

Bibliogr. 64 poz., rys., tab.

Twórcy

autor

Konicki W.

w.konicki@am.szczecin.pl

Maritime University of Szczecin, Department of Integrated Transport Technology and Environmental Protection, Henryka Pobożnego St. 11, 70-507 Szczecin, Poland

autor

Pelka R.

West Pomeranian University of Technology, Szczecin, Institute of Chemical and Environment Engineering, Pułaskiego St. 10, 70-322 Szczecin, Poland

autor

Arabczyk W.

West Pomeranian University of Technology, Szczecin, Institute of Chemical and Environment Engineering, Pułaskiego St. 10, 70-322 Szczecin, Poland

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-e03c4a57-0ec9-4d91-bbff-47db68f9a6fc