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The research aimed at the selection of polyurethanes synthesized from poly(tetramethylene ether) glycol (PTMEG), as well as from two different isocyanates 4,4′-methylenebis(cyclohexyl)isocyanate (HMDI) and 4.4′-methylenebis(phenyl isocyanate) (MDI) in order to obtain polyurethane with increased resistance to abrasive wear and degradation for bio-medical application. Polyurethanes were fabricated from crystalline prepolymers extended by water. The paper presents preliminary results on polyurethane surface wettability, friction coeffi cient for different couples of the co-working materials such as polyurethane–polyurethane, polyurethane–titanium alloy, polyurethane–alumina, in comparison to commonly used polyethylene–titanium alloy. Shear strength of polyurethane–alumina joint, as well as viscosity of prepolymers were also measured. The values of friction coeffi cient were compared to literature data on commercially available polyurethane with the trade name Pellethane. Polyurethanes obtained are characterized by low abrasive wear and low friction coeffi cient in couple with the titanium alloy, what makes them attractive as possible components of ceramic-polymer endoprosthesis joints.
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14--20
Opis fizyczny
Bibliogr. 26 poz., rys., tab., zdj.
Twórcy
autor
- agata.domanska@inmat.pw.edu.pl
autor
- Warsaw University of Technology, Faculty of Materials Science and Engineering, Woloska 141, 02-507 Warsaw, Poland
autor
- Warsaw University of Technology, Faculty of Materials Science and Engineering, Woloska 141, 02-507 Warsaw, Poland
autor
- Institute of Ceramics and Building Materials, Postepu 9, 02-676 Warsaw, Poland
- Bialystok University of Technology, Faculty of Mechanical Engineering, Wiejska 45C, 15-351 Białystok, Poland
Bibliografia
- 1. Nair, L.S., Laurencin, C.T. (2007). Biodegradable polymers as biomaterials Prog. Polym. Sci. 32, 762–798. DOI: 10.1016/j. progpolymsci.2007.05.017.
- 2. Oledzka, E., Sobczak, M. & Kołodziej, W.L. (2007). Polymers in medicine – review of past achievements. Polimery 11–12, 793, in Polish.
- 3. Ryszkowska, J.L., Auguścik, M., Sheikh, A. & Boccaccini, A.R. (2010). Biodegradable polyurethane composite scaffolds containing Bioglass® for bone tissue engineering. Comp. Sci. Tech. 70, 1894–1908. DOI: 10.1016/j.compscitech.2010.05.011.
- 4. Waśniewski, B., Auguścik, M., Parzuchowski, P., Zielecka, M. & Ryszkowska, J. (2012). Polycarbonate urethane nanocomposites with nanosilica for implants of the intervertebral disc. Polimery 11–12, 812, in Polish.
- 5. Domańska, A., Boczkowska, A., Izydorzak, M., Jaegermann, Z. & Kurzydłowski, K.J. (2010). Polyurethanes used In the endoprosthesis of joints. Pol. J. Chem. Tech. 12, 3, 10–14. DOI: 10.2478/v10026-010-0025-y.
- 6. Jaegermanna, Z., Boczkowska, A., Paszewska, A. & Michałowski, S. (2008). Ceramic-polymer gradient composite for joint endoprosthesis application – preliminary report. Pr. Komis. Nauk Ceram. PAN, CERAMIKA, 101, 41–48, in Polish
- 7. Jaegermann, Z., Boczkowska, A., Domańska, A. & Michałowski, S. (2008). Composite biomaterial alumina-polyurethane. Pr. Inst. Szkła, Ceramiki, Materiałów Ogniotrwałych i Budowlanych 2, 7–22, in Polish.
- 8. Gruin, I., Markiewicz, B., Ryszkowska, J., Pacułt, J., Lubaszka, J., Kocjan, R. & Pasik, J. (1993). ”The method of cold cure elastomers fabrication”, Know-how no WP/20/93 from 26.03.93 Politechnika Warszawska, in Polish.
- 9. Boczkowska, A. & Gruin, I. (1999). Polyurethanes from crystalline prepolymers. Eur. Polym. J. 35, 1569–1579.
- 10. Boczkowska, A. (2000). Structural polymers obtained from crystalline ether-urethane-isocyanate prepolymers. PhD thesis, Warszawa, in Polish.
- 11. Izydorzak, M. (2009). Selection of polyurethanes with increased resistance to abrasive wear for biomedical applications. MSc Thesis – Politechnika Warszawska, Warszawa, in Polish.
- 12. Wirpsza, Z. (1991). Polyurethanes. Chemistry, technology, applications. Warszawa: WNT, in Polish.
- 13. Guess, J.F. & Campbell, J.S. (1995). Acoustic properties of some biocompatible polymers at body temperature. Ultrasound in Medicine & Biology Vol. 21(2), 273–277.
- 14. Rudnik, E., Resiak, I. & Wojciechowski, C. (1998) Thermoanalytical investigations of polyurethanes for medical purposes. Thermochimica Acta 320, 285–289.
- 15. Martin, D.J., Poole Warren, L.A., Gunatillake, P.A., Mc-Carthy, S.J., Meijs, G.F. & Schindhelm, K. (2000). Polydimethylsiloxane/polyether-mixed macrodiol-based polyurethaneelastomers:biostability. Biomaterials, 1021–1029.
- 16. Ojha, U., Kulkarni, P., Faust, R. (2009). Syntheses and characterization of novel biostable polyisobutylene based thermoplastic polyurethanes. Polymer 50, 3448–3457.
- 17. Poussard, L., Burel, F., Couvercelle, J.P., Merhi, Y., Tabrizian, M. & Bunel, C. (2004). Hemocompatibilty of New ionic polyurethanes: infl uence of carboxylic group insertion modes. Biomaterials 25, 3473–3483. DOI: 10.1016/j.biomaterials. 2003.10.069.
- 18. Yamamoto, K., Kiura, T., Nam, K., Funamoto, S., Ito, Y., Shiba, K., Katoh, A., Shimizu, S., Kurita, K., Higami, T., Masuzawa, T. & Kishida, A. (2011). Synthetic polymer-tissue adhesion Rusing an ultrasonic scalpel. Surg. Endosc. 25, 1270–1275. DOI: 10.1007/s00464-010-1357-7.
- 19. Żenkiewicz, M. (2000). Adhesion and modifi cation of the surface layer of macromolecular materials. Warszawa, WNT, in Polish.
- 20. Olczyk, W. (1968). Polyurethanes. Warszawa, WNT, In Polish.
- 21. Rymuza, Z. (1986). Tribology of polymers sliping Warszawa, WNT, in Polish.
- 22. Schwart, Ch.J. & Bahadur, S. (2006). Development and testing of a novel joint wear Simulator and investigation of the viability of an elastomeric polyurethane for total-joint arthroplasty devices. Wear 262, 332–339. DOI: 10.1016/j.wear.2006.05.018.
- 23. Guan, J., Fujimoto, K.L., Sacks, M.S. & Wagner, W.R. (2005). Preperation and characterization of highly porous, biodegradable polyurethane scaffolds for soft tissue applications. Biomaterials 26, 3961. DOI: 10.1016/j.biomaterials.2004.10.018.
- 24. Gorna, K. & Gogolewski, S. (2002). Biodegaradable polyurethanes for implants. II. In vitro degradation and calcifi cation of materials from poly(e-caprolactone)–poly(ethylene oxide) diols and various chain extenders. J. Biomed. Mater. Res., 60(4), 592–606.
- 25. Guan, J., Sacks, M.S., Beckman, E.J. & Wagner, W.R. (2002). Synthesis, characterization, and cytocompatibility of elastomeric, biodegradable poly(ester-urethane)ureas based on poly(caprolactone) and putrescine. J. Biomed. Mater. Res. 61(3), 493–503.
- 26. Gogolewski, S. & Gorna, K. (2007). Biodegradable polyurethane cancellous bone graft substites in the treatment of iliac crest defects. J. Biomed. Mater. Res. Part A, Volume 80A, Issue 1, 94–101. DOI: 10.1002/jbm.a.30834.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e002521b-4357-4b54-bf9c-a5023711be58