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The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption

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EN
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EN
The performance of adsorbent synthesized by alkali activation of aluminosilicate precursor metakaolin with sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) as well as the foaming agent was studied for copper ions adsorption from aqueous solution. This paper investigated the effect of adding hydrogen peroxide (H2O2) and aluminium powder as foaming agents to an alkali activated materials slurry. The experimental range included 0.50 wt%, 0.75 wt%, and 1.00 wt% hydrogen peroxide and 0.02 wt%, 0.04 wt%, and 0.06 wt% aluminium powder. A control sample without a foaming agent was also created for comparison. The specific surface area, water absorption, density, compressive strength and microstructure of metakaolin based alkali activated materials were evaluated. The adsorption capability of Cu2+ with addition of hydrogen peroxide and aluminium powder was then tested. Results indicate hydrogen peroxide addition had superior pore size distribution and homogeneous porosity than aluminium powder, implying improved copper ion elimination. Cu2+ adsorption capability reached 98% with 0.75 wt% hydrogen peroxide and 24.6076 m2/g surface area. The results demonstrating that low cost metakaolin-based AAMs are the most effective adsorbent for removing copper ions.
Twórcy
  • Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, Malaysia
  • Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CeGeoGTech), 02600, Arau, Perlis, Malaysia
  • Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CeGeoGTech), 02600, Arau, Perlis, Malaysia
  • Universiti Malaysia Perlis (UniMAP), Faculty of Mechanical Engineering Technology, 02600, Arau, Perlis, Malaysia
  • Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, Malaysia
  • Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CeGeoGTech), 02600, Arau, Perlis, Malaysia
  • Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, Malaysia
  • Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, Malaysia
  • Universiti Tun Hussein Onn Malaysia, Faculty of Engineering Technology, Johor, Malaysia
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Uwagi
The author would like to acknowledge the support from the Fundamental Research Grant Scheme (FRGS) under a grant number of FRGS/1/2019/TK10/UNIMAP/02/21 from the Ministry of Education Malaysia.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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