The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu²⁺ Adsorption

• Autorzy: Ibrahim Masdiyana , Ibrahim Wan Mastura Wan , Abdullah Mohd Mustafa Al Bakri , Mahamud L.H. , Tajuddin Muhammad Noorfadzlin Najmi , Yahya Nur Faezah

Identyfikatory

DOI

10.24425/amm.2023.145478

• Języki publikacji: EN

Abstrakty

EN

The performance of adsorbent synthesized by alkali activation of aluminosilicate precursor metakaolin with sodium hydroxide (NaOH) and sodium silicate (Na₂SiO₃) as well as the foaming agent was studied for copper ions adsorption from aqueous solution. This paper investigated the effect of adding hydrogen peroxide (H₂O₂) and aluminium powder as foaming agents to an alkali activated materials slurry. The experimental range included 0.50 wt%, 0.75 wt%, and 1.00 wt% hydrogen peroxide and 0.02 wt%, 0.04 wt%, and 0.06 wt% aluminium powder. A control sample without a foaming agent was also created for comparison. The specific surface area, water absorption, density, compressive strength and microstructure of metakaolin based alkali activated materials were evaluated. The adsorption capability of Cu²⁺ with addition of hydrogen peroxide and aluminium powder was then tested. Results indicate hydrogen peroxide addition had superior pore size distribution and homogeneous porosity than aluminium powder, implying improved copper ion elimination. Cu²⁺ adsorption capability reached 98% with 0.75 wt% hydrogen peroxide and 24.6076 m²/g surface area. The results demonstrating that low cost metakaolin-based AAMs are the most effective adsorbent for removing copper ions.

Słowa kluczowe

EN

metakaolin; alkali activated materials; hydrogen peroxide; aluminium powder adsorption; copper ions adsorption

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2023
• Tom: Vol. 68, iss. 3
• Strony: 1077--1086
• Opis fizyczny: Bibliogr. 69 poz., fot., rys., tab., wzory

Twórcy

autor

Ibrahim Masdiyana

• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CeGeoGTech), 02600, Arau, Perlis, Malaysia

• https://orcid.org/0000-0001-7632-2717

autor

Ibrahim Wan Mastura Wan

• Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CeGeoGTech), 02600, Arau, Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Mechanical Engineering Technology, 02600, Arau, Perlis, Malaysia

• https://orcid.org/0000-0002-6766-3541

autor

Abdullah Mohd Mustafa Al Bakri

• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CeGeoGTech), 02600, Arau, Perlis, Malaysia

• https://orcid.org/0000-0002-9779-8586

autor

Mahamud L.H.

• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, Malaysia

• https://orcid.org/0000-0002-6408-1095

autor

Tajuddin Muhammad Noorfadzlin Najmi

• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, Malaysia

• https://orcid.org/0000-0002-4608-7530

autor

Yahya Nur Faezah

• Universiti Tun Hussein Onn Malaysia, Faculty of Engineering Technology, Johor, Malaysia

• https://orcid.org/0000-0002-5819-1618

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Uwagi

The author would like to acknowledge the support from the Fundamental Research Grant Scheme (FRGS) under a grant number of FRGS/1/2019/TK10/UNIMAP/02/21 from the Ministry of Education Malaysia.