Multi-component sorption and utilization of solid waste to simultaneous removing basic dye and heavy metal from aqueous system

• Autorzy: Sočo Eleonora , Pająk Dariusz , Kalembkiewicz Jan

Identyfikatory

DOI

10.24425/aep.2020.132527

Warianty tytułu

PL

Wieloskładnikowa sorpcja oraz utylizacja odpadu stałego do jednoczesnego usuwania barwnika zasadowego i metalu ciężkiego z układu wodnego

• Języki publikacji: EN

Abstrakty

EN

The presented work introduces a simple modification of coal fly ash (FA) with 30% solution of H₂O₂, used as a new efficient sorbent for the removal of organic dye crystal violet (CV) in the presence of Cu(II) ions in single- and bi-component systems Cu(II)-CV. FT-IR, TG, SEM-EDS, and XRD suggested that the mechanism of Cu(II) and CV sorption onto FA-H2O2 includes ion-exchange and surface adsorption process. Comparing the values of the reduced chi-square test (χ²/DoF) and the determination coefficient R² obtained for CV of the considered isotherms, the fitting degree follows the sequence: Jovanović > Langmuir > Elovich > Freundlich > Redlich-Peterson (R-P) > Tóth > Halsey > BET. Sorption of Cu(II) ions in a single system by means of FA-H₂O₂ was well fitted by the Langmuir and R-P model. The studies of equilibrium in a bi-component system by means of extended Langmuir (EL), extended Langmuir-Freundlich (ELF), and Jain-Snoeyink (JS) models were analysed. The estimation of parameters of sorption isotherms in a bi-component system Cu(II)-CV has shown that the best of fit calculated values of experimental data for both sorbates have been the EL model and the JS model, but only in the case of a CV dye. The sorption kinetic of Cu(II) and CV onto FA-H₂O₂ was discussed by means of the PFO, PSO, and intra-particle diffusion models.

PL

W pracy przedstawiono prostą modyfikację popiołu lotnego węglowego (FA) za pomocą 30% roztworu H2O2 oraz wykorzystanie go jako nowego skutecznego sorbentu do usuwania barwnika organicznego fioletu krystalicznego (CV) w obecności jonów Cu(II) w układzie jedno- i dwuskładnikowym Cu(II)-CV. Badania FT-IR, TG, SEM-EDS i XRD potwierdziły, że mechanizm sorpcji Cu(II) i CV na FA- H₂O₂ obejmuje proces wymiany jonowej i adsorpcji powierzchniowej. Porównując wartości zredukowanego testu chi-kwadrat (χ²/DoF) i współczynnika determinacji R² uzyskane dla rozpatrywanych izoterm CV, stopień dopasowania odpowiednich modeli odpowiada następującej kolejności: Jovanović > Langmuir > Elovich > Freundlich > Redlich-Peterson (RP) > Tóth > Halsey > BET. Sorpcja jonów Cu(II) w układzie jednosładnikowym za pomocą FA-H₂O₂ została dobrze opisana za pomocą modelu Langmuira i R-P. Przeanalizowano badania równowagi w układzie dwuskładnikowym wykorzystując rozszerzony model Langmuira (EL), rozszerzony Langmuira-Freundlicha (ELF) i Jain-Snoeyinka (JS). Estymacja parametrów izoterm sorpcji w układzie binarnym Cu(II)-CV wykazała, że najlepsze dopasowanie wartości obliczonych do danych doświadczalnych dla obu sorbatów posiada model EL oraz model JS, ale tylko w przypadku barwnika CV. Kinetykę sorpcji Cu(II) i CV na FA-H₂O₂ przeanalizowano za pomocą modeli PFO, PSO i dyfuzji wewnątrzziarnowej.

Słowa kluczowe

EN

heavy metal; immobilization; sorption; waste material; bi-component system; basic dye

PL

metal ciężki; unieruchomienie; sorpcja; odpady; system dwuskładnikowy; barwnik

• Wydawca: Institute of Environmental Engineering, Polish Academy of Sciences
• Czasopismo: Archives of Environmental Protection
• Rocznik: 2020
• Tom: Vol. 46, no. 1
• Strony: 62--75
• Opis fizyczny: Bibliogr. 36 poz., rys., tab., wykr.

Twórcy

autor

Sočo Eleonora

• Department of Inorganic and Analytical Chemistry, University of Technology, Rzeszów, Poland

autor

Pająk Dariusz

• Department of Inorganic and Analytical Chemistry, University of Technology, Rzeszów, Poland

autor

Kalembkiewicz Jan

• Department of Inorganic and Analytical Chemistry, University of Technology, Rzeszów, Poland

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).