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Study on fluoride fixation effect of Bayan Obo rare earth iron ore and three sodium agents under microwave irradiation

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
To investigate the fluorine fixation of Bayan Obo rare-earth iron ores in beneficiation and metallurgy processes, the effect of three sodium agents, namely, sodium hydroxide, sodium carbonate, and sodium bicarbonate, on fluorine fixation under the action of microwaves was investigated using Xray diffraction, chemical detection, and orthogonal experiments. The effects of different types of sodium, roasting temperatures, sodium ratios, and roasting times on the fluorine fixation rate were evaluated. Results show that compared with conventional roasting, the fluorine fixation efficiency of Bayan Obo rare-earth iron ore under the action of microwave is superior after the formulation of the sodium agent, which is crucial for the study. Among the three sodium agents, the fluorine fixation effect of NaHCO3 can be used as the preferred sodium agent. Orthogonal experiments showed that the factors influencing the magnitude of the fluorine fixation rate are the roasting temperature, sodium agent ratio, and roasting constant temperature time in the order of priority. The optimal conditions for the fluorine fixation process are the microwave roasting temperature of 973.15 K, sodium bicarbonate ratio of 40%, and roasting time of 60 min. The highest fluorine fixation rate of 86.72% can be obtained. The findings of this study can provide a reference for the development of green and economic recovery processes for Bayan Obo rare-earth iron ores.
Rocznik
Strony
63--76
Opis fizyczny
Bibliogr. 22 poz., rys.
Twórcy
autor
  • Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology,Baotou 014010,China
  • JINGNENG Holding Group, Datong 037300, China
autor
  • Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology,Baotou 014010,China
autor
  • Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology,Baotou 014010,China
autor
  • Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology,Baotou 014010,China
autor
  • Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology,Baotou 014010,China
autor
  • Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology,Baotou 014010,China
Bibliografia
  • CHEN, Q., YU, Y., 1992. Some Characteristics of Niobium Mineral Resources of Low and Medium Grade Oxide Ores in the Main and Eastern Mining Areas at the Bayan Obo Mine. Rare Metals, 02, 147-152.
  • FENG, Z., HUANG, X., WANG, M., ZHANG, G., 2017. Advances and trends in green chemistry of extraction and separation processes of typical rare earth resources. Rare Metals, 41(05), 604-612.
  • HAO, Z., WANG, X., LI, Z., XIAO, G., ZHANG, T., 2002. The Bayan Obo carbonatite REE-Nb-Fe deposit - a rare ex ample of Middle Proterozoic broken volcanic agency diagenetic mineralization. Journal of Geology, 04, 525-540.
  • HOU, X., YANG, Z.F., WANG, Z., 2020. The occurrence characteristics and recovery potential of middle-heavy rare earth elements in the Bayan Obo deposit, Northern China. Ore Geology Reviews, 126.
  • HUANG, J., 2000. An Application of Microwave Pre-oxidation in Improving Gold Recovery of a Refractory Gold Ore. Rare Metals, 03, 161-171.
  • KANG, D., LI, J., LI, W., ZHANG, W., XU, X., ZHANG, CH., 2017. Experiment on iron extraction and fluoride reduction in Bayan Obo magnetic separation iron ore concentrate. Metal Mining, 09, 78-81.
  • KE, CH., SUN, S., ZHAO, Y., LI, Y., XU, Z., HAO, M., LI, R., ZHANG, L., 2021. Ore-controlling tectonic features and deep-search directions of the Bayan Obo ultra-large rare earth-niobium-iron deposit in Inner Mongolia. Geological Bulletin, 40(01), 95-109.
  • LIU, T., ZHANG, Z., YE, L., SHEN, N., YANG, Z., LI, W., FENG, J, 2012. Geogeochemical characteristics and genesis of the Bayan Obo "dolomite". Journal of Geology, 86(05), 723-734.
  • LI, M., GENG, Y., ZHANG, D., GAO, K., LI, J., QIAO, X., 2016. Na2CO3-NaOH roasting of high-grade mixed rare earth concentrates. Chinese Journal of Rare Earths, 34(01), 55-61.
  • LI, J., LI, C.Y., LI, W.W., WANG, S.B., HAN J.X., WANG J., 2014. Experimental study on acid leaching of low-grade rare earth concentrates by microwave heating. Rare Metals, 38(05), 839-845.
  • LIN, J., 2021. Spectroscopy and Spectral Analysis, 41(04), 1281-1287
  • OMRAN, M., FABRITIUS, T., ELMAAHDY, A.M., ABDEL-KHALEK, N.A., EL-AREF, M., EL-HAMID, ELMANAWI A., 2014. Effect of microwave pre-treatment on the magnetic properties of iron ore and its implications on magnetic separation. Sep. Purif. Technol. 136, 223–232.
  • OPARE, E.O., STRUHS, E., MIRKOUEI, A., 2021. A comparative state-of-technology review and future directions for rare earth element separation. Renewable and Sustainable Energy Reviews ,143.
  • REN, Y.S., 2019. Study on the mineralization mechanism of REE-U elements in northern China . University of Science and Technology of China.
  • TIAN, P., YANG, X. Y., YUAN, W. M., 2020. Formation and preservation of the Bayan Obo Fe-REE-Nb deposit, Inner Mongolia: Insights from evidences of petrogenesis, geochemistry and apatite fission track dating. Solid Earth Sciences, 6, 228-245.
  • WENG, S.-U., 2016 Transform Infrared Spectrum Analysis. Chemical Industry Press, China.
  • WANG, Y., ZHANG, J., SONG, X., ZHANG, F., LUO, G., WANG, J., 2014. Study on the escape of gaseous fluoride during the roasting of fluorine-containing iron ore concentrate. Rare Earths, 35(01), 11-15.
  • XU, L., 2005. Characterization and geotectonic evolution of the Garidonian-Halcynian-Indusian magmatism in the Bayan Obo-Mandurah area of Inner Mongolia. China University of Geosciences (Beijing).
  • XIAO, W.H., ZHI, Q.L., LIANG, S.W., ZONG, Y.F., 2015.Technology development for rare earth cleaner hydrometallurgy in China. Rare Metals, 34(04), 215-222.
  • XUE, M., ZHANG, X.Y., YANG, M., XIE, J.Y., LV, R.-Q., CHAI, Y.-M., DONG, B., 2021. High-pressure microwaveassisted synthesis of WS x/Ni_9S_8/NF hetero-catalyst for efficient oxygen evolution reaction. Rare Metals, 40(05), 1048-1055.
  • ZHANG, M.I., 2014. Thermodynamics and kinetics of fluoride generation during iron ore concentrate roasting. Inner Mongolia University of Science and Technology.
  • ZHENG Q., 2017. Study on integrated recovery of iron, rare earth, fluorine and phosphorus from weakly magnetic tailings of Bayan Obo, Northeastern University.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-defdb8eb-7332-4a81-adc0-e1b66c64930c
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