PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Speciation of Mercury Contaminant in Public Gold Mine Tailing and its Stabilization Using Sulfur and Sulfide

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The mercury-containing tailing waste from public gold mines in Indonesia is generally deposited on soil without treatment. This research aimed at determining the amount and composition of mercury species in the tailing, and testing the effect of sulfur and sulfide on mercury stabilization. Samples were collected from a tailing pile at different depths in a public gold mine in Kulon Progo, Indonesia. The samples were characterized according to the mercury concentrations and Toxicity Characteristic Leaching Procedure (TCLP) test. Mercury speciation was carried out using nitrogen gas flow into tailing samples, which were placed in three test tubes. The released mercuric species was entrapped in KCl and KmnO4 solutions. The mercury stabilization was carried out using sulfur and sodium sulfide. TCLP test was performed to the stabilization products. The mercury concentrations were measured using a mercury analyzer. The results showed that the mercury in the tailings were dominated by elemental Hgo, the concentrations of which in the tailing piles of 30, 60, and 90 cm depths were 74.7%, 71.6%, and 76.5% respectively. Those of ionic Hg2+ form were 25.3%, 28.4%, and 23.5%, respectively. Additions of sulfur powder and sodium sulfide solution produced stable black-colored mercury sulfide. When compared to sulfide, sulfur was more recommended for stabilizing mercury in the tailing waste.
Słowa kluczowe
Rocznik
Strony
29--34
Opis fizyczny
Bibliogr. 20 poz., rys., tab.
Twórcy
  • Department of Environmental Engineering, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Jl. A.R. Hakim, Surabaya 60111, Indonesia
  • Department of Environmental Engineering, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Jl. A.R. Hakim, Surabaya 60111, Indonesia
  • Department of Environmental Engineering, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Jl. A.R. Hakim, Surabaya 60111, Indonesia
Bibliografia
  • 1. Biester H., Müller G., and Schöler H. 2002. Binding and mobility of mercury in soils contaminated by emissions from chlor-alkali plants. Journal of Science of the Total Environment 2002, 284(1–3): 191–203.
  • 2. Blanchard A.A. 1936. Synthetic inorganic chemistry. 151–152, New York.
  • 3. Chang C.Y., Hsu C.P., Jann J.S., Chen Y.W., Shih Y.C., Mao C.F., Lin W.Y., Lin KL, Wu Y.M. 1993. Stabilization of mercury containing sludge by a combined process of two-stage pretreatment and solidification. Journal of Hazardous Materials, 35(1): 73–88.
  • 4. Hamilton WP, Bowers A.R. 1997. Determination of acute Hg emissions from solidified/stabilized cement waste forms. Journal of Waste Management, 1: 25–32.
  • 5. Herman D.Z. 2006. Evaluation on tailing containing arsenic (As), mercury (Hg), lead (Pb), and cadmium (Cd) from residual ore. Jurnal Geologi Indonesia, 1: 31–36. (in Indonesian)
  • 6. Ilyas T.Y., Rahayu W., and Arifin D.S. 2008. Study on strength behavior of peat soil in Kalimantan after stabilization with Portland cement. Jurnal Teknologi 1: 1–8. (In Indonesian)
  • 7. Lee S.J., Seo Y.C., Jurng J., Hong J.H., Park J.W., Hyun J.E., and Lee T.G., 2004. Mercury emissions from selected stationary combustion sources in Korea. Journal of Science of Total Environment. 325: 155–161.
  • 8. Kalimantoro T.T., Trihadiningrum Y. 2016. Stabilization/Solidification of tailing from public gold mining in Kulon Progo using Portland cement and trass soil. Jurnal Teknik ITS, 5 (2): 2337–3539. (In Indonesian).
  • 9. López F.A., Alguacil F.J., Roman C.P., Tayibi H., and López-Delgado A. 2008. Disposal of Elemental Mercury Via Sulphur Reaction by Milling. First International Conference on Hazardous Waste Management, 1–3 October,Chaina, Greece
  • 10. López F.A., López-Delgado A., Padilla I., Tayibi H., Alguacil F.J., 2010. Formation of Metacinnabar by Milling of Liquid Mercury and Elemental Sulphur for Long Term Mercury Storage. Journal of Science of the Total Environment 2010, 408(20): 4341–4345
  • 11. McWhinney H.G.. Cocke D.L., Balke K., Ortego J.D. 1990. An Investigation of Mercury Solidification and Stabilization in Portland Cement Using X-Ray Photoelectron Spectroscopy and Energy Dispersive Spectroscopy. Cement and Concrete Research, 20 (1): 79–91.
  • 12. Pamayo A.I. and Trihadiningrum, Y. 2015. Stabilization/solidification of tailing pile from public gold mining in Kulon Progo using Portland cement. Jurnal Teknik ITS, 5 (2): 242–247.
  • 13. Piao H. and Bishop P.L. 2001. Sulfide-induced mercury stabilization. In: Proceedings, American Chemical Society, 221st Annual Meeting & Exhibition, San Diego, California.
  • 14. Piao H. and Bishop P.L. 2006. Stabilization of mercury containing wastes using sulfide. Journal of Environmental Pollution, 139(3): 498–506.
  • 15. Rachman R.M., Kharismawati E., and Trihadiningrum Y. 2017. Stabilization/solidification of mercury contaminated soil of traditional gold mining in Kulon Progo Yogyakarta, Indonesia using a mixture of Portland cement and tras soil. ARPN Journal of Engineering and Applied Sciences, 22 (12): 6380–6387
  • 16. Rachman, R.M., Bahri, A.S., Trihadiningrum, Y. 2018. Stabilization/solidification of tailing on traditional gold mining in Kulun Progo using fly ash. Journal of Ecological Engineering 19 (3), 178–184
  • 17. Richard J.H. 2016. Mercury contaminated groundwater: Speciation Analysis, Modeling, and Remediation. TU Braunschweig. Institut für Geoökologie, Umweltgeochemie, Germany.
  • 18. Robles I., Lakatos J., Scharek P., Planck Z., Hernández G., Solís S., Bustos E. 2014. Characterization and Remediation of Soils and Sediments Polluted with Mercury: Occurrence, Transformations, Environmental Considerations and San Joaquin’s Sierra Gorda Case. Environmental Risk Assessment of Soil Contamination, Chapter 29: 827–850.
  • 19. USEPA, 1992. EPA Test Method 1311 – TCLP, Toxicity Characteristic Leaching Procedure.
  • 20. Zhang H., Chen J., Liang P., Wang L., 2012. Mercury Oxidation and Adsorption Characteristics of Potassium Permanganate Modified Lignite Semi-Coke. Journal of Environmental Science, 24 (12): 2083–2090.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-dee363b8-9442-4713-9054-58023ae22c62
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.