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Tytuł artykułu

Thermal and mechanical properties of PLA/ENR thermoplastic vulcanizates compatibilized with tetrafunctional double-decker silsesquioxanes

Autorzy
Paszkiewicz Sandra , Kramek Grzegorz , Walkowiak Konrad , Irska Izabela , Piesowicz Elżbieta , Rzonsowska Monika , Dudziec Beata , Barczewski Mateusz
Treść / Zawartość
Pełne teksty:
Polimery_2023_11_593_606.pdf
Identyfikatory
DOI
10.14314/polimery.2023.11.3
Warianty tytułu
PL
Właściwości termiczne i mechaniczne termoplastycznych wulkanizatów PLA/ENR kompatybilizowanych czterofunkcyjnym silseskwiokanem typu double-decker
Języki publikacji
EN
Abstrakty
EN
The influence of the addition of tetrafunctional double-decker silsesquioxanes (DDSQ-ether- -4OH) on the compatibility, thermal and mechanical properties of polylactide and epoxidized natural rubber (PLA/ENR) vulcanizates was investigated. The apparent cross-linking density and thermal stability of PLA/ENR vulcanizates were also determined. The FTIR analysis confirmed the compatibilizing effect of DDSQ-ether-4OH and the formation of the PLA-g-ENR copolymer. A strong effect of ENR content and DDSQ-ether-4OH addition on the thermal and mechanical properties of the obtained vulcanizates was demonstrated.
PL
Zbadano wpływ dodatku czterofunkcyjnego silseskwioksanu typu double-decker (DDSQ-eter-4OH) na kompatybilność oraz właściwości termiczne i mechaniczne wulkanizatów polilaktydu i epoksydowanego kauczuku naturalnego (PLA/ENR). Oznaczono również pozorną gęstość usieciowania i stabilność termiczną wulkanizatów PLA/ENR. Metodą FTIR potwierdzono kompatybilizujące działanie DDSQ-eter-4OH i utworzenie kopolimeru PLA-g-ENR. Wykazano silny wpływ zawartości ENR i dodatku DDSQ-eter-4OH na właściwości termiczne i mechaniczne otrzymanych wulkanizatów.
Słowa kluczowe
EN
PL
Wydawca
Sieć Badawcza Łukasiewicz – Instytut Chemii Przemysłowej
Czasopismo
Polimery
Rocznik
2023
Tom
Vol. 68, nr 11-12
Strony
593--606
Opis fizyczny
Bibliogr. 67 poz., rys., tab., wykr.
Twórcy
autor
Paszkiewicz Sandra
spaszkiewicz@zut.edu.pl
  • West Pomeranian University of Technology, Faculty of Mechanical Engineering and Mechatronics, Department of Materials Technologies, Piastow Av. 19, 70-310 Szczecin, Poland
autor
Kramek Grzegorz
  • West Pomeranian University of Technology, Faculty of Mechanical Engineering and Mechatronics, Department of Materials Technologies, Piastow Av. 19, 70-310 Szczecin, Poland
autor
Walkowiak Konrad
  • West Pomeranian University of Technology, Faculty of Mechanical Engineering and Mechatronics, Department of Materials Technologies, Piastow Av. 19, 70-310 Szczecin, Poland
autor
Irska Izabela
  • West Pomeranian University of Technology, Faculty of Mechanical Engineering and Mechatronics, Department of Materials Technologies, Piastow Av. 19, 70-310 Szczecin, Poland
autor
Piesowicz Elżbieta
  • West Pomeranian University of Technology, Faculty of Mechanical Engineering and Mechatronics, Department of Materials Technologies, Piastow Av. 19, 70-310 Szczecin, Poland
autor
Rzonsowska Monika
  • Adam Mickiewicz University in Poznan, Faculty of Chemistry and Centre for Advanced Technologies, Uniwersytetu Poznanskiego 8–10, 61-614 Poznan, Poland
autor
Dudziec Beata
  • Adam Mickiewicz University in Poznan, Faculty of Chemistry and Centre for Advanced Technologies, Uniwersytetu Poznanskiego 8–10, 61-614 Poznan, Poland
autor
Barczewski Mateusz
  • Poznan University of Technology, Faculty of Mechanical Engineering and Management, Institute of Materials Technology, Polymer Processing Division, Piotrowo 3, 61-138 Poznan, Poland
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-dec3b32f-4578-46df-91d6-77da98ee1f45
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