Study of Ammonium Perchlorate-based Molecular Perovskite (H2DABCO)[NH4(ClO4)3]/Graphene Energetic Composite with Insensitive Performance

• Autorzy: Liu Yang , Hu Li-shuang , Gong Shida , Guang Chunyu , Li Lianqiang , Hu Shuangqi , Deng Peng

Identyfikatory

DOI

10.22211/cejem/127934

• Języki publikacji: EN

Abstrakty

EN

In order to improve the safety properties of molecular perovskite energetic materials, ammonium perchlorate-based molecular perovskite ((H2DABCO)[NH4(ClO4)3], DAP)/graphene composite was prepared and characterized. Molecular perovskite DAP was prepared via a molecular assembly strategy by the facile one-pot reaction of triethylenediamine (TEDA, DABCO), perchloric acid, and ammonium perchlorate, and the DAP/graphene composite was fabricated by mechanical mixing with 10 wt.% graphene. The results demonstrated that impact sensitivity (>120 cm), friction sensitivity (25%) and electrostatic spark sensitivity (7.04 J) of the DAP/graphene composite was less sensitive than raw DAP (impact, friction and electrostatic spark sensitivity: 112.3 cm, 45%, and 5.39 J, respectively), due to the composite desensitization mechanism of graphene. This work may offer new ideas for the design and fabrication of insensitive molecular perovskite-based energetic composites.

Słowa kluczowe

EN

ammonium perchlorate; molecular perovskite; graphene; energetic composites; composite desensitization

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2020
• Tom: Vol. 17, no. 3
• Strony: 451--469
• Opis fizyczny: Bibliogr. 26 poz., rys., tab.

Twórcy

autor

Liu Yang

• School of Environment and Safety Engineering, North University of China, China

autor

Hu Li-shuang

• School of Environment and Safety Engineering, North University of China, China

autor

Gong Shida

• School of Environment and Safety Engineering, North University of China, China

autor

Guang Chunyu

• School of Environment and Safety Engineering, North University of China, China

autor

Li Lianqiang

• Institute of Occupational Health of Ordnance Industry, China

autor

Hu Shuangqi

• School of Environment and Safety Engineering, North University of China, China

autor

Deng Peng

• School of Environment and Safety Engineering, North University of China, China

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).