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Influence of styrene-butadiene rubber latex on the early hydration of cement
Języki publikacji
Abstrakty
W pracy badano wpływ dodatku kopolimeru styrenowo-butadienowego (SBR) na wczesną hydratację cementu. Badania wykazały, że kopolimer SBR opóźnia wiązanie cementu i efekt ten wzrasta ze wzrostem dodatku. Kopolimer SBR zwiększa więc okres indukcji, opóźnia okres wzrastającej szybkości reakcji, a także zwiększa hydratację w okresach zmniejszania szybkości reakcji i małej szybkości reakcji. Ciepło hydratacji i jej stopień w przypadku cementu z dodatkiem SBR jest większy niż wzorca, po 48 godzinach. SBR przyspiesza powstawanie i zwiększa trwałość ettringitu. SBR utrudnia i opóźnia powstawanie CH.
Early hydration of cement in the presence of styrene-butadiene rubber (SBR) latex was investigated in this paper. The initial/final setting time, hydration heat, hydration degree, hydrates of calcium aluminate and hydrates of calcium silicate were analyzed. The results show that SBR latex retards the initial/final setting of cement. The more SBR latex is added, the stronger the retarding effect. SBR latex prolongs the induction period of cement hydration, postpones the accelerating period but promotes the decelerating and stable periods. The hydration heat and hydration degree of cement with SBR latex is higher than the control one after 48 hours. SBR latex promotes the formation and enhances the stability of ettringite. SBR latex also inhibits and retards the formation of CH.
Wydawca
Czasopismo
Rocznik
Tom
Strony
36--45
Opis fizyczny
Bibliogr. 21 poz., il., tab.
Twórcy
autor
- Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education; School of Materials Science and Engineering, Tongji University, Shanghai, China
autor
- Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education; School of Materials Science and Engineering, Tongji University, Shanghai, China
Bibliografia
- 1 . Z. J. Xia, L. F. Luo, The impact of curing conditions on the mechanical properties of modified mortars and cement. Journal of South China University of Technology (Natural Science Edition) 29, 83-86 (2001).
- 2. S. Y. Zhong, Z. Y. Chen, Properties of latex blends and its modified cement mortars. Cem. Concr. Res., 32,1515-1524 (2002).
- 3. S. Y. Zhong, M. L. Shi, Z. Y. Chen, The AC response of polymer-coated mortar specimens. Cem. Concr. Res., 32, 983-987 (2002).
- 4. J. Mirza, M. S. Mirza, R. Lapointe, Laboratory and field performance of polymer-modified cement-based repair mortars in cold climates, Constr. Build. Mat., 16, 365-374 (2002).
- 5. R. Wang, P. M. Wang, Function of styrene-acrylic ester copolymer latex in cement mortar, Mat. Struc., 43, 443-451 (2010).
- 6. R. Wang, P. M. Wang, Transverse deformation and ratio of compressive strength to flexural strength of SAE latex-modified mortar and their relationship, J. of Build. Mat., 11, 464-468 (2008).
- 7. S. Y. Zhong, J. M. Li, J. G. Wu, Early water loss in polymer modified mortar with polypropylene fiber added, J. Build. Mat., 14, 581-585 (2011).
- 8. D. H. He, P. M. Wang, P. Liu, Interface bond mechanism of EVA-modified mortar and porcelain tile, J. Mat. Civil Eng., 25, 726-730 (2013).
- 9. H. M. Zhu, P. M. Wang, G. F. Zhang, Effects of redispersible EVA and E/VL/VC powders on properties of decorative mortar, In Proceedings of the 14th International Congress on Polymers in concrete, pp. 241-248, Ru Wang, Zhenghong Yang, Shanghai, China 2013.
- 10. R. Wang, L. J. Yao, P. M. Wang, Mechanism analysis and effect of styrene-acrylate copolymer powder on cement hydrates, Constr. Build. Mat,. 27, 538-544 (2013).
- 11. B. Singh, R. Sarita, Effect of polyvinyl alcohol on the hydration of cement with rice husk ash, Cem. Concr. Res., 31, 239-243 (2001).
- 12. A. Peschard, A. Govin, P. Grosseau, Effect of polysaccharides on the hydration of cement paste at early ages, Cem. Concr. Res., 34, 2153–2158 (2004).
- 13. D. A. Silva, H. R. Roman, P. J. P. Gleize, Evidences of chemical interaction between EVA and hydrating Portland cement, Cem. Concr. Res., 32, 1383-1390 (2002).
- 14. M. Betioli, P. Gleize, D. Silva, Effect of HMEC on the consolidation of cement pastes: Isothermal calorimetry versus oscillatory rheometry, Cem. Concr. Res., 39, 440–445 (2009).
- 15. G. F. Zhang, P. M. Wang, Effects of vinyl redispersible polymer on cement hydration products, J. Build. Mat., 13, 143-149 (2010).
- 16. R. Wang, X. G. Li, P. M. Wang, Influence of polymer on cement hydration in SBR-modified cement paste, Cem. Concr. Res., 36, 1744-1751 (2006).
- 17. F. Xu, M. K. Zhou, B. X. Li et al., Influences of polypropylene fiber and SBR polymer latex on abrasion resistance of cement mortar, Journal of Wuhan University of Technology-Mater. Sci. Ed., 25, 4, 624-627 (2010).
- 18. Z. X. Yang, X. M. Shi, C. Andrew et al., Effect of styrene-butadiene rubber latex on the chloride permeability and microstructure of Portland cement mortar, Constr. Build. Mat., 23, 6, 2283-2290 (2009).
- 19. X. X. Shi, R. Wang, P. M. Wang, Dispersion and absorption of SBR latex in the system of mono-dispersed cement particles in water, In Proceedings of the 14th International Congress on Polymers in concrete, pp. 347-353, Ru Wang, Zhenghong Yang, Shanghai, China 2013.
- 20. P. M. Wang, S. X. Feng, X. P. Liu, Research approaches of cement hydration degree and their development, J. Build. Mat., 8, 646-651 (2005).
- 21. N. R. Yang, W. H. Yue, Handbook of a Collection of Illustrative Plates of Inorganic Nonmetal Materials, Wuhan University of Technology Publishing Company, China 2000.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-de8defdf-2500-4a91-a30f-11fcfe4044fd