Application of Bimetallic Nanoparticles as Eco-Friendly Metal Corrosion Inhibitors in a Thiol Medium Through the Example of Cysteine

• Autorzy: Daumova Gulzhan , Van Yelena , Masyutin Yakov , Gradov Anton , Ivashchenko Yelena

Identyfikatory

DOI

10.12911/22998993/187958

• Języki publikacji: EN

Abstrakty

EN

This article raises the relevancy problems of bimetallic nanostructures using to inhibit corrosion processes specific to various sulfur-containing media, including the extraction and transportation of natural hydrocarbons, in oil and gas condensate equipment. The environmental aspect of the research is the possibility of using bimetallic nanostructures modified with cysteine as environmentally friendly agents that protect steel from corrosion, especially in a thiol medium. There are presented experimental data on the synthesis and study of bimetallic nanostructures based on copper and silver in a thiol medium based on cysteine aminoacid. The research field is conditioned by these days’ tendency that advanced developments in many branches of science are directly associated to the application of nanomaterials. The high action efficiency of these materials is achieved due to their highly dispersed state, distinguishing them favorably from conventional macroobjects. The synthesis of Cu/Ag nanostructures was carried out due to the unique properties of bimetals, such as increased activity of atoms in the surface layer, display of quantum effects, etc., that are more pronounced than those in monometallic nanostructures. The main article concept lies within simulation the process of sulfides and other sulfur compounds formation with bimetallic nanoparticles to protect oil and gas equipment from sulfur-containing corrosive agents in aqueous medium. The goal is to synthesize the copper-silver bimetallic microparticles stabilized with apple pectin and verification of the possibility of forming a metal-sulfur bond at the nanoscale level with cysteine aminoacid as a suitable and convenient compound. The objectives include directly the method of synthesis of the bimetallic microstructure Cu-Ag, stabilized with a solution of apple pectin; absorption spectrophotometry of the studied disperse system of bimetallic Cu-Ag microparticles in the visible region; scanning electron microscopy (SEM) of the bimetallic CuAg microparticles obtained; study of chemisorption of L-cysteine hydrochloride on the dispersed phase surface of bimetallic Cu-Ag microparticles; Raman-scattering spectroscopy of the sample obtained after chemisorption.

Słowa kluczowe

EN

bimetallic microstructures Cu-Ag; eco-friendly agent; thiols; cysteine; corrosion

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2024
• Tom: Vol. 25, nr 7
• Strony: 105--114
• Opis fizyczny: Bibliogr. 13 poz., rys., tab.

Twórcy

autor

Daumova Gulzhan

• D. Serikbayev East Kazakhstan Technical University, 19, Serikbayev str., 070000, Ust-Kamenogorsk, Kazakhstan

• https://orcid.org/0000-0001-6312-5343

autor

Van Yelena

• Immanuel Kant Baltic Federal University, 14 A. Nevskogo ul., 236016 Kaliningrad, Russia

autor

Masyutin Yakov

• Immanuel Kant Baltic Federal University, 14 A. Nevskogo ul., 236016 Kaliningrad, Russia

• https://orcid.org/0000-0003-4347-3425

autor

Gradov Anton

• Immanuel Kant Baltic Federal University, 14 A. Nevskogo ul., 236016 Kaliningrad, Russia

autor

Ivashchenko Yelena

• D. Serikbayev East Kazakhstan Technical University, 19, Serikbayev str., 070000, Ust-Kamenogorsk, Kazakhstan

• https://orcid.org/0000-0002-9233-6593

Bibliografia

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