Improved Synthesis of Glycidyl Nitrate in the Presence of 5-Aminotetrazolium Nitrate: a New Method Optimised Using the Taguchi Method

• Autorzy: Bayat Y. , Mohammadi M. M.

Identyfikatory

DOI

10.22211/cejem/65024

• Języki publikacji: EN

Abstrakty

EN

This paper describes a method for increasing the yield of glycidyl nitrate from chloro-epoxypropane and dilute nitric acid, in the presence of 5-aminotetrazolium nitrate. The presence of 5-aminotetrazolium nitrate as catalyst and co-nitrating agent, enabled glycidyl nitrate to be produced smoothly and in excellent yield under mild condition. The optimal reaction conditions were obtained by the Taguchi method, increasing the yield from 66 to 81%. The product was characterized by FTIR and 1H NMR spectroscopy.

Słowa kluczowe

EN

glycidyl nitrate; 5-aminotetrazolium nitrate; chloro-epoxy-propane; Taguchi method

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2016
• Tom: Vol. 13, no. 3
• Strony: 579--591
• Opis fizyczny: Bibliogr. 25 poz., rys., tab.

Twórcy

autor

Bayat Y.

• Department of Chemistry and Chemical Engineering, Malek-Ashtar University of Technology, P.O. Box 16765-3454, Tehran, Iran

autor

Mohammadi M. M.

• Department of Chemistry and Chemical Engineering, Malek-Ashtar University of Technology, P.O. Box 16765-3454, Tehran, Iran

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