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Formation of Al-alloyed Layer on Magnesium with Use of Casting Techniques

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Al-enriched layer was formed on a magnesium substrate with use of casting. The magnesium melt was cast into a steel mould with an aluminium insert placed inside. Different conditions of the casting process were applied. The reaction between the molten magnesium and the aluminium piece during casting led to the formation of an Al-enriched surface layer on the magnesium substrate. The thickness of the layer was dependent on the casting conditions. In all fabricated layers the following phases were detected: a solid solution of Mg in Al, Al3Mg2, Mg17Al120 and a solid solution of Mg in Al. When the temperature of the melt and the mould was lower (variant 1 – 670oC and 310oC; variant 2 – 680oC and 310oC, respectively) the unreacted thin layer of aluminium was observed in the outer zone. Applying higher temperatures of the melt (685oC) and the mould (325oC) resulted in deep penetration of aluminium into the magnesium substrate. Areas enriched in aluminium were locally observed. The Al-enriched layers composed mainly of Mg-Al intermetallic phases have hardness from 187-256 HV0.1.
Rocznik
Strony
112--116
Opis fizyczny
Bibliogr. 22 poz., il., tab.
Twórcy
autor
  • Faculty of Mechatronics and Machine Engineering, Kielce University of Technology, Al. Tysiąclecia Państwa Polskiego 7, 25-314 Kielce, Poland
autor
  • Faculty of Mechatronics and Machine Engineering, Kielce University of Technology, Al. Tysiąclecia Państwa Polskiego 7, 25-314 Kielce, Poland
autor
  • Faculty of Mechatronics and Machine Engineering, Kielce University of Technology, Al. Tysiąclecia Państwa Polskiego 7, 25-314 Kielce, Poland
Bibliografia
  • [1] Gray, J.E. & Luan, B. (2002). Protective coatings on magnesium and its alloys – a critical review, J. Alloys Compd 336, 88-113.
  • [2] Stankiewicz, A., Laszczyńska, A. Winiarski, J. & Szczygieł, B. (2010). Selected methods for preparing the coating on magnesium and its alloys., Ochrona przed korozją, 53, nr 4-5, 286-292. (in Polish).
  • [3] Singh, A. & Harimkar, S.P.(2012). Laser surface engineering of magnesium alloys: a review. JOM, 64(6), 716-733. DOI: 10.1007/s11837-012-0340-2.
  • [4] Ignat, S., Sallamand, P., Grevey, D. & Lambertin, M. (2004). Magnesium alloys laser (Nd:YAG) cladding and alloying with side injection of aluminium powder. Appl. Surf. Sci., 225, 124-134. DOI: 10.1016/j.apsusc.2003.09.043.
  • [5] Dziadoń, A. & Mola, R. (2011). Microstructure analysis of magnesium surface layer enriched in aluminium by means of laser alloying procedure. Rudy i Metale Nieżelazne R56 5, 272-278.
  • [6] Zhong, C., He, M., Liu, L., Wu, Y., Chen, Y., Deng, Y., Shen, B. & Hu, W. (2010). Lower temperature fabrication of continuous intermetallic coatings on AZ91D magnesium alloy in molten salts. J. Alloys Compd. 504, 377-381. DOI: 10.1016/j.jallcom.2010.05.120.
  • [7] He, M., Liu, L., Wu, Y., Tang, Z. & Hu, W. (2009). Improvement of the properties of AZ91D magnesium alloy by treatment with molten AlCl3-NaCl salt to form an Mg-Al inrermetallic surface layer. J.Coat. Technol. Res 6(3), 407-411. DOI: 10.1007/s11998-008-9132-6.
  • [8] Shigematsu, M., Nakamura, M., Saitou, K. & Shimojima, K. (2000). Surface treatment of AZ91D magnesium alloy by aluminum diffusion coating. J. Mater. Sci. Lett. 19, 473-475.
  • [9] Ma, Y., Xu, K., Wen, W., He, X. & Liu, P. (2005). The effect of solid diffusion surface alloying on properties of ZM5 magnesium alloy. Surf. Coat. Technol. 190, 165-170. DOI: 10.1016/j.surfcoat.2004.08.214.
  • [10] Zhu, L. & Song, G. (2006). Improved corrosion resistance of AZ91D magnesium alloy by an aluminum-alloyed coating. Surf. Coat. Technol. 200, 2834-2840. DOI: 10.1016/j.surfcoat.2004.11.042.
  • [11] Liu, F., Li, X., Liang, W., Zhao, X. & Zhang, Y. (2009). Effect of temperature on microstructures and properties of aluminized coating on pure magnesium. J. Alloys Compd. 478, 579-585. DOI: 10.1016/j.jallcom.2008.11.093.
  • [12] Mola, R. (2013). Fabrication and microstructure of layers containing intermetallic phases on magnesium. Archives of Foundry Engineering 13(1), 99-102. DOI: 10.2478/afe-2013-0019.
  • [13] Mola, R. (2013). Fabrication and microstructural characterization of Al/Zn-enriched layers on pure magnesium. Mater. Charact. 78, 121-128. DOI: 10.1016/j.matchar.2013.02.004.
  • [14] Mola, R. & Jagielska-Wiaderek, K (2014). Formation of Al-enriched surface layers through reaction at the Mg-substrate/Al-powder interface. Surf. Interface Anal. DOI: 10.1002/sia.5579.
  • [15] Mola, R. (2014). The properties of Al/Zn-enriched surface layers on Mg, Archives of Foundry Engineering, Special Issue 1 4(3), 45-48.
  • [16] Huo, H., Li, Y. & Wang, F. (2007). Improvement on the corrosion resistance of AZ91D magnesium alloy by aluminum diffusion coating. J. Mater. Sci. Technol. 23(3), 379-382.
  • [17] Zhu, T. & Gao, W. (2009) Formation of intermetallic compound coating on magnesium AZ91 cast alloy, Mater. Sci. Eng., 4, 1-6. DOI: 10.10.88/1757-899X/4/1/012024.
  • [18] Spencer, K. & Zhang, M.X.(2009). Heat treatment of cold spray coatings to form protective intermetallic layers. Scr. Mater. 61, 44-47. DOI: 10.1016.j.scriptamat.2009.03.002
  • [19] Bu, H., Yandouzi, M., Lu, Ch. & Jodoin, B. (2011) Effect of heat treatment on the intermetallic layer of cold sprayed aluminum coatings on magnesium alloy. Surf. Coat. Technol., 205, 4665-4671. DOI: 10.1016/j.surfcoat.2011.04.018.
  • [20] Mola, R., Bucki, T. & Dziadoń, A. (2015) Surface alloying of magnesium by GTAW using AlMg4,5Mn wire, Rudy i Metale Nieżelazne, R60, 3, 110-114.
  • [21] Yang, H., Guo, X., Wu, G., Ding, W. & Birbilis, N. (2011). Electrodeposition of chemically and mechanically protective Al-coatings on AZ91D Mg alloy. Corros. Sci. 53, 381-387. DOI: 10.1016/j.corsci.2010.09.047.
  • [22] Crystallographic and Thermodynamic Data of Binary Alloys, Landolt-Börstein New Series, Group IV, Springer-Verlag Berlin 1998.
Uwagi
PL
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-ddaf0934-5a9e-42a3-a82d-9e60d81dd44d
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