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The Properties of Al/Zn-enriched Surface Layers on Mg

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Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The Al/Zn-enriched surface layers were fabricated on Mg substrate by heating the specimens in contact with an Al + 40 wt.% Zn powder mixture at 445oC for 60 min. The microstructure and corrosion and wear resistance of the layers were investigated and discussed. The experimental results show that the layers were composed of Mg17(Al,Zn)12 and Mg5Al2Zn2 intermetallic phases and a solid solution of Al and Zn in Mg. They were integrated with the substrate trough a zone of a solid solution of Al and Zn in Mg. The potentiodynamic polarization measurements indicated that the specimens with Al/Zn-enriched layer had better corrosion resistance than the bare Mg. The microhardness of the layers containing Mg-Al-Zn intermetallic phases was much higher than that of the Mg substrate. The sliding wear tests showed that the wear resistance of the specimens with a surface layer containing intermetallic phases was also superior to that of untreated Mg.
Rocznik
Strony
45--48
Opis fizyczny
Bibliogr. 22 poz., rys., tab., wykr.
Twórcy
autor
  • Faculty of Mechatronics and Machine Design, Kielce University of Technology, Al. 1000-lecia P.P. 7, 25-314 Kielce, Poland
Bibliografia
  • [1] Singh, A. & Harimkar, S.P. (2012). Laser surface engineering of magnesium alloys: a review. JOM. 64(6), 716-733. DOI: 10.1007/s11837-012-0340-2.
  • [2] Dziadoń, A. & Mola, R. (2011). Microstructure analysis of magnesium surface layer enriched in aluminium by means of laser alloying procedure. Rudy i Metale Nieżelazne. R56 5, 272-278.
  • [3] Dziadoń, A. & Mola, R. (2013). Microstructure characteristic of magnesium surface layer enriched in aluminium and silicon with the aid CO2 laser. Rudy i Metale Nieżelazne. R58 10, 551-556.
  • [4] Zhong, C., He, M., Liu, L., Wu, Y., Chen, Y., Deng, Y., Shen, B. & Hu, W. (2010). Lower temperature fabrication of continuous intermetallic coatings on AZ91D magnesium alloy in molten salts. J. Alloys Compd. 504, 377-381. DOI:10.1016/j.jallcom.2010.05.120.
  • [5] Zhong, C., He, M.F., Liu, L., Chen, Y.J., Shen, B., Wu, Y.T., Deng, Y.D. & Hu, W.B. (2010). Formation of aluminum alloyed coating on AZ91D magnesium alloy in molten salts at lower temperature. Surf. Coat. Technol. 205, 2412-2418. DOI:10.1016/j.surfcoat.2010.09.034.
  • [6] He, M., Liu, L., Wu, Y., Tang, Z. & Hu, W. (2009). Improvement of the properties of AZ91D magnesium alloy by treatment with molten AlCl3-NaCl salt to form an Mg-Al intermetallic surface layer. J.Coat. Technol. Res 6(3), 407-411. DOI: 10.1007/s11998-008-9132-6.
  • [7] Shigematsu, M., Nakamura, M., Saitou, K. & Shimojima, K. (2000). Surface treatment of AZ91D magnesium alloy by aluminum diffusion coating. J. Mater. Sci. Lett. 19, 473-475.
  • [8] Ma, Y., Xu, K., Wen, W., He, X. & Liu, P. (2005). The effect of solid diffusion surface alloying on properties of ZM5 magnesium alloy. Surf. Coat. Technol. 190, 165-170. DOI: 10.1016/j.surfcoat.2004.08.214.
  • [9] Zhu, L. & Song, G. (2006). Improved corrosion resistance of AZ91D magnesium alloy by an aluminum-alloyed coating. Surf. Coat. Technol. 200, 2834-2840. DOI:10.1016/j.surfcoat.2004.11.042.
  • [10] Liu, F., Li, X., Liang, W., Zhao, X. & Zhang, Y. (2009). Effect of temperature on microstructures and properties of aluminized coating on pure magnesium. J. Alloys Compd. 478, 579-585. DOI: 10.1016/j.jallcom.2008.11.093.
  • [11] Hirmke, J., Zhang, M.X. & StJohn, D.H.(2011). Surface alloying of AZ91E alloy by Al-Zn packed powder diffusion coating. Surf. Coat. Technol. 206, 425-433. DOI:10.1016/j.surfcoat.2011.07.050.
  • [12] Mola, R. (2013). Fabrication and microstructure of layers containing intermetallic phases on magnesium. Archives of Foundry Engineering. 13(1), 99-102. DOI: 10.2478/afe-2013-0019.
  • [13] Mola, R. (2013). Fabrication and microstructural characterization of Al/Zn-enriched layers on pure magnesium. Mater. Charact. 78, 121-128. DOI:10.1016/j.matchar.2013.02.004.
  • [14] Mola, R. & Jagielska-Wiaderek, K. (2014). Formation of Alenriched surface layers through reaction at the Mgsubstrate/Al-powder interface. Surf. Interface Anal.DOI: 10.1002/sia.5579.
  • [15] Lei, M.K., Li, P., Yang, H.G. & Zhu X.M. (2001). Wear and corrosion resistance of Al ion implanted AZ31 magnesium alloy, Surf. Coat. Technol., 201, 5182-5185. DOI:10.1016/j.surfcoat.2006.07.091.
  • [16] Wu, G., Xu, R., Feng, K., Wu, S., Wu, Z., Sun, G., Zheng, G., Li, G. & Chu P.K. (2012). Retardation of surface corrosion of biodegradable magnesium-based materials by aluminum ion implantation. Appl. Surf. Sci. 258, 7651-7657. DOI: 10.1016/iapsusc.2012.04.112.
  • [17] Huo, H. & Li, Y., Wang F. (2007). Improvement on the corrosion resistance of AZ91D magnesium alloy by aluminum diffusion coating. J. Mater. Sci. Technol. 23(3), 379-382.
  • [18] Zhu, T. & Gao, W. (2009) Formation of intermetallic compound coating on magnesium AZ91 cast alloy, Mater. Sci. Eng., 4, 1-6. DOI: 10.10.88/1757-899X/4/1/012024.
  • [19] Spencer, K. & Zhang, M.X.(2009). Heat treatment of cold spray coatings to form protective intermetallic layers. Scr. Mater. 61, 44-47. DOI: 10.1016.j.scriptamat.2009.03.002.
  • [20] Bu, H., Yandouz,i M., Lu, Ch. & Jodoin, B. (2011) Effect of heat treatment on the intermetallic layer of cold sprayed aluminum coatings on magnesium alloy. Surf. Coat. Technol., 205, 4665-4671. DOI: 10.1016/j.surfcoat.2011.04.018.
  • [21] Yang, H., Guo, X., Wu, G., Ding, W. & Birbilis, N. (2011). Electrodeposition of chemically and mechanically protective Al-coatings on AZ91D Mg alloy. Corros. Sci. 53, 381-387. DOI: 10.1016/j.corsci.2010.09.047.
  • [22] Czerwiński, F. (2002). The oxidation behaviour of an AZ91D magnesium alloy at high temperatures. Acta Mater. 50, 2639-2654.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-dda52449-a043-4a05-b43f-f8f053399375
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