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Gravity/buoyancy competition within coagulation of copper droplets in slag

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: A suspension of copper droplets in the slag coming from the direct-to-blister process was subjected to the treatment analogous to that usually applied to the electric arcfurnace process. In particular, recently patented by authors, complex reagent was applied and verified. Design/methodology/approach: The suspension was subjected to coagulation and solidification. Both processes were studied, independently. The suspension of droplets was treated not only by the recently patented complex reagent but by the CaO – industrial compound (in the amount of 5 %wt.) as well, to make comparison between both substances effectiveness. Findings: The observation was focused on the behavior of droplets to conclude whether the droplets are settled on the crucible bottom due to the effect of gravity or pushed to the liquid slag’s surface due to buoyancy force influence. In the case of the patented reagent application, the coagulation mainly was completed by the droplets’ settlement on the crucible bottom. The treatment performed with the use of the CaO – compound promoted the influence of buoyancy force. The coagulated copper droplets were pushed to the liquid slag’s surface. Research limitations/implications: Rest reagents known in the industry practice will be subjected to the analogous analysis in order to make further comparison with the effect of the patented chemical. Practical implications: Conclusion from the performed experiment made in the crucible (laboratory scale) allow to suggest how to improve not only the semi- or fully industrial directto-blister technology but the treatment of the slag in the electric arc-furnace as well.
Rocznik
Strony
35--45
Opis fizyczny
Bibliogr. 20 poz.
Twórcy
  • Institute of Metallurgy and Materials Science, ul. Reymonta 25, 30-059 Kraków, Poland
  • AGH University of Science and Technology, Mickiewicza 30, 30-059 Kraków, Poland
Bibliografia
  • [1] A.W. Bydałek, W. Wołczyński, A. Bydałek, P. Schlafka, Analysis of separation mechanism of the metallic phase of slag in the direct-to-blister process, Archives of Metallurgy and Materials 60 (2015) (in print).
  • [2] A.W. Bydałek, A. Bydałek, W. Wołczyński, S. Biernat, The concept of slag decopperisation in the flash furnace process by use of complex reagents, Archives of Metallurgy and Materials 60 (2015) 319-322.
  • [3] W. Wołczyński, Back-diffusion in crystal growth. Eutectics, Archives of Metallurgy and Materials 60 (2015) (in print).
  • [4] J. Nowakowski, Thermodynamic problems in copperfire refining, Metalurgia i Odlewnictwo, 2 (1976) 3-14.
  • [5] A.W. Bydałek, Role of carbon in melting copper processes, Archives of Foundry Engineering 11 (2011) 37-42.
  • [6] P. Migas, M. Karbowniczek, Interactions between liquid slag and graphite during the reduction of metallic oxides, Archives of Metallurgy and Materials 55 (2010) 1147-1157.
  • [7] A. Gierek, T. Karwan, J. Rojek, J. Szymek, Results of test with decopperisation of slag from flash process. Ores and Non-Ferrous Metals 50 (2005) 669-680.
  • [8] P. Migas, Analysis of the rheological behaviour of selected semi-solid slag systems in blast furnace flow conditions, Archives of Metallurgy and Materials 60 (2015) 85-93.
  • [9] A.W. Bydałek, The liquid surface during copper melting with carbon monoxide slag, Proceedings of the 3 rd Conference “High Temperature Capillarity”, Kurashiki, 2000, 157-158.
  • [10] A.W. Bydałek, The thermal analysis of the carbides slags solutions, Journal of Thermal Analysis 45 (1995) 919-921.
  • [11] A.W. Bydałek, A. Bydałek, K. Najman, P. Schlafka, The estimation of slag refining features for the Cu-Si alloys melting process, Archives of Foundry Engineering 8 (2008) 41-44.
  • [12]E. Krasicka-Cydzik, Copper de-oxidation with calcium carbide melts: electrochemical reactions, Journal of Applied Electrochemistry 31 (2001) 1155-1161.
  • [13] Y. Takeda, A. Yazawa, Fire Refining of Gruel Copper by Alkaline Carbonate Fluxes, Transactions of the Japan Institute of Metals 29 (1988) 224-232.
  • [14] W. Wołczyński, Transition phenomena in the diffusion soldering/brazing, Archives of Metallurgy and Materials 51 (2006) 609-615.
  • [15] J. Szajnar, Casting structure change caused by magnetic field, Journal of Achievements in Materials and Manufacturing Engineering 24 (2007) 297-306.
  • [16] W. Wołczyński, E. Guzik, D. Kopyciński, C. Senderowski, Mechanism of the intermetallic phase/ compound growth on the substrate, Journal of Achievements in Materials and Manufacturing Engineering 24 (2007) 324-327.
  • [17] C. Baron, J. Szajnar, The determination of the thickness of composite layer, Archives of Materials Science and Engineering 30 (2008) 45-48.
  • [18] J. Szajnar, M. Stawarz, T. Wróbel, W. Sebzda, Influence of electromagnetic field on pure metals and alloys structure, Journal of Achievements in Materials and Manufacturing Engineering 34 (2009) 95-102.
  • [19] M. Cholewa, T. Wróbel, S. Tenerowicz, Bimetallic layer castings, Journal of Achievements in Materials and Manufacturing Engineering 43 (2010) 385-392.
  • [20] T. Wróbel, Bimetallic layered castings alloy steelgrey cast iron, Archives of Materials Science and Engineering 48 (2011) 118-125.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-dd46612e-5f71-4b1b-a187-f00fc0c2f457
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