Preparation of ternary (35 – x)Sb2O3–xBi2O3–65P2O5 glasses for lead-free glass application

• Autorzy: Li Yu-Ting , Zhang Jing-Jing , Wang Zhi-Qiang , Xu Fei-Long , Lin Hai

Identyfikatory

DOI

10.2478/msp-2019-0088

• Języki publikacji: EN

Abstrakty

EN

Glasses composed of ternary components (35 – x)Sb₂O₃–x Bi₂O₃–65P₂O₅ (0 ⩽ x ⩽ 20 mol%) have been prepared and investigated as a potential alternative to lead-free glass for low temperature applications. Their structural properties were studied by Infrared Spectroscopy IR and Differential Thermal Analysis DTA. Results from the IR showed that Sb³⁺ and Bi³⁺ were responsible for glass network structure, which was supported by the diversification of density ρ and molar volume V_m with an increasing amount of Bi₂O₃. Glass transition temperature T_g, thermal stability, and coefficient of thermal expansion increased after substitution of Bi₂O₃ for Sb₂O₃ within the range of 0 mol% to 20 mol%. The water durability decreased and then increased; it could be attributed to the corrosion resistant P–O–Sb bonds. A typical sample of 25Sb₂O₃–10Bi₂O₃–65P₂O₅ possesses excellent properties and can be a promising candidate for further applications.

Słowa kluczowe

EN

structure; chemical properties; bismuth phosphates

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2020
• Tom: Vol. 38, No. 1
• Strony: 28--33
• Opis fizyczny: Bibliogr. 20 poz., tab., rys.

Twórcy

autor

Li Yu-Ting

• School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, China

autor

Zhang Jing-Jing

• School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, China

autor

Wang Zhi-Qiang

• School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, China

autor

Xu Fei-Long

• School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, China

autor

Lin Hai

• School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, China

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).