Decontamination of Metronidazole Antibiotic: A Novel Nanocomposite-Based Strategy

• Autorzy: Mhemid Rasha Khalid Sabri , Saeed Liqaa I. , Shihab Mohammed Salim

Identyfikatory

DOI

10.12911/22998993/168500

• Języki publikacji: EN

Abstrakty

EN

In this study, the synthesis of magnetic nanoparticles (MNPs) employing leaf extract from Alocasiamacrorrhiza was investigated as a reducing agent. CuFe₂O₄, CuFe₂O₄/CuO, and CuFe₂O₄/CuO/CdS made constituted the coreshell of these MNPs, which were stabilized on naturally Ninevite rocks (NRs) to provide a more cost-effective support. Analytical techniques of various methods were used to characterize the MNPs/NR nanocomposite that was produced utilizing eco-friendly methods. Among the methods used were infrared spectroscopy, X-ray diffraction, scanning electron microscopy, and vibrating sample magnetometry (VSM). The antibiotic Metronidazole (MET) was broken down using a potent nanocatalyst made of MNPs in a solar-irradiated batch system. A solar-photocatalytic system was used to investigate the effects of the initial MET concentration, irradiation time, H₂O₂ concentration, catalyst nanocomposite concentration, and pH solution on MET photodegradation. Artificial neural networks (ANNs) were also used in data modeling to determine which oxidation technique performed the best in certain conditions. This investigation showed that the CuFe₂O₄/CuO/CdS magnetic catalyst had the greatest MET removal efficiency of 97% among all MNPs. Moreover, ANN were used to examine data from the photocatalytic oxidation of MET utilizing a CuFe₂O₄/CuO/CdS/NRs catalyst. The results revealed that the MNP dose had the highest influence on the photodegradation of MET. The correlation coefficients (R²) for the training regressions, validation, testing, and total data were all 0.999, 0.996, 0.993, and 0.998, respectively.

Słowa kluczowe

EN

metronidazole antibiotic; magnetic nanoparticles; photodegradation; Ninevite rock; artificial neural network

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2023
• Tom: Vol. 24, nr 9
• Strony: 246--259
• Opis fizyczny: Bibliogr. 32 poz., rys., tab.

Twórcy

autor

Mhemid Rasha Khalid Sabri

• Department of Environmental Technologies, College of Environmental Science and Technologies, University of Mosul, 41001, Mosul, Iraq

• https://orcid.org/0000-0002-7008-7573

autor

Saeed Liqaa I.

• Department of Mining Engineering, College of Petroleum and Mining Engineering, University of Mosul, 41001, Mosul, Iraq

autor

Shihab Mohammed Salim

• Department of Environmental Engineering, College of Engineering, University of Mosul, 41001, Mosul, Iraq

• https://orcid.org/0000-0001-8628-921X

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