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Purpose: In this paper the oxidation behaviour of zirconium-doped NiAl coatings deposited on a pure nickel was investigated. Design/methodology/approach: The zirconium-doped NiAl coatings were deposited by the chemical vapour deposition method on the pure nickel. The microstructure investigations of zirconium-doped aluminide coatings were performed by the use of an optical microscope (Nikon Epiphot 300) and a scanning electron microscope (Hitachi S-3400N) equipped with an Energy Dispersive Spectroscope EDS (VOYAGER of NORAN INSTRUMENTS). Oxidation behaviour at 1100ºC for 500 h in the air atmosphere in the furnace manufactured by Czylok company was evaluated. The phase composition of oxidized coatings were identified by the X-ray (ARL X’TRAX) diffractometer. Findings: The microstructures of zirconium-doped aluminide coatings consist of the β-NiAl, γ’-Ni3Al and γ-Ni(Al) phases. EDS analysis results of elements distribution indicate that zirconium is located at the distance of 13-16 μm from the surface after 1.5 h of aluminizing and randomly distributed in the whole coating after 5 h of aluminizing. Zirconium (less than 1% at) could contribute to a faster reduction of Al vacancies through fast diffusion towards the metal/oxide interface and increases adhesion of the oxide layer to the coating and this why the oxidation resistance improves. Research limitations/implications: The research involve microstructure, phase composition and oxidation behaviour investigation of zirconium doped aluminide coatings. Practical implications: The zirconium-doped aluminide coatings may be used as the cheaper alternative to platinum and palladium modified aluminide coatings for turbine blades of aircraft engines. Originality/value: The range of investigation includes microstructure, phase composition and oxidation behaviour of zirconium doped aluminide coating.
Wydawca
Rocznik
Tom
Strony
250--254
Opis fizyczny
Bibliogr. 18 poz.
Twórcy
autor
- Department of Materials Science, Rzeszow University of Technology, Al. Powstańców Warszawy 12, 35-959 Rzeszów, Poland
autor
- Department of Materials Science, Rzeszow University of Technology, Al. Powstańców Warszawy 12, 35-959 Rzeszów, Poland
autor
- Department of Materials Science, Rzeszow University of Technology, Al. Powstańców Warszawy 12, 35-959 Rzeszów, Poland
Bibliografia
- [1] M. Warnes, N. DuShane, J. Cockerill, Cyclic oxidation of diffusion aluminide coatings on cobalt base superalloys, Surface and Coatings Technology 148 (2001) 163-170.
- [2] Y. Tamarin, Protective coatings for turbine blades, American Society for Metals International, 2002.
- [3] T. Narita, K. Thosin, L. Fengqun, S. Hayashi, H. Murakami, B. Gleeson, D. Young, Development of Re-based diffusion barrier, Materials and Corrosion 56 (2005) 923-929.
- [4] M. Yavorska, J. Sieniawski, Oxidation behaviour of platinum modified aluminide coatings deposited by CVD method on nickel-based superalloys under air atmosphere, Journal in Achievement in Materials and Manufacturing Engineering 46/2 (2011) 204-210.
- [5] J. Devis, Nickel, cobalt and their alloys, ASM Specialty Handbook, 2000.
- [6] F. Pedraza, A. Kennedy, J. Kopecek, P. Moretto, Investigation of the microstructure of platinum-modified aluminide coating, Surface and Coatings Technology 200 (2006) 4032- 4039.
- [7] P. Hou, V. Tolpygo, Examination of the platinum effect on the oxidation behaviour of nickel-aluminide coatings, Surface and Coatings Technology 202 (2007) 623-627.
- [8] S. Dryepondt D. Clarke, Cyclic oxidation-induced cracking of platinum-modified nickel-aluminide coatings, Scripta Materialia 60 (2009) 917-920.
- [9] M. Yavorska, J. Sieniawski, Effect of diffusion on platinum coatings deposited on the surface of nickel based superalloy by the electroplating process, Archives of Materials Science and Egineering 45 (2010) 56-60.
- [10] R. Swadźba, M. Hetmańczyk, M. Sozańska, B. Witala, L. Swadźba, Structure and cyclic oxidation resistance of Pt, Pt/Pd-modified and simple aluminide coatings on CMSX-4 superalloy, Surface and Coatings Technology 206 (2011) 1538-1544.
- [11] S. Hamadi, M. Bacos, M. Poulain, A. Seyeux, V. Maurice, P. Marcus, Oxidation resistance of a Zr-doped NiAl coating thermochemically deposited on a nickel-based superalloy, Surface and Coating Technology 204 (2009) 756-760.
- [12] Y. Wang, M. Suneson, G. Sayre, Synthesis of Hf-modified aluminide coatings on Ni-base superalloys, Surface and Coating Technology 206 (2011) 1218-1228.
- [13] V. Tolpygo, K. Murphy, D Clarke, Effect of Hf, Y and C in the underlying superalloy on the rumpling of diffusion aluminide coatings, Acta Materialia 56 (2008) 489-499.
- [14] M. Zagula-Yavorska, J. Sieniawski, T. Gancarczyk, Some properties of platinum and palladium modified aluminide coatings deposited by CVD method on nickel-base superalloys, Archives of Metallurgy and Materials 57 (2012) 503-509.
- [15] S. Hamadi, M. Bacos, M. Poulain, S. Zanna, V. Maurice, P. Marcus, Short-time oxidation of a NiAl(Zr) bond coat thermochemically deposited on a nickel-based superalloy, Materials Science Forum 595-598 (2008) 95-100.
- [16] D. Larson, M. Miller, Atom probe field-ion microscopy, characterization of nickel and titanium aluminides, Materials Characterization 44 (2000) 159-176.
- [17] M. Brumm, H. Grabke, Oxidation behaviour of NiAl-II. cavity formation beneath the oxide scale on NiAl of different stoichiometries, Corrosion Science 34 (1993) 547-553.
- [18] R. Haugsrud, On the high-temperature oxidation of nickel, Corrosion Science 45 (2003) 211-235.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-dc3d7f4b-e8cb-433c-866d-afca86d13938