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The purpose of this work was to determine the impact of a operating conditions on the deNOx system efficiency.in a 966MWth supercritical circulating fluidized bed boiler. Experimental tests were carried out on a full-scale DeNOx system installed in the world’s largest once through supercritical circulating fluidized bed boiler. In this work, the effects of the following parameters were studied: flue gas temperature inside the separators between 636°C and 845°C, relative ammonia mass flow over the range 0.22-1.00 and three relative values of O2 concentration (i.e. 0.94, 1.0 and 1.13). The efficiency of deNOx system increases (ca. 53%) with increasing relative ammonia mass flow. A maximum DeNOx system efficiency (ca. 70%) was achieved at flue gas temperature in the range from 720°C to 790°C. In the case of all unit loads, deNOx system efficiency from 36% to 70% was observed and performs a standard emissions relate to permissible concentration of NOx in the flue gas.
Czasopismo
Rocznik
Tom
Strony
1--8
Opis fizyczny
Bibliogr. 23 poz., rys., tab., wykr.
Twórcy
autor
- Czestochowa University of Technology, Institute of Advanced Energy Technologies, Poland
autor
- Czestochowa University of Technology, Institute of Advanced Energy Technologies, Poland
autor
- Tauron Generation S.A., Lagisza Power Plant, Poland
Bibliografia
- [1] R. Zevenhoven, P. Kilpinen, Control of pollutans in flue gases and fuel gases, 3rd Edition, Picaset Oy, Espoo, 2005.
- [2] K. Skalska, J. Miller, S. Ledakowicz, Trens in nox abatement: A review, Science of the Total Enviroment 48 (2010) 3976–3989.
- [3] T. Shimizu, M. Toyono, Emission of nox and n2o during co-combustion of dried sewage sludge with coal in a circulating fluidized-bed combustor, Fuel 86 (2007) 2308–2315.
- [4] M. Mansha, A. Qureshi, E. Shahid, Prediction of optimum parameters for nox reduction utilizing selective noncatalytic reduction (sncr) technique (thermal denox process), Pakistan Journal of Engineering and Applied Sciences 1 (2007) 67–72.
- [5] J. Zhao, C. Brereton, J. Grace, J. Lim, R. Legros, Gas concentration profiles and nox formation in circulating fluidized-bed combustor, Fuel 76 (1997) 853–860.
- [6] X. Hou, H. Zhang, M. Pilawska, J. Lu, G. Yue, The formation of n2o during the reduction of no by nh3, Fuel 87 (2008) 3271–3277.
- [7] X. Hou, S. Yang, J. Lu, H. Zhang, G. Yue, Effect of circulating ash from cfb boiler on no and n2o emission, Frontiers of Energy and Power Engineering in China 3 (2009) 241–246.
- [8] Z. Li, Q. Lu, Y. Na, N2o and no emissions from co-firing msw with coals in pilot scale cfbc, fuel process, Technol. 85 (2004) 1539–1549.
- [9] O. Ogunsola, Investigation of the cause of seasonal variations on nox emissions from waste-coal-fired circulating fluidized-bed utility plants, Ind. Eng. Chem. Res. 40 (2011) 3869–3878.
- [10] A. Tourunen, J. Saastamoinen, H. Nevalainen, Trends of no in circulating fluidized bed combustion, Fuel 88 (2009) 1333–1341.
- [11] S. Mahmooudi, J. Baeyens, J. Seville, Nox formation and selective non-catalic reduction (sncr) in a fluidized bed combustor of biomass, Biomass and Bioenergy 34 (2010) 1393–1409.
- [12] L. Duan, C. Zhao, W. Zhou, C. Qu, X. Chen, Effects of operation parameters on no emission in an oxy-fired cfb combustor, Fuel Processing Technology 92 (2011) 379– 384.
- [13] Y. Zeldovich, The oxidation of nitrogen in combustion and explosions, Acta Physicochimica 21 (1946) 577–628.
- [14] J. Benitez, Process engineering and design for air pollution control, New Yersey: Prentice Hall, Englewood Cliffs, 1993.
- [15] N. De Nevers, Air pollution, physical and chemical fundamentals, 2nd Edition, McGraw Hill Higher Education, 1999.
- [16] MDU-Westmoreland, Gascoyne Power Project, 175MW CFB BACT Determination (January 2005).
- [17] X. Wang, B. Gibbs, M. Rhodes, Impact of air staging on the fate of no and n2o in circulating fluidized-bed combustor, Combustion and Flame 99 (1994) 508–515.
- [18] B. Gibbs, T. Salam, S. Sibtain, R. Pragnell, D. Gauld, The reduction of nox emissions from a fluidized bed combustor by staged combustion combined with ammonia addition, in: 20th International conference on fluidized bed combustion, Vol. 22, San Francisco, USA, 1989, pp. 1147–1152.
- [19] B. Gibbs, F. Pereira, J. Beér, The influence of air staging on the no emission from fluidised bed coal combustion, in: 16th Symposium on combustion, Vol. 16, USA, 1977, pp. 461–474.
- [20] J. Kitto, Air pollution control for industrial boiler systems, in: ABMA Industrial Boiler Systems Conference, West Palm Beach, Florida, USA, 1996, pp. 1–12.
- [21] K. Tran, P. Kilpinen, N. Kumar, In-situ catalytic abatement of nox during fluidized bed combustion – a literature study, Applied Catalysis B: Enviromental 78 (2008) 129–138.
- [22] S. Goidich, Supercritical boiler options to match fuel combustion characteristic, in: Power-Gen Europe, Madrid, 2007, pp. 9–20.
- [23] A. Heider, O. Levenspiel, Drag coefficient and terminal velocity of spherical and nonspherical particles, Powder Technology 58 (1989) 63.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-dc3a0aa7-6f40-431f-a89d-77e3b7e5754f