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Micro-FTIR analysis to study the change in surface chemistry after addition of collectors and their effect on coal hydrophobicity

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In this study, the micro-FTIR analysis was used to investigate in-situ surface properties of coal, and was directly correlated to coal hydrophobicity, as measured by the contact angle before and after the addition of collectors, to understand their suitability for flotation. Three different collectors, diesel, pine needle oil and dodecyl trimethyl ammonium bromide (DTAB) were tested. The micro-FTIR technique provided a semi-quantitative analysis of functional groups present on the coal surface exactly where the contact angle was measured and provided a visualization of collector adsorption on specific areas of coal and associated changes in coal surface properties. This analysis could lead to a smarter way of using process design in terms of reagent selection for coal flotation to obtain a product of desired petrographic composition, which would especially be useful for coking coals. This study presents a work in progress for developing a procedure for a quick pre-selection of collectors for coal flotation based on coal surface properties.
Słowa kluczowe
Rocznik
Strony
1292--1302
Opis fizyczny
Bibliogr. 25 poz., rys., tab.
Twórcy
autor
  • China University of Mining and Technology
autor
  • University of British Columbia
  • University of British Columbia
autor
  • Indiana University
Bibliografia
  • ARNOLD, B. J., APLAN, F. F., 1989. The hydrophobicity of coal macerals. Fuel. 68, 651-658. DOI: 10.1016/00162361(89)90168-3.
  • BUJNOWSKA, B., 1985. Studies on floatability of petrographic constituents of sub-bituminous coals. Journal of Coal Preparation. 1(2), 169-188. DOI: 10.1080/07349348508945547.
  • CHEN, Y., CARO, L., MASTALERZ, M., SCHIMMELANN, A., BLANDON, A., 2013. Mapping the chemistry of resinite, funginite and associated vitrinite in coal with micro FTIR. Journal of microscopy. 249, 69-81. DOI: 10.1111/j.1365-2818.2012.03685.x.
  • CHEN, Y., MASTALERZ, M., SCHIMMELANN, A., 2012. Characterization of Chemical Functional Groups in Macerals across Different Coal Ranks via Micro-FTIR Spectroscopy. International Journal of Coal Geology. 104, 22–33. DOI: 10.1016/j.coal.2012.09.001.
  • GIVEN, P. H., CRONAUER, D. C., SPACKMAN, W., LOVELL, H. L., DAVIS, A., BISWAS, B. 1975. Dependence of coal liquefaction behaviour on coal characteristics. 1. vitrinite-rich samples. Fuel. 54(1), 34-39. DOI: 10.1016/00162361(75)90027-7.
  • GUTIERREZ-RODRIGUEZ, J. A., APLAN, F. F., 1984. The effect of oxygen on the hydrophobicity and floatability of coal. Colloids and surfaces. 12, 27-51. DOI: 10.1016/0166-6622(84)80087-6.
  • GUTIERREZ-RODRIGUEZ, J. A., PURCELL, R. J., APLAN, F. F., 1984. Estimating of hydrophobicity of coal. Colloids and surfaces. 12, 1-25. DOI: 10.1016/0166-6622(84)80086-4.
  • HANNING, R. N., RUTTER, P. R., 1989. A simple method of determining contact angles on particles and their relevance to flotation. International Journal of Mineral Processing. 27, 133–146. DOI: 10.1016/03017516(89)90011-2.
  • HOLUSZKO, M. E., MASTALERZ, M. D., 2015. Coal maceral chemistry and its implications for selectivity in coal floatability. International Journal of Coal Preparation and Utilization. 35, 99-110. DOI: 10.1080/19392699.2014.967850.
  • KLASSEN, V., 1953. Elements of Coal Flotation Theory. Ugletekhizdat, Moscow.
  • LASKOWSKI, J. S., 2001. Coal flotation and fine coal utilization. Amsterdam, New York, Elsevier. Volume 14(1).
  • LIU, J., 2016. Chemical composition of coal surface as derived from micro-FTIR and its effects on contact angle. (Master of Applied Science thesis, University of British Columbia). DOI: 10.14288/1.0307285.
  • LIU, J., HOLUSZKO, M.E., MASTALERZ, M.D., 2017. Applications of micro-FTIR technique in studying hydrophobicity of coal. International Journal of Coal Geology. 178, 74-83. DOI: 10.1016/j.coal.2017.04.015.
  • MASTALERZ, M., BUSTIN, R. M., 1993. Variation in maceral chemistry within and between coals of varying rank: an electron microprobe and micro-Fourier Transform Infra-Red investigation. Journal of Microscopy. 171, 153–166. DOI: 10.1111/j.1365-2818.1993.tb03369.x.
  • MASTALERZ, M., BUSTIN, R. M., 1996. Application of reflectance micro-Fourier Transform infrared analysis to the study of coal macerals: an example from the Late Jurassic to Early Cretaceous coals of the Mist Mountain Formation, British Columbia, Canada. International Journal of Coal Geology. 32, 55-67. DOI: 10.1016/S0166-5162(96)00030-4.
  • OFORI, P., FIRTH, B., O’BRIEN, G., MCNALLY, C., NGUYEN, A. V., 2010. Assessing the Hydrophobicity of Petrographically Heterogeneous Coal Surfaces. Energy and Fuels. 24, 5965-5971. DOI: 10.1021/ef100793t.
  • OFORI, P., O’BRIEN, G., FIRTH, B., JENKINS, B., 2006. Flotation Process Diagnostics and Modelling by Coal Grain Analysis. Minerals Engineering. 19, 633-640. DOI: 10.1016/j.mineng.2005.09.036.
  • ONLIN, T.J., APLAN, F.F., 1984. Use of oily collectors for the flotation of coals of various ranks. Proceedings of Annual AIME meeting, Denver, Colorado.
  • PAINTER, P. C., SNYDER, R. W., STARSINIC, M., COLEMAN, M. M., KUEHN, D. W., DAVIS, A. 1981. Concerning the application of FT-IR to the study of coal: A critical assessment of band assignments and the application of spectral analysis programs. Applied Spectroscopy. 35, 475-485. DOI: 10.1366/0003702814732256.
  • PAINTER, P. C., STARSINIC, M., COLEMAN, M. M., 1985. Determination of functional groups in coal by Fourier Transform Interferometry. In: Fourier Transform Infrared Spectroscopy (Ferraro, J. R., and basile, L. J., Eds.). Academic Press, New York, 169-240. DOI: 10.1016/B978-0-12-254104-9.50011-0.
  • PARKASH, S., LALI, K., HOLUSZKO, M., 1985. Separation of macerals from sub-bituminous coals and their response to liquefaction. Liquid Fuels Technology. 3(3), 345–375. DOI: 10.1080/07377268508915389.
  • PARKASH, S., LALI, K., HOLUSZKO, M., DU PLESSIS, M. P., 1984. Contribution of vitrinite macerals to the liquefaction of sub-bituminous coals. Fuel Processing Technology. 9, 139–148. DOI: 10.1016/0378-3820(84)90027-4.
  • SHIBAOKA, M., UEDA, S., 1978. Formation and stability of mesophase during coal hydrogenation. 1. Formation of mesophase. Fuel. 57(11), 667-672. DOI: 10.1016/0016-2361(78)90018-2.
  • WANG, S., GRIFFITHS, P., 1985. Resolution enhancement of diffuse reflectance i.r. spectra of coals by Fourier selfdeconvolution. Fuel. 64(2), 229-236. DOI: 10.1016/0016-2361(85)90223-6.
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-dbbc1df2-d60d-4bca-9d91-d1d147f95607
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