Hydration layers on clay mineral surfaces in aqueous solutions: a review

• Autorzy: Min F. , Peng C. , Song S.

Identyfikatory

DOI

10.2478/amsc-2014-0035

Warianty tytułu

PL

Warstwy uwodnione na powierzchni minerałów ilastych w roztworach wodnych: przegląd

• Języki publikacji: EN

Abstrakty

EN

Hydration layer on clay mineral surfaces is originated from the adsorption of polar water molecules and hydrated cations on the surfaces through unsaturated ionic bonds, hydrogen bonds and van der Waals bonds. It has attracted great attentions because of their important influences on the dispersive stability of the particles in aqueous solutions. This review highlighted the molecular structure of clay minerals, the origin of hydration layers on clay mineral surfaces, the hydration layer structural model, hydration force and the main parameters of affecting the hydration layers on clay minerals (crystal structure, cationic type and strength, and solution pH). Also, the research methods for hydration layers were briefly described, especially the determination of hydration layer thickness by the Einstein viscosity method and AFM method. In addition, the applications of the stability of fine clay mineral particles in aqueous suspensions were summarized.

PL

Warstwa uwodniona na powierzchni minerałów ilastych (gliniastych) powstaje w wyniku adsorpcji polarnych cząsteczek wody i uwodnionych kationów powierzchniowych wiązanych za pomocą nienasyconych wiązań jonowych, wiązań wodorowych i wiązań van der Waalsa. Zagadnienie to wzbudza wiele uwagi ze względu na to, że w dużej mierze warunkuje stabilność dyspersyjną cząstek w roztworach wodnych. W pracy omówiono strukturę molekularną minerałów ilastych, powstawanie warstw uwodnionych na powierzchni minerałów ilastych i siły hydratacji; przedstawiono także model strukturalny warstwy uwodnionej oraz główne parametry warunkujące powstawanie warstwy uwodnionej na powierzchni materiałów ilastych (struktura krystaliczna, rodzaj występujących kationów, stężenie roztworu i jego pH). Ponadto, pokrótce przedstawiono metody badań, ze szczególnym uwzględnieniem badania grubości warstw uwodnionych przy zastosowaniu modelu lepkości Einsteina oraz metody AFM. Ponadto, zestawiono zagadnienia związane ze stabilnością cząstek drobnoziarnistych minerałowa ilastych i ich potencjalne zastosowania.

Słowa kluczowe

EN

hydration layers; clay minerals; dispersion; hydration force

PL

warstwy uwodnione; minerały ilaste; dyspersja; siła hydratacji

• Wydawca: Instytut Mechaniki Górotworu PAN
• Czasopismo: Archives of Mining Sciences
• Rocznik: 2014
• Tom: Vol. 59, no. 2
• Strony: 489--500
• Opis fizyczny: Bibliogr. 69 poz., rys.

Twórcy

autor

Min F.

• School of Materials Science and Engineering, Anhui University of Science and Technology, Shungeng Road 168, Huainan, Anhui, C.P. 232001, China

autor

Peng C.

• School of Materials Science and Engineering, Anhui University of Science and Technology, Shungeng Road 168, Huainan, Anhui, C.P. 232001, China

autor

Song S.

• Instituto de Metalurgia, Universidad Autonoma de San Luis Potosi, Av. Sierra Leona 550, San Luis Potosi, C.P. 78210, Mexico

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