Synthesis and Property of 1,4-Diamino-3,6- dinitropyrazolo[4,3-c]pyrazole and Its Derivatives

• Autorzy: Li Y.-N. , Wang B.-Z. , Shu Y.-J. , Zhang S.-Y. , Lian P.
• Języki publikacji: EN

Abstrakty

EN

A synthetic procedure has been developed for the synthesis of 1,4-diamino- 3,6-dinitropyrazolo[4,3-c]pyrazole (DADNP) via N-amination reaction. Its derivatives, 4,4’-(triaz-1-ene-1,3-diyl)bis(1-amine-3,6-dinitropyrazolo[4,3-c] pyrazole) (TBADNP) and 1,4-dinitramino-3,6-dinitropyrazolo[4,3-c]pyrazole (DNADNP), were first designed and synthesized by the diazotization and nitrification of amino group, and their structures were characterized by IR, 1H NMR, 13C NMR, elementary analysis and MS. The thermal properties of target compounds were studied by means of differential scanning calorimetry (DSC) and thermogravimetry (TG). The thermal decomposition peak temperatures of DADNP, TBADNP and DNADNP are 227, 236 and 288 °C, respectively. Results show that the derivatives of 1,4-diamino-3,6-dinitropyrazolo[4,3-c]pyrazole have better thermal stability.

Słowa kluczowe

EN

3,6-dinitropyrazolo[4,3-c]pyrazole (DNPP); 1,4-diamino-3,6- dinitropyrazolo[4,3-c]pyrazole (DADNP); 4,4’-(triaz-1-ene-1,3-diyl)bis(1- amine-3,6-dinitropyrazolo[4,3-c]pyrazole) (TBADNP); N-amination reaction; synthesis; property

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2016
• Tom: Vol. 13, no. 2
• Strony: 321--331
• Opis fizyczny: Bibliogr. 26 poz., rys., tab.

Twórcy

autor

Li Y.-N.

• Xi'an Modern Chemistry Research Institute, Xi’an 710065, China

autor

Wang B.-Z.

• Xi'an Modern Chemistry Research Institute, Xi’an 710065, China

autor

Shu Y.-J.

• Xi'an Modern Chemistry Research Institute, Xi’an 710065, China

autor

Zhang S.-Y.

• Xi'an Modern Chemistry Research Institute, Xi’an 710065, China
• Department of Chemistry, School of Pharmacy, Fourth Military Medical University, Xi’an 710032, China

autor

Lian P.

• Xi'an Modern Chemistry Research Institute, Xi’an 710065, China

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.